新型瞬态热线导热仪和 20 K 至 300 K 温度下氦气的测量结果

IF 2.2 3区 工程技术 Q3 CHEMISTRY, PHYSICAL
Xiufang Zhao , Xian Wang , Xueqiang Dong , Yunxiao Wang , Yanxing Zhao , Bowen Sheng , Maoqiong Gong
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引用次数: 0

摘要

本研究设计了一种基于瞬态热线法(THW)的仪器,用于测量温度范围为 20-300 K、压力范围为 0-20 MPa 的低温流体的导热系数,相对扩展不确定度 Ur(λ) 为 0.0284 (k = 2, 95 %)。甲烷、乙烷和二氧化碳的实验数据与 ECS 模型显示出良好的一致性,验证了仪器的可靠性。除了 70 K 以上热线电阻的线性温度依赖性之外,还校准了 70 K 以下的非线性温度依赖性,验证了 THW 方法在 20-70 K 温度范围内测量的可行性。测量过程中热线的温升与模拟计算结果吻合。此外,还建立了一个高达 600 K 的氦气热导率模型。这项工作中提供的数据以及之前公布的数据与模型计算结果非常吻合,平均绝对相对偏差 (AARD) 为 1.46%。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
A new transient hot-wire thermal conductivity apparatus and measurements of helium at temperatures from 20 K to 300 K

In this study, an apparatus based on the transient hot-wire method (THW) was designed to measure the thermal conductivity of cryogenic fluid within the temperature range of 20–300 K and the pressure range of 0–20 MPa, with a relative expanded uncertainty Ur(λ) of 0.0284 (k = 2, 95 %). The experimental data of methane, ethane, and carbon dioxide showed good consistency with the ECS model, validating the reliability of the apparatus. In addition to the linear temperature dependence of hot-wire resistance above 70 K, the nonlinear temperature dependence below 70 K is calibrated, and the feasibility of the THW method for measurements in the temperature range of 20–70 K is validated. Subsequently, the thermal conductivity data for helium are presented from 20 to 300 K. The temperature rises of hot-wire during the measurement agreed well with the simulation calculation results. Furthermore, a thermal conductivity model for helium gas up to 600 K was developed. The presented data in this work, as well as previously published data, demonstrated good agreement with the model calculation results, with an average absolute relative deviation (AARD) of 1.46 %.

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来源期刊
Journal of Chemical Thermodynamics
Journal of Chemical Thermodynamics 工程技术-热力学
CiteScore
5.60
自引率
15.40%
发文量
199
审稿时长
79 days
期刊介绍: The Journal of Chemical Thermodynamics exists primarily for dissemination of significant new knowledge in experimental equilibrium thermodynamics and transport properties of chemical systems. The defining attributes of The Journal are the quality and relevance of the papers published. The Journal publishes work relating to gases, liquids, solids, polymers, mixtures, solutions and interfaces. Studies on systems with variability, such as biological or bio-based materials, gas hydrates, among others, will also be considered provided these are well characterized and reproducible where possible. Experimental methods should be described in sufficient detail to allow critical assessment of the accuracy claimed. Authors are encouraged to provide physical or chemical interpretations of the results. Articles can contain modelling sections providing representations of data or molecular insights into the properties or transformations studied. Theoretical papers on chemical thermodynamics using molecular theory or modelling are also considered. The Journal welcomes review articles in the field of chemical thermodynamics but prospective authors should first consult one of the Editors concerning the suitability of the proposed review. Contributions of a routine nature or reporting on uncharacterised materials are not accepted.
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