R. Janipoor, Azita Mohagheghian, M. Shirzad-Siboni
{"title":"通过合成甘蔗渣磁性氧化石墨烯,在可见光照射下光催化去除水溶液中的 AR14","authors":"R. Janipoor, Azita Mohagheghian, M. Shirzad-Siboni","doi":"10.1080/03067319.2021.2009473","DOIUrl":null,"url":null,"abstract":"ABSTRACT At this present investigation, sugarcane bagasse magnetic graphene oxide (SCBMGO) was synthesised in several stages and used to remove Acid Red 14 dye under LED visible light. XRD, FT-IR, SEM, EDX, VSM and pHPZC analyses demonstrated the structural characteristics. The effect of variables like the pH, catalyst dose, dye concentration, hydrogen peroxide, purging gases, organic compounds, ionic strength, and comparison of different processes, radical scavengers, and reusability on AR14 removal efficiency were investigated. The most removal efficiency occurred under ideal situation: [AR14]0 = 10 mgL−1, SCBMGO dosage = 0.5 gL−1, pH = 3, hydrogen peroxide = 5 mM, and contact time equal to 120 minutes. Except for the dose, the efficiency of photocatalytic removal of AR14 decreased with the addition of other variables. AR14 photocatalytic removal obeyed the pseudo-second-order reaction kinetic. The EEO value for LED/SCBMGO (59.62 kWh/m3) process, as a function of removal proficiency, illustrated that this process was elevated productivity and diminished the cost of electrical energy consumed by the system. The highest removal efficiency of AR14 occurred in the LED/SCBMGO process (89.85%). In addition, recycling test efficiency was the same at the beginning, and the 6th stage. The removal efficiency of AR14 in drinking water was (71.45%). SCBMGO, as an effective and environmentally friendly catalyst, can be used in removing AR14 dye and organic pollutants of aqueous environments under the LED visible light.","PeriodicalId":13973,"journal":{"name":"International Journal of Environmental Analytical Chemistry","volume":"89 6","pages":"9353 - 9371"},"PeriodicalIF":2.3000,"publicationDate":"2023-12-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Photocatalytic removal of AR14 from aqueous solutions under visible light irradiation by synthesising sugarcane bagasse magnetic graphene oxide\",\"authors\":\"R. Janipoor, Azita Mohagheghian, M. Shirzad-Siboni\",\"doi\":\"10.1080/03067319.2021.2009473\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"ABSTRACT At this present investigation, sugarcane bagasse magnetic graphene oxide (SCBMGO) was synthesised in several stages and used to remove Acid Red 14 dye under LED visible light. XRD, FT-IR, SEM, EDX, VSM and pHPZC analyses demonstrated the structural characteristics. The effect of variables like the pH, catalyst dose, dye concentration, hydrogen peroxide, purging gases, organic compounds, ionic strength, and comparison of different processes, radical scavengers, and reusability on AR14 removal efficiency were investigated. The most removal efficiency occurred under ideal situation: [AR14]0 = 10 mgL−1, SCBMGO dosage = 0.5 gL−1, pH = 3, hydrogen peroxide = 5 mM, and contact time equal to 120 minutes. Except for the dose, the efficiency of photocatalytic removal of AR14 decreased with the addition of other variables. AR14 photocatalytic removal obeyed the pseudo-second-order reaction kinetic. The EEO value for LED/SCBMGO (59.62 kWh/m3) process, as a function of removal proficiency, illustrated that this process was elevated productivity and diminished the cost of electrical energy consumed by the system. The highest removal efficiency of AR14 occurred in the LED/SCBMGO process (89.85%). In addition, recycling test efficiency was the same at the beginning, and the 6th stage. The removal efficiency of AR14 in drinking water was (71.45%). SCBMGO, as an effective and environmentally friendly catalyst, can be used in removing AR14 dye and organic pollutants of aqueous environments under the LED visible light.\",\"PeriodicalId\":13973,\"journal\":{\"name\":\"International Journal of Environmental Analytical Chemistry\",\"volume\":\"89 6\",\"pages\":\"9353 - 9371\"},\"PeriodicalIF\":2.3000,\"publicationDate\":\"2023-12-29\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"International Journal of Environmental Analytical Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1080/03067319.2021.2009473\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, ANALYTICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"International Journal of Environmental Analytical Chemistry","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1080/03067319.2021.2009473","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, ANALYTICAL","Score":null,"Total":0}
Photocatalytic removal of AR14 from aqueous solutions under visible light irradiation by synthesising sugarcane bagasse magnetic graphene oxide
ABSTRACT At this present investigation, sugarcane bagasse magnetic graphene oxide (SCBMGO) was synthesised in several stages and used to remove Acid Red 14 dye under LED visible light. XRD, FT-IR, SEM, EDX, VSM and pHPZC analyses demonstrated the structural characteristics. The effect of variables like the pH, catalyst dose, dye concentration, hydrogen peroxide, purging gases, organic compounds, ionic strength, and comparison of different processes, radical scavengers, and reusability on AR14 removal efficiency were investigated. The most removal efficiency occurred under ideal situation: [AR14]0 = 10 mgL−1, SCBMGO dosage = 0.5 gL−1, pH = 3, hydrogen peroxide = 5 mM, and contact time equal to 120 minutes. Except for the dose, the efficiency of photocatalytic removal of AR14 decreased with the addition of other variables. AR14 photocatalytic removal obeyed the pseudo-second-order reaction kinetic. The EEO value for LED/SCBMGO (59.62 kWh/m3) process, as a function of removal proficiency, illustrated that this process was elevated productivity and diminished the cost of electrical energy consumed by the system. The highest removal efficiency of AR14 occurred in the LED/SCBMGO process (89.85%). In addition, recycling test efficiency was the same at the beginning, and the 6th stage. The removal efficiency of AR14 in drinking water was (71.45%). SCBMGO, as an effective and environmentally friendly catalyst, can be used in removing AR14 dye and organic pollutants of aqueous environments under the LED visible light.
期刊介绍:
International Journal of Environmental Analytical Chemistry comprises original research on all aspects of analytical work related to environmental problems. This includes analysis of organic, inorganic and radioactive pollutants in air, water, sediments and biota; and determination of harmful substances, including analytical methods for the investigation of chemical or metabolic breakdown patterns in the environment and in biological samples.
The journal also covers the development of new analytical methods or improvement of existing ones useful for the control and investigation of pollutants or trace amounts of naturally occurring active chemicals in all environmental compartments. Development, modification and automation of instruments and techniques with potential in environment sciences are also part of the journal.
Case studies are also considered, particularly for areas where information is scarce or lacking, providing that reported data is significant and representative, either spatially or temporally, and quality assured. Owing to the interdisciplinary nature of this journal, it will also include topics of interest to researchers in the fields of medical science (health sciences), toxicology, forensic sciences, oceanography, food sciences, biological sciences and other fields that, in one way or another, contribute to the knowledge of our environment and have to make use of analytical chemistry for this purpose.