{"title":"利用粉末冶金技术获得的含 3 wt.% W 和 0.1 wt.% Y 的 Ti2AlNb 合金的微观结构演变和力学性能","authors":"Youyu Li","doi":"10.1007/s11106-023-00394-1","DOIUrl":null,"url":null,"abstract":"<p>TiAl intermediate compound is an important material for high-temperature applications due to its superior creep resistance and oxidation resistance. It is suitable for high-pressure compressors and low-pressure turbine blades of advanced military aircraft engines. TiAl intermediate compound is an excellent substitute for nickel-based superalloys, as it can decrease weight by 40% and greatly enhance aircraft thrust-to-weight ratio. In this paper, the microstructure evolution and the mechanical properties of Ti<sub>2</sub>AlNb alloy with a 3.0 wt.% W and 0.1 wt.% Y addition obtained by blending elemental ultrafine powders was investigated by XRD, SEM-EDS, and mechanical testing device. The findings show that high relative density of 0.9945, and the excellent mechanical properties of Ti<sub>2</sub>AlNb–3W–0.1Y alloy can be obtained through isothermal sintering for 3 hour in a furnace with controllable argon atmosphere flow of 200 mL/min at 1,500°C. The alloy’s tensile strength, yield strength, and elongation reach 1,030 MPa, 913 MPa, and 15.1% at 700°C, respectively. Meanwhile, the 3 wt.% of element W is added to the alloy to form (TiW)C as the second strengthening phase, which is uniformly distributed in the matrix of Ti<sub>2</sub>AlNb. The addition of Y element at 0.1 wt.% into the alloy can act as an effective scavenger of oxygen and inhibit the unsatisfactory precipitation of the brittle α<sub>2</sub>-phase in the Ti<sub>2</sub>AlNb alloy. Compared to the alloy without additions, the Ti<sub>2</sub>AlNb alloy with 3 wt.% W and 0.1 wt.% Y demonstrated 13.5% and 19.35% improvements in the fracture resistance at 25°C and 700°C, respectively. The alloy’s yield strength was increased as well. The evolution regularity of the main metallography is (Ti<sub>2</sub>AlNb–TiAl–Ti<sub>3</sub>Al) → (Ti<sub>2</sub>AlNb–Ti<sub>3</sub>Al) → (Ti<sub>2</sub>AlNb–Ti<sub>3</sub>Al–(TiW) C) during the isothermal sintering of Ti–22Al–25Nb–3W–0.1Y alloy at 1,500°C. This study provides technical guidance for the preparation of ultrafine TiAl-based alloy powder and high-temperature aerospace applications</p>","PeriodicalId":742,"journal":{"name":"Powder Metallurgy and Metal Ceramics","volume":"62 5-6","pages":"302 - 311"},"PeriodicalIF":0.9000,"publicationDate":"2023-12-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Microstructural Evolution and Mechanical Properties of the Ti2AlNb Alloy with 3 wt.% W and 0.1 wt.% Y Obtained Using Powder Metallurgy Technique\",\"authors\":\"Youyu Li\",\"doi\":\"10.1007/s11106-023-00394-1\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>TiAl intermediate compound is an important material for high-temperature applications due to its superior creep resistance and oxidation resistance. It is suitable for high-pressure compressors and low-pressure turbine blades of advanced military aircraft engines. TiAl intermediate compound is an excellent substitute for nickel-based superalloys, as it can decrease weight by 40% and greatly enhance aircraft thrust-to-weight ratio. In this paper, the microstructure evolution and the mechanical properties of Ti<sub>2</sub>AlNb alloy with a 3.0 wt.% W and 0.1 wt.% Y addition obtained by blending elemental ultrafine powders was investigated by XRD, SEM-EDS, and mechanical testing device. The findings show that high relative density of 0.9945, and the excellent mechanical properties of Ti<sub>2</sub>AlNb–3W–0.1Y alloy can be obtained through isothermal sintering for 3 hour in a furnace with controllable argon atmosphere flow of 200 mL/min at 1,500°C. The alloy’s tensile strength, yield strength, and elongation reach 1,030 MPa, 913 MPa, and 15.1% at 700°C, respectively. Meanwhile, the 3 wt.% of element W is added to the alloy to form (TiW)C as the second strengthening phase, which is uniformly distributed in the matrix of Ti<sub>2</sub>AlNb. The addition of Y element at 0.1 wt.% into the alloy can act as an effective scavenger of oxygen and inhibit the unsatisfactory precipitation of the brittle α<sub>2</sub>-phase in the Ti<sub>2</sub>AlNb alloy. Compared to the alloy without additions, the Ti<sub>2</sub>AlNb alloy with 3 wt.% W and 0.1 wt.