乙醇、鼠李糖脂和 Triton X-165 水溶液对石英表面张力的润湿性能

IF 2.5 Q3 CHEMISTRY, PHYSICAL
A. Zdziennicka, K. Szymczyk, B. Jańczuk
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引用次数: 0

摘要

不同液体和溶液对石英的润湿性在实际应用中起着非常重要的作用。因此,研究了乙醇(ET)、鼠李糖脂(RL)和 Triton X-165 (TX165)水溶液对石英表面张力的润湿行为。研究基于水 (W)、甲酰胺 (F) 和二碘甲烷 (D) 以及 ET、RL 和 TX165 溶液在石英表面的接触角测量。所获得的 W、F 和 D 的接触角结果被用于确定石英表面张力及其成分和参数,并采用了不同的方法,而所获得的 ET、RL 和 TX165 水溶液的结果则考虑了它们在石英-空气、石英-溶液和溶液-空气界面上的吸附情况,以及溶液在石英-溶液界面上的相互作用。根据石英表面张力的成分和参数,考虑了不同界面上溶液成分的接触角和吸附之间的关系。除其他外,我们还可以利用这些参数确定溶液各组分在界面上的吸附机理以及吸附的标准吉布斯表面自由能。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Wettability of Quartz by Ethanol, Rhamnolipid and Triton X-165 Aqueous Solutions with Regard to Its Surface Tension
The wettability of quartz by different liquids and solutions plays a very important role in practical applications. Hence, the wetting behaviour of ethanol (ET), rhamnolipid (RL) and Triton X-165 (TX165) aqueous solutions with regard to the quartz surface tension was investigated. The investigations were based on the contact angle measurements of water (W), formamide (F) and diiodomethane (D) as well as ET, RL and TX165 solutions on the quartz surface. The obtained results of the contact angle for W, F and D were used for the determination of quartz surface tension as well as its components and parameters using different approaches, whereas the results obtained for the aqueous solution of ET, RL and TX165 were considered with regard to their adsorption at the quartz–air, quartz–solution and solution–air interfaces as well as the solution interactions across the quartz–solution interface. The considerations of the relations between the contact angle and adsorption of solution components at different interfaces were based on the components and parameters of the quartz surface tension. They allow us to, among other things, establish the mechanism of the adsorption of individual components of the solution at the interfaces and standard Gibbs surface free energy of this adsorption.
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来源期刊
Colloids and Interfaces
Colloids and Interfaces CHEMISTRY, PHYSICAL-
CiteScore
3.90
自引率
4.20%
发文量
64
审稿时长
10 weeks
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