钴铁氧体催化分子氧氧化苄醇

Q4 Earth and Planetary Sciences
R. Changwal, R. Ameta, S. Ameta
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引用次数: 0

摘要

将醇氧化成醛/酮/羧酸是有机合成的关键步骤。通常情况下,强氧化剂会将醇氧化成羧酸,这一反应可能会也可能不会在形成醛和酮的中间步骤中停止。在这一阶段,需要一些温和的氧化剂来阻止反应。在这里,分子氧可以帮助实现这一目标,但使用分子氧作为氧化剂有其缺点,因为它的氧化速度较慢。因此,这种反应可以由金属铁氧体催化。这些金属铁氧体很容易用外部磁铁分离,而且可以循环使用。钴铁氧体已被用于将苯甲醇氧化成相应的苯甲醛。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Oxidation of benzyl alcohols by molecular oxygen catalyzed by cobalt ferrite
Oxidation of alcohols to aldehydes/ketones/carboxylic acids is a crucial step in organic synthesis. Normally, strong oxidants oxidize alcohol to carboxylic acid and this reaction may or may not stop at the intermediate steps to form aldehyde and ketone. Some mild oxidants are required to stop it here at this stage. Here, molecular oxygen can help in achieving this objective, but there is a disadvantage to use molecular oxygen as an oxidant as it has a slow rate of oxidation. Hence, such a reaction may be catalyzed by metal ferrites. These metal ferrites are easy to separate by using an external magnet and can be recycled. Cobalt ferrite has been used for the oxidation of benzyl alcohols to corresponding benzaldehydes.
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来源期刊
CiteScore
0.50
自引率
0.00%
发文量
195
审稿时长
4-8 weeks
期刊介绍: Information not localized
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