利用阿尔伯塔油砂沥青在微波等离子体辅助下制造碳纤维

C Pub Date : 2023-12-22 DOI:10.3390/c10010001
Lin Ge, Sharath Chandra, Talha Zafar, Simon S. Park
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引用次数: 0

摘要

与碳纤维(CF)生产相关的巨额费用限制了其在各行各业的广泛应用,这主要是由于前驱体材料的成本和能源密集型后处理程序造成的。本研究探讨了利用阿尔伯塔油砂沥青质(AOAs)(一种从油砂开采中提取的富碳副产品)作为更具成本效益的碳纤维生产前体的可能性。聚苯乙烯和聚(苯乙烯-丁二烯-苯乙烯)也被用作聚合物添加剂。除了传统的热后处理外,碳化过程还采用了微波等离子体。对通过这种方法生成的 CF 进行了综合分析,包括扫描电镜、傅立叶变换红外光谱、热重分析、X 射线衍射和拉曼光谱。在使用传统热后处理时,AOA 碳纤维的最佳拉伸强度和杨氏模量分别为 600 兆帕和 70 千兆帕。微波等离子体工艺温度较高,有望消除 AOA 碳纤维的杂原子。微波等离子体建模温度是通过 COMSOLTM 设置的,建模温度和检测温度分别为 1600 K 和 1568 K。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Manufacturing Carbon Fiber Using Alberta Oilsands Asphaltene with Microwave Plasma Assistance
The considerable expenses associated with carbon fiber (CF) production have imposed limitations on its widespread application across diverse industries, primarily due to the costs of precursor materials and energy−intensive post−treatment procedures. This research explores the potential utilization of Alberta oilsands asphaltenes (AOAs), a carbon−rich by−product derived from oilsands extraction, as a more cost−effective precursor for CF production. Polystyrene and poly(styrene–butadiene–styrene) were also used as polymer additives. In addition to conventional thermal post−treatment, microwave plasma was employed for the carbonization process. The CFs generated through this approach were subjected to a comprehensive analysis involving SEM, FTIR, TGA, XRD, and Raman spectroscopy. The best tensile strength and Young’s modulus of the AOA carbon fibers when using conventional thermal post−treatment were 600 MPa and 70 GPa, respectively. The microwave plasma process indicates the higher temperature and promise of eliminating heteroatoms of AOA carbon fibers. The temperature for microwave plasma modelling was set using COMSOLTM, with the modelling temperature and detection temperature being established at 1600 K and 1568 K, respectively.
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