基于金管的碳氢化合物生成动力学研究进展

Yaoyu Li , Shixin Zhou , Jing Li , Zexiang Sun , Wenjun Pang
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摘要

金管热模拟实验是探索碳氢化合物源岩中碳氢化合物生成动力学的重要工具。与其他反应系统相比,金管内的反应环境和热解产物组成更接近实际地质条件,特别是对于脱烃能力较差的煤系烃源岩。角质层与各种热解产物密切接触,并在金管内相互反应。近年来,研究人员对基于金管的碳氢化合物生成动力学进行了广泛的研究和应用。但对这些研究缺乏系统全面的总结。本文从研究对象、影响因素、应用和问题等方面对近年来基于金管的动力学研究进行了综述。基于金管的碳氢化合物生成动力学研究的主要对象包括 CH4、C1-5、C8+ 等。阐明不同热解产物的动力学有助于理解有机物热解的机理。反应条件、矿物质和有机物结构都会影响碳氢化合物的生成动力学。弄清这些影响因素的作用,对于理解烃源岩的热解机理和碳氢化合物领域的热解研究具有重要意义。基于黄金管的碳氢化合物生成动力学研究具有良好的应用潜力,不仅可以确定研究区域碳氢化合物的生成历史,还可以研究天然气的成因、起源和储层形成模式。本文还总结了金管烃生成动力学的一些问题和解决方法,如样品的不均匀性、金管系统与自然条件的差异、石油二次裂解时间点的确定等。不断优化的解决方案增强了金管模拟实验的真实性。本综述旨在为基于金管研究烃源岩和烃的热解动力学提供理论基础和研究建议。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Research progress of hydrocarbon generation kinetics based on gold tube

Gold tube thermal simulation experiments represent a pivotal tool in exploring hydrocarbon generation kinetics in hydrocarbon source rocks. Compared to other reaction systems, the reaction environment and the pyrolysis product composition within the gold tube display a greater resemblance to actual geological conditions, especially for coal-based hydrocarbon rocks with poor hydrocarbon removal capacity. The kerogen is in close contact with various pyrolysis products and reacts with each other in the gold tube. Researchers have carried out extensive research and application in hydrocarbon generation kinetics based on gold tubes in recent years. But a systematic and comprehensive summary of these studies is lacking. This paper provides a review of the kinetic study based on golden tubes in recent years from the perspectives of research objects, influencing factors, applications and problems. The main targets of hydrocarbon generation kinetics based on gold tubes include CH4, C1-5, C8+ and so on. Elucidating the kinetics of diverse pyrolysis products aids comprehension of the mechanism of organic matter pyrolysis. Reaction condition, minerals and organic structure all influence hydrocarbon production kinetics. Clarifying the effects of these influencing factors is of great importance in understanding the pyrolysis mechanism of hydrocarbon source rocks and pyrolysis research in the domain of hydrocarbons. Golden tube-based kinetic studies of hydrocarbon production have good potential application, not only in determining the hydrocarbon generation history of hydrocarbons in the study area, but also in studying the genesis, origin, and reservoir formation mode of natural gas. This paper also summarizes some problems and solutions of the gold tube hydrocarbon generation kinetics, such as the inhomogeneity of the samples, the difference between the gold tube system and natural conditions, and the determination of the time point of oil secondary cracking. Continuous optimization of the solution enhances the authenticity of the golden tube simulation experiment. This review aims to offer a theoretical foundation and research suggestions for investigating pyrolysis kinetics of hydrocarbon source rocks and hydrocarbons based on golden tubes.

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