评估酸性介质中白花前胡叶和果皮水提取物对低碳钢的缓蚀和吸附效果

IF 1.1 4区 材料科学 Q3 METALLURGY & METALLURGICAL ENGINEERING
K. T. Dauda, T. F. Owoeye, I. G. Akande, O. S. I. Fayomi
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引用次数: 0

摘要

摘要 低碳钢的使用故障一直是汽车、石化和海洋等许多行业面临的挑战,从而限制了低碳钢的应用。这促使人们使用多种抑制剂作为表面防腐蚀保护剂。在这项研究中,使用失重法、气相法和极化法研究了白叶金雀花叶片和果皮提取物在 1 M H2SO4 溶液中对低碳钢腐蚀的抑制作用。结果表明,随着抑制剂浓度的增加,抑制作用也随之增强。浓度为 1.5 g/L 的树叶和果皮萃取物在 18 天内的最高效率分别为 94.39% 和 99.96%。此外,树叶和果皮提取物对低碳钢的显著腐蚀率分别为 0.0616 毫米/年和 0.0254 毫米/年。失重法、气相法和电化学法(电位极化)之间的结果非常一致。白叶菊在低碳钢表面的吸附符合 Langmuir 等温线吸附模型,叶片和果皮提取物的 R2 值分别为 0.9940 和 0.9937。这项研究表明,白叶女贞提取物可减少低碳钢的腐蚀,因此建议在酸性介质中使用白叶女贞提取物。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Evaluation of Corrosion Inhibition and Adsorption Effect of Aqueous Chrysophyllum Albidum Leaves and Peels Extract on Mild Steel in Acidic Medium

Evaluation of Corrosion Inhibition and Adsorption Effect of Aqueous Chrysophyllum Albidum Leaves and Peels Extract on Mild Steel in Acidic Medium

Service failure of mild steel has been a challenge in many industries such as automotive, petrochemical and marine, thus, limiting the application of mild steel. This has prompted the use of several inhibitors as surface protectors against corrosion. In this work, the inhibiting action of the extract from leaves and peels of Chrysophyllum albidum on mild steel corrosion in 1 M H2SO4 solution was studied using weight loss, gasometric and polarization techniques. The results showed that the inhibiting action increased with the increasing concentration of the inhibitors. The highest efficiency of 94.39 and 99.96% were respectively obtained for leaves and peels extract for 18 days with a concentration of 1.5 g/L. More so, the leaves and peels extract inhibited mild steel exhibited a significant corrosion rate of 0.0616 and 0.0254 mm/year, respectively. There was a good agreement between weight loss, gasometric and electrochemical methods (potentiodynamic polarization). Chrysophyllum albidum adsorbed on the mild steel surface in accordance with a Langmuir isotherm adsorption model with R2 values of 0.9940 and 0.9937 for the leaves and peels extract, respectively. In this study, Chrysophyllum albidum extract was shown to reduce corrosion of low carbon steel, and its use in acidic media is thus recommended.

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来源期刊
CiteScore
1.90
自引率
18.20%
发文量
90
审稿时长
4-8 weeks
期刊介绍: Protection of Metals and Physical Chemistry of Surfaces is an international peer reviewed journal that publishes articles covering all aspects of the physical chemistry of materials and interfaces in various environments. The journal covers all related problems of modern physical chemistry and materials science, including: physicochemical processes at interfaces; adsorption phenomena; complexing from molecular and supramolecular structures at the interfaces to new substances, materials and coatings; nanoscale and nanostructured materials and coatings, composed and dispersed materials; physicochemical problems of corrosion, degradation and protection; investigation methods for surface and interface systems, processes, structures, materials and coatings. No principe restrictions exist related systems, types of processes, methods of control and study. The journal welcomes conceptual, theoretical, experimental, methodological, instrumental, environmental, and all other possible studies.
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