K. T. Dauda, T. F. Owoeye, I. G. Akande, O. S. I. Fayomi
{"title":"评估酸性介质中白花前胡叶和果皮水提取物对低碳钢的缓蚀和吸附效果","authors":"K. T. Dauda, T. F. Owoeye, I. G. Akande, O. S. I. Fayomi","doi":"10.1134/S2070205123701137","DOIUrl":null,"url":null,"abstract":"<p>Service failure of mild steel has been a challenge in many industries such as automotive, petrochemical and marine, thus, limiting the application of mild steel. This has prompted the use of several inhibitors as surface protectors against corrosion. In this work, the inhibiting action of the extract from leaves and peels of <i>Chrysophyllum albidum</i> on mild steel corrosion in 1 M H<sub>2</sub>SO<sub>4</sub> solution was studied using weight loss, gasometric and polarization techniques. The results showed that the inhibiting action increased with the increasing concentration of the inhibitors. The highest efficiency of 94.39 and 99.96% were respectively obtained for leaves and peels extract for 18 days with a concentration of 1.5 g/L. More so, the leaves and peels extract inhibited mild steel exhibited a significant corrosion rate of 0.0616 and 0.0254 mm/year, respectively. There was a good agreement between weight loss, gasometric and electrochemical methods (potentiodynamic polarization). C<i>hrysophyllum albidum</i> adsorbed on the mild steel surface in accordance with a Langmuir isotherm adsorption model with <i>R</i><sup>2</sup> values of 0.9940 and 0.9937 for the leaves and peels extract, respectively. In this study, <i>Chrysophyllum</i> <i>albidum</i> extract was shown to reduce corrosion of low carbon steel, and its use in acidic media is thus recommended.</p>","PeriodicalId":745,"journal":{"name":"Protection of Metals and Physical Chemistry of Surfaces","volume":"59 6","pages":"1290 - 1297"},"PeriodicalIF":1.1000,"publicationDate":"2023-12-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Evaluation of Corrosion Inhibition and Adsorption Effect of Aqueous Chrysophyllum Albidum Leaves and Peels Extract on Mild Steel in Acidic Medium\",\"authors\":\"K. T. Dauda, T. F. Owoeye, I. G. Akande, O. S. I. Fayomi\",\"doi\":\"10.1134/S2070205123701137\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>Service failure of mild steel has been a challenge in many industries such as automotive, petrochemical and marine, thus, limiting the application of mild steel. This has prompted the use of several inhibitors as surface protectors against corrosion. In this work, the inhibiting action of the extract from leaves and peels of <i>Chrysophyllum albidum</i> on mild steel corrosion in 1 M H<sub>2</sub>SO<sub>4</sub> solution was studied using weight loss, gasometric and polarization techniques. The results showed that the inhibiting action increased with the increasing concentration of the inhibitors. The highest efficiency of 94.39 and 99.96% were respectively obtained for leaves and peels extract for 18 days with a concentration of 1.5 g/L. More so, the leaves and peels extract inhibited mild steel exhibited a significant corrosion rate of 0.0616 and 0.0254 mm/year, respectively. There was a good agreement between weight loss, gasometric and electrochemical methods (potentiodynamic polarization). C<i>hrysophyllum albidum</i> adsorbed on the mild steel surface in accordance with a Langmuir isotherm adsorption model with <i>R</i><sup>2</sup> values of 0.9940 and 0.9937 for the leaves and peels extract, respectively. In this study, <i>Chrysophyllum</i> <i>albidum</i> extract was shown to reduce corrosion of low carbon steel, and its use in acidic media is thus recommended.</p>\",\"PeriodicalId\":745,\"journal\":{\"name\":\"Protection of Metals and Physical Chemistry of Surfaces\",\"volume\":\"59 6\",\"pages\":\"1290 - 1297\"},\"PeriodicalIF\":1.1000,\"publicationDate\":\"2023-12-29\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Protection of Metals and Physical Chemistry of Surfaces\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S2070205123701137\",\"RegionNum\":4,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"METALLURGY & METALLURGICAL ENGINEERING\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Protection of Metals and Physical Chemistry of Surfaces","FirstCategoryId":"88","ListUrlMain":"https://link.springer.com/article/10.1134/S2070205123701137","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"METALLURGY & METALLURGICAL ENGINEERING","Score":null,"Total":0}
Evaluation of Corrosion Inhibition and Adsorption Effect of Aqueous Chrysophyllum Albidum Leaves and Peels Extract on Mild Steel in Acidic Medium
Service failure of mild steel has been a challenge in many industries such as automotive, petrochemical and marine, thus, limiting the application of mild steel. This has prompted the use of several inhibitors as surface protectors against corrosion. In this work, the inhibiting action of the extract from leaves and peels of Chrysophyllum albidum on mild steel corrosion in 1 M H2SO4 solution was studied using weight loss, gasometric and polarization techniques. The results showed that the inhibiting action increased with the increasing concentration of the inhibitors. The highest efficiency of 94.39 and 99.96% were respectively obtained for leaves and peels extract for 18 days with a concentration of 1.5 g/L. More so, the leaves and peels extract inhibited mild steel exhibited a significant corrosion rate of 0.0616 and 0.0254 mm/year, respectively. There was a good agreement between weight loss, gasometric and electrochemical methods (potentiodynamic polarization). Chrysophyllum albidum adsorbed on the mild steel surface in accordance with a Langmuir isotherm adsorption model with R2 values of 0.9940 and 0.9937 for the leaves and peels extract, respectively. In this study, Chrysophyllumalbidum extract was shown to reduce corrosion of low carbon steel, and its use in acidic media is thus recommended.
期刊介绍:
Protection of Metals and Physical Chemistry of Surfaces is an international peer reviewed journal that publishes articles covering all aspects of the physical chemistry of materials and interfaces in various environments. The journal covers all related problems of modern physical chemistry and materials science, including: physicochemical processes at interfaces; adsorption phenomena; complexing from molecular and supramolecular structures at the interfaces to new substances, materials and coatings; nanoscale and nanostructured materials and coatings, composed and dispersed materials; physicochemical problems of corrosion, degradation and protection; investigation methods for surface and interface systems, processes, structures, materials and coatings. No principe restrictions exist related systems, types of processes, methods of control and study. The journal welcomes conceptual, theoretical, experimental, methodological, instrumental, environmental, and all other possible studies.