Henrik-Christian Graichen, G. Boye, Jörg Sauerhering, Florian Köhler, Frank Beyrau
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Furthermore, this study experimentally clarifies to which extent the application of polymer mini-channel cold plates between battery cells is suitable to delay TR by heat dissipation and to prevent thermal runaway propagation (TRP) to adjacent cells by simultaneously acting as a thermal barrier. NMC pouch cells of 12.5 Ah capacity were overcharged at 1 C to induce TR. Without cold plates, TR and TRP occurred within one hour. Utilizing the polymer mini-channel cold plates for face cooling, the overcharge did not produce a condition leading to cell fire in the same time frame. When the fluid inlet temperature was varied between 5 and 40 °C, the overcharged cell’s surface temperature peaked between 50 and 60 °C. Indications were found that thermal conditioning with the polymer cold plates significantly slowed down parts of the process chain before cell firing. Their peak performance was measured to be just under 2.2 kW/m2. 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引用次数: 0
摘要
锂离子电池在比能量、成本和使用寿命等方面都具有合适的特性,因此被广泛应用于移动应用中。然而,锂离子电池有可能发生热失控(TR),因此需要采取安全措施和强化热管理来预防和控制这种失控。本研究介绍了一种新型热管理和安全组合应用,该应用专为大纵横比电池电池(如袋装电池和薄棱柱电池)而设计。它包括基于聚合物的微型通道冷板,可间接对电池表面进行液体热调节。它们重量轻、节省空间,适用于移动系统。此外,本研究还通过实验阐明了在电池单元之间应用聚合物微型通道冷板在多大程度上适合通过散热延迟 TR,以及通过同时充当热屏障防止热失控传播(TRP)到相邻电池单元。将容量为 12.5 Ah 的 NMC 袋装电池在 1 C 下过量充电,以诱发 TR。在没有冷板的情况下,TR 和 TRP 在一小时内发生。使用聚合物微型通道冷板进行表面冷却时,过充电不会在相同的时间内导致电池起火。当流体入口温度在 5 至 40 °C 之间变化时,过充电池的表面温度在 50 至 60 °C 之间达到峰值。有迹象表明,使用聚合物冷板进行热调节大大减缓了电池点火前的部分工艺链。据测量,其峰值性能略低于 2.2 kW/m2。此外,还对热管理系统故障进行了测试,结果表明聚合物冷板防止了相邻电池的 TRP。总之,由聚合物微型通道冷板组成的热管理和安全组合系统为锂电池系统提供了必要的与 TR 相关的安全方面,值得进一步研究。
The Impact of a Combined Battery Thermal Management and Safety System Utilizing Polymer Mini-Channel Cold Plates on the Thermal Runaway and Its Propagation
Lithium-ion batteries are widely used in mobile applications because they offer a suitable package of characteristics in terms of specific energy, cost, and life span. Nevertheless, they have the potential to experience thermal runaway (TR), the prevention and containment of which require safety measures and intensive thermal management. This study introduces a novel combined thermal management and safety application designed for large aspect-ratio battery cells such as pouches and thin prismatics. It comprises polymer-based mini-channel cold plates that can indirectly thermally condition the batteries’ faces with liquid. They are lightweight and space-saving, making them suitable for mobile systems. Furthermore, this study experimentally clarifies to which extent the application of polymer mini-channel cold plates between battery cells is suitable to delay TR by heat dissipation and to prevent thermal runaway propagation (TRP) to adjacent cells by simultaneously acting as a thermal barrier. NMC pouch cells of 12.5 Ah capacity were overcharged at 1 C to induce TR. Without cold plates, TR and TRP occurred within one hour. Utilizing the polymer mini-channel cold plates for face cooling, the overcharge did not produce a condition leading to cell fire in the same time frame. When the fluid inlet temperature was varied between 5 and 40 °C, the overcharged cell’s surface temperature peaked between 50 and 60 °C. Indications were found that thermal conditioning with the polymer cold plates significantly slowed down parts of the process chain before cell firing. Their peak performance was measured to be just under 2.2 kW/m2. In addition, thermal management system malfunction was tested, and evidence was found that the polymer cold plates prevented TRP to adjacent cells. In conclusion, a combined thermal management and safety system made of polymer mini-channel cold plates provides necessary TR-related safety aspects in lithium battery systems and should be further investigated.