% Y demonstrated 13.5% and 19.35% improvements in the fracture resistance at 25°C and 700°C, respectively. The alloy’s yield strength was increased as well. The evolution regularity of the main metallography is (Ti<sub>2</sub>AlNb–TiAl–Ti<sub>3</sub>Al) → (Ti<sub>2</sub>AlNb–Ti<sub>3</sub>Al) → (Ti<sub>2</sub>AlNb–Ti<sub>3</sub>Al–(TiW) C) during the isothermal sintering of Ti–22Al–25Nb–3W–0.1Y alloy at 1,500°C. This study provides technical guidance for the preparation of ultrafine TiAl-based alloy powder and high-temperature aerospace applications</p>\",\"PeriodicalId\":742,\"journal\":{\"name\":\"Powder Metallurgy and Metal Ceramics\",\"volume\":\"62 5-6\",\"pages\":\"302 - 311\"},\"PeriodicalIF\":0.9000,\"publicationDate\":\"2023-12-22\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Powder Metallurgy and Metal Ceramics\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s11106-023-00394-1\",\"RegionNum\":4,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"MATERIALS SCIENCE, CERAMICS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Powder Metallurgy and Metal Ceramics","FirstCategoryId":"88","ListUrlMain":"https://link.springer.com/article/10.1007/s11106-023-00394-1","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"MATERIALS SCIENCE, CERAMICS","Score":null,"Total":0}
引用次数: 0
摘要
TiAl 中间化合物具有优异的抗蠕变性和抗氧化性,是一种重要的高温应用材料。它适用于先进军用飞机发动机的高压压缩机和低压涡轮叶片。TiAl 中间化合物是镍基超合金的绝佳替代品,因为它可以减轻 40% 的重量,大大提高飞机的推重比。本文通过 XRD、SEM-EDS 和机械测试装置研究了通过混合元素超细粉获得的添加 3.0 wt.% W 和 0.1 wt.% Y 的 Ti2AlNb 合金的微观结构演变和机械性能。研究结果表明,在氩气流量为 200 mL/min、温度为 1,500°C 的可控炉中等温烧结 3 小时后,Ti2AlNb-3W-0.1Y 合金可获得 0.9945 的高相对密度和优异的机械性能。在 700°C 时,合金的抗拉强度、屈服强度和伸长率分别达到 1,030 兆帕、913 兆帕和 15.1%。同时,在合金中加入 3 重量%的 W 元素,形成 (TiW)C 作为第二强化相,均匀地分布在 Ti2AlNb 的基体中。在合金中添加 0.1 重量%的 Y 元素可作为有效的氧清除剂,抑制 Ti2AlNb 合金中脆性 α2- 相的析出。与未添加的合金相比,添加了 3 wt.% W 和 0.1 wt.% Y 的 Ti2AlNb 合金在 25°C 和 700°C 时的抗断裂强度分别提高了 13.5% 和 19.35%。合金的屈服强度也有所提高。Ti-22Al-25Nb-3W-0.1Y 合金在 1,500°C 等温烧结过程中,主要金相组织的演变规律为 (Ti2AlNb-TiAl-Ti3Al) → (Ti2AlNb-Ti3Al) → (Ti2AlNb-Ti3Al-(TiW) C)。这项研究为制备超细 TiAl 基合金粉末和高温航空航天应用提供了技术指导
Microstructural Evolution and Mechanical Properties of the Ti2AlNb Alloy with 3 wt.% W and 0.1 wt.% Y Obtained Using Powder Metallurgy Technique
TiAl intermediate compound is an important material for high-temperature applications due to its superior creep resistance and oxidation resistance. It is suitable for high-pressure compressors and low-pressure turbine blades of advanced military aircraft engines. TiAl intermediate compound is an excellent substitute for nickel-based superalloys, as it can decrease weight by 40% and greatly enhance aircraft thrust-to-weight ratio. In this paper, the microstructure evolution and the mechanical properties of Ti2AlNb alloy with a 3.0 wt.% W and 0.1 wt.% Y addition obtained by blending elemental ultrafine powders was investigated by XRD, SEM-EDS, and mechanical testing device. The findings show that high relative density of 0.9945, and the excellent mechanical properties of Ti2AlNb–3W–0.1Y alloy can be obtained through isothermal sintering for 3 hour in a furnace with controllable argon atmosphere flow of 200 mL/min at 1,500°C. The alloy’s tensile strength, yield strength, and elongation reach 1,030 MPa, 913 MPa, and 15.1% at 700°C, respectively. Meanwhile, the 3 wt.% of element W is added to the alloy to form (TiW)C as the second strengthening phase, which is uniformly distributed in the matrix of Ti2AlNb. The addition of Y element at 0.1 wt.% into the alloy can act as an effective scavenger of oxygen and inhibit the unsatisfactory precipitation of the brittle α2-phase in the Ti2AlNb alloy. Compared to the alloy without additions, the Ti2AlNb alloy with 3 wt.% W and 0.1 wt.% Y demonstrated 13.5% and 19.35% improvements in the fracture resistance at 25°C and 700°C, respectively. The alloy’s yield strength was increased as well. The evolution regularity of the main metallography is (Ti2AlNb–TiAl–Ti3Al) → (Ti2AlNb–Ti3Al) → (Ti2AlNb–Ti3Al–(TiW) C) during the isothermal sintering of Ti–22Al–25Nb–3W–0.1Y alloy at 1,500°C. This study provides technical guidance for the preparation of ultrafine TiAl-based alloy powder and high-temperature aerospace applications
期刊介绍:
Powder Metallurgy and Metal Ceramics covers topics of the theory, manufacturing technology, and properties of powder; technology of forming processes; the technology of sintering, heat treatment, and thermo-chemical treatment; properties of sintered materials; and testing methods.