Qiang Meng , Yu Xiao , Jianglong Shi , Heng Zhao , Yan Liu , Yiqing Wang , Xiaomin Xie , Yaohui Xu
{"title":"中国鄂尔多斯盆地中东部奥陶系马家沟地层密潭-1 井天然气成因与来源","authors":"Qiang Meng , Yu Xiao , Jianglong Shi , Heng Zhao , Yan Liu , Yiqing Wang , Xiaomin Xie , Yaohui Xu","doi":"10.1016/j.jnggs.2023.12.001","DOIUrl":null,"url":null,"abstract":"<div><p>The Well Mitan-1 has achieved a major breakthrough in the exploration of Ordovician subsalt natural gas in the mid-eastern Ordos Basin, demonstrating a high-yield industrial gas flow in fourth member of the Majiagou Formation of Ordovician (O<sub>1</sub><em>m</em><sub>4</sub>). Despite this success, there are ongoing disputes regarding the origin of the natural gas found in Well Mitan-1. Measured results show that the natural gas in Well Mitan-1 is mainly composed of alkane gas (95.18 %). The gas drying coefficient (C<sub>1</sub>/C<sub>1-5</sub>) is measured at 0.947, and the H<sub>2</sub>S content is 3.49 %, with a small amount of N<sub>2</sub> and CO<sub>2</sub> in the non-hydrocarbon gas. The carbon isotopic compositions of methane, ethane, and propane in the natural gas are −45.5 ‰, −26.4 ‰, and −24.3 ‰, respectively. Based on the regional geological background, the characteristics of potential source rocks and the geochemical characteristics of natural gas, it is considered that the natural gas in Well Mitan-1 is self-generated and self-accumulated oil-associated gas in Ordovician subsalt carbonate rocks. However, certain geochemical anomalies, such as the lighter methane carbon isotope value (<em>δ</em><sup>13</sup>C<sub>1</sub>) and coal-type gas characteristics in ethane carbon isotope (<em>δ</em><sup>13</sup>C<sub>2</sub>), raise questions. Further insights from thermal simulation experiments on hydrocarbon generation and the analysis of residual gas in rocks suggest a close relationship between the special geochemical characteristics of Well Mitan-1 and the presence of gypsum rocks. The ubiquitous gypsum rock serves a dual purpose: acting as an effective caprock, facilitating the retention of early-generated natural gas, and promoting the generation of heavy hydrocarbon gases (C<sub>2+</sub>) and H<sub>2</sub>S. The relatively low H<sub>2</sub>S content (less than 5 %) and higher C<sub>2+</sub> content indicate that thermochemical sulfate reduction (TSR), if present, is not strong enough to significantly impact methane. The <em>δ</em><sup>13</sup>C<sub>2</sub> is identified as a potentially sensitive parameter for identifying TSR.</p></div>","PeriodicalId":100808,"journal":{"name":"Journal of Natural Gas Geoscience","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2024-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2468256X23000779/pdfft?md5=a464f79b1c6ee6243f72a630ee2b4016&pid=1-s2.0-S2468256X23000779-main.pdf","citationCount":"0","resultStr":"{\"title\":\"Genesis and source of natural gas in Well Mitan-1 of Ordovician Majiagou Formation, middle-eastern Ordos Basin, China\",\"authors\":\"Qiang Meng , Yu Xiao , Jianglong Shi , Heng Zhao , Yan Liu , Yiqing Wang , Xiaomin Xie , Yaohui Xu\",\"doi\":\"10.1016/j.jnggs.2023.12.001\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The Well Mitan-1 has achieved a major breakthrough in the exploration of Ordovician subsalt natural gas in the mid-eastern Ordos Basin, demonstrating a high-yield industrial gas flow in fourth member of the Majiagou Formation of Ordovician (O<sub>1</sub><em>m</em><sub>4</sub>). Despite this success, there are ongoing disputes regarding the origin of the natural gas found in Well Mitan-1. Measured results show that the natural gas in Well Mitan-1 is mainly composed of alkane gas (95.18 %). The gas drying coefficient (C<sub>1</sub>/C<sub>1-5</sub>) is measured at 0.947, and the H<sub>2</sub>S content is 3.49 %, with a small amount of N<sub>2</sub> and CO<sub>2</sub> in the non-hydrocarbon gas. The carbon isotopic compositions of methane, ethane, and propane in the natural gas are −45.5 ‰, −26.4 ‰, and −24.3 ‰, respectively. Based on the regional geological background, the characteristics of potential