哈科特港四个选定市场番茄中农药残留的监测与评估

O. M. Azeez, U. Zakka, Y. Akinyemi, O. Akpore
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引用次数: 0

摘要

在哈科特港的果园、Rumuokoro、Mile 3 和油坊市场对番茄的农药残留进行了调查。对公开市场上的水果进行了农药残留监测,并与规定的安全限值进行了比较。预处理后的样品经索氏提取后,使用气相色谱仪结合电子捕获检测器(GC-ECD)分析了各组农药,尤其是有机氯农药(OCPs)的含量。大多数样本中都检测到了 12 种有机氯农药和其他残留物,出现率从 35% 到 100%不等,含量都超过了最高残留限量(MRL)。样本中α氯丹和硫丹的方法检测限(MDL)分别为 0.0408 毫克/千克和 0.0723 毫克/千克,定量限(LOQ)分别为 0.0047 毫克/千克和 0.3952 毫克/千克。在番茄样品中检测到的农药中,杀虫剂(14 种)占 58.7%,杀菌剂(5 种)占 22.7%,除草剂(4 种)占 17.9%。在四个市场的样品中,甲氧氯的平均浓度过高。此外,Oil Mill 和 Mile 3 市场的 О'ρ Рρ、DDT(0.18±0.20)浓度高于其代谢物(0.13±0.03)(0.14±0.02),这可能会对我们的健康造成危害。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Monitoring and Assessment of Pesticide Residue in Tomato from Four Selected Markets in Port Harcourt
Investigation of pesticide residues of tomato was carried out in Fruit garden, Rumuokoro, Mile 3 and Oil Mill markets, Port Harcourt. The pesticide residues of the fruit obtained in open markets was monitored and compared with established safety limits. The pretreated samples were Soxhlet extracted and analysed for groups of pesticide most especially Organochlorine pesticides (OCPs) content using a Gas Chromatograph coupled with an Electron Capture Detector (GC-ECD). A total of 12 OCPs and other residues were detected in most of the samples with the percentage occurrence ranging from 35%-100%, and the levels found exceeding their Maximum Residue Limits (MRLs). The Method Detection Limit (MDL) of the samples was 0.0408 mg/kg α Chlordane and 0.0723 mg/kg endosulfan sulfate; while the limit of quantitation (LOQ) of these pesticides were 0.0047mg/kg and 0.3952 mg/kg respectively. Among the pesticides determined 58.7% insecticides (14), 22.7% fungicides (5) and 17.9% Herbicide (4) were detected in the tomato samples. The mean concentration of Metoxychlor was excessively higher in samples obtained across the four markets. Also, the concentration of О’ρ Рρ, DDT (0.18±0.20) was higher than its metabolite, (0.13±0.03) in Oil Mill and Mile 3 markets (0.14±0.02) which might portend danger for our health.
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