氧化和监测环境基质中多环芳烃的快速高效工艺

IF 3.4 3区 化学 Q2 CHEMISTRY, PHYSICAL
Kelvin C. Araújo , Eryka T.D. Nóbrega , Ailton J. Moreira , Sherlan G. Lemos , Wallace D. Fragoso , Ernesto C. Pereira
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引用次数: 0

摘要

本研究提出了一种高效光降解多环芳烃及其衍生物的新方法。利用一个能产生高浓度 -OH 的微波光化学反应器(2.3 mmol L-1 h-1),在短短几分钟内就能去除 PAH。荧光激发-发射矩阵(EEM)光谱法与并行因子分析法(PARAFAC)相结合,对低浓度(μg L-1)的两种多环芳烃和一种烷基化多环芳烃进行了定量分析。这些结果凸显了光化学降解系统与 EEM-PARAFAC 相结合作为一种快速、廉价、高效的多环芳烃环境修复研究替代方法的巨大潜力。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Fast and efficient processes for oxidation and monitoring of polycyclic aromatic hydrocarbons in environmental matrices

Fast and efficient processes for oxidation and monitoring of polycyclic aromatic hydrocarbons in environmental matrices

Fast and efficient processes for oxidation and monitoring of polycyclic aromatic hydrocarbons in environmental matrices

This study proposes a new approach for the efficient photodegradation of polycyclic aromatic hydrocarbons (PAH) and derivatives. PAH removal was achieved in just a few minutes using a microwave photochemical reactor capable of producing a high concentration of OH (2.3 mmol L−1 h−1). Fluorescence excitation-emission matrix (EEM) spectroscopy coupled to parallel factor analysis (PARAFAC) was used for quantifying two PAH and one alkylated PAH at low concentrations (μg L−1). These results highlight the high potential of the photochemical degradation system coupled to EEM-PARAFAC as an alternative fast, inexpensive, and efficient approach for environmental remediation studies of PAH.

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来源期刊
Catalysis Communications
Catalysis Communications 化学-物理化学
CiteScore
6.20
自引率
2.70%
发文量
183
审稿时长
46 days
期刊介绍: Catalysis Communications aims to provide rapid publication of significant, novel, and timely research results homogeneous, heterogeneous, and enzymatic catalysis.
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