source rocks and the geochemical characteristics of natural gas, it is considered that the natural gas in Well Mitan-1 is self-generated and self-accumulated oil-associated gas in Ordovician subsalt carbonate rocks. However, certain geochemical anomalies, such as the lighter methane carbon isotope value (<em>δ</em><sup>13</sup>C<sub>1</sub>) and coal-type gas characteristics in ethane carbon isotope (<em>δ</em><sup>13</sup>C<sub>2</sub>), raise questions. Further insights from thermal simulation experiments on hydrocarbon generation and the analysis of residual gas in rocks suggest a close relationship between the special geochemical characteristics of Well Mitan-1 and the presence of gypsum rocks. The ubiquitous gypsum rock serves a dual purpose: acting as an effective caprock, facilitating the retention of early-generated natural gas, and promoting the generation of heavy hydrocarbon gases (C<sub>2+</sub>) and H<sub>2</sub>S. The relatively low H<sub>2</sub>S content (less than 5 %) and higher C<sub>2+</sub> content indicate that thermochemical sulfate reduction (TSR), if present, is not strong enough to significantly impact methane. The <em>δ</em><sup>13</sup>C<sub>2</sub> is identified as a potentially sensitive parameter for identifying TSR.</p></div>\",\"PeriodicalId\":100808,\"journal\":{\"name\":\"Journal of Natural Gas Geoscience\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2024-02-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.sciencedirect.com/science/article/pii/S2468256X23000779/pdfft?md5=a464f79b1c6ee6243f72a630ee2b4016&pid=1-s2.0-S2468256X23000779-main.pdf\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Natural Gas Geoscience\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2468256X23000779\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Natural Gas Geoscience","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2468256X23000779","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Genesis and source of natural gas in Well Mitan-1 of Ordovician Majiagou Formation, middle-eastern Ordos Basin, China
The Well Mitan-1 has achieved a major breakthrough in the exploration of Ordovician subsalt natural gas in the mid-eastern Ordos Basin, demonstrating a high-yield industrial gas flow in fourth member of the Majiagou Formation of Ordovician (O1m4). Despite this success, there are ongoing disputes regarding the origin of the natural gas found in Well Mitan-1. Measured results show that the natural gas in Well Mitan-1 is mainly composed of alkane gas (95.18 %). The gas drying coefficient (C1/C1-5) is measured at 0.947, and the H2S content is 3.49 %, with a small amount of N2 and CO2 in the non-hydrocarbon gas. The carbon isotopic compositions of methane, ethane, and propane in the natural gas are −45.5 ‰, −26.4 ‰, and −24.3 ‰, respectively. Based on the regional geological background, the characteristics of potential source rocks and the geochemical characteristics of natural gas, it is considered that the natural gas in Well Mitan-1 is self-generated and self-accumulated oil-associated gas in Ordovician subsalt carbonate rocks. However, certain geochemical anomalies, such as the lighter methane carbon isotope value (δ13C1) and coal-type gas characteristics in ethane carbon isotope (δ13C2), raise questions. Further insights from thermal simulation experiments on hydrocarbon generation and the analysis of residual gas in rocks suggest a close relationship between the special geochemical characteristics of Well Mitan-1 and the presence of gypsum rocks. The ubiquitous gypsum rock serves a dual purpose: acting as an effective caprock, facilitating the retention of early-generated natural gas, and promoting the generation of heavy hydrocarbon gases (C2+) and H2S. The relatively low H2S content (less than 5 %) and higher C2+ content indicate that thermochemical sulfate reduction (TSR), if present, is not strong enough to significantly impact methane. The δ13C2 is identified as a potentially sensitive parameter for identifying TSR.
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