S. Y. Misyura, A. V. Bilsky, V. S. Morozov, M. N. Ryabov, O. A. Gobyzov
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At <span>\\(C_{0}= 65\\)</span>% and <span>\\(C_{0}= 90\\)</span>%, the average temperature <span>\\(T_{\\rm S}\\)</span> on the free surface of droplet changed during polymerization by 2.8C° and 3.7°C, respectively. After polymerization, <span>\\(T_{\\rm S}\\)</span> for the hydrogel became higher than <span>\\(T_{\\rm S }\\)</span> of droplet of pure water. The average velocity of motion of polyamide particles <span>\\(U_{C}\\)</span> for water was 2.2–2.4 times higher than that for the PEGDA solution with the initial concentration <span>\\(C_{0} = 65\\)</span>%, which is associated with the higher viscosity of the solution. At the onset of polymerization, the velocity <span>\\(U_{C}\\)</span>dropped to 0 mm/s in a very short time. With increase in the concentration <span>\\(C_{0}\\)</span> in the pre-polymer, the time of polymerization reaction start decreased significantly, which shortened the time in which the particles stopped completely. Different limiting factors govern evaporation of a water droplet and a hydrogel droplet. The evaporation rate of droplet of hydrogel decreased with time due to the porous structure of the hydrogel.</p>","PeriodicalId":627,"journal":{"name":"Journal of Engineering Thermophysics","volume":"32 4","pages":"702 - 713"},"PeriodicalIF":1.3000,"publicationDate":"2023-12-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Polymerization in Droplet of Aqueous Solution of PEGDA/Irgacure at Various Concentrations of Components\",\"authors\":\"S. Y. Misyura, A. V. Bilsky, V. S. Morozov, M. N. Ryabov, O. A. Gobyzov\",\"doi\":\"10.1134/S1810232823040057\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>The authors experimentally studied the behavior of evaporation, convection in the liquid, and temperature of the free surface of a pendant droplet of aqueous solution of PEGDA/Irgacure 2959 before and after the onset of polymerization under UV radiation. Data on the temperature of the free surface of droplet were obtained for a wide range of the initial concentration of the polymer base <span>\\\\(C_{0}\\\\)</span>. For <span>\\\\(C_{0}= 35\\\\)</span>% and less, no polymerization area was observed (according to thermal images). The temperature gradients observed over the droplet surface were very low (less than 0.3°C). At <span>\\\\(C_{0}= 65\\\\)</span>% and <span>\\\\(C_{0}= 90\\\\)</span>%, the average temperature <span>\\\\(T_{\\\\rm S}\\\\)</span> on the free surface of droplet changed during polymerization by 2.8C° and 3.7°C, respectively. 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引用次数: 0
摘要
摘要实验研究了PEGDA/Irgacure 2959水溶液在紫外辐射下发生聚合前后的蒸发行为、液相对流行为和自由表面温度。在聚合物基的初始浓度\(C_{0}\)范围内,得到了液滴自由表面的温度数据。因为\(C_{0}= 35\)% and less, no polymerization area was observed (according to thermal images). The temperature gradients observed over the droplet surface were very low (less than 0.3°C). At \(C_{0}= 65\)% and \(C_{0}= 90\)%, the average temperature \(T_{\rm S}\) on the free surface of droplet changed during polymerization by 2.8C° and 3.7°C, respectively. After polymerization, \(T_{\rm S}\) for the hydrogel became higher than \(T_{\rm S }\) of droplet of pure water. The average velocity of motion of polyamide particles \(U_{C}\) for water was 2.2–2.4 times higher than that for the PEGDA solution with the initial concentration \(C_{0} = 65\)%, which is associated with the higher viscosity of the solution. At the onset of polymerization, the velocity \(U_{C}\)dropped to 0 mm/s in a very short time. With increase in the concentration \(C_{0}\) in the pre-polymer, the time of polymerization reaction start decreased significantly, which shortened the time in which the particles stopped completely. Different limiting factors govern evaporation of a water droplet and a hydrogel droplet. The evaporation rate of droplet of hydrogel decreased with time due to the porous structure of the hydrogel.
Polymerization in Droplet of Aqueous Solution of PEGDA/Irgacure at Various Concentrations of Components
The authors experimentally studied the behavior of evaporation, convection in the liquid, and temperature of the free surface of a pendant droplet of aqueous solution of PEGDA/Irgacure 2959 before and after the onset of polymerization under UV radiation. Data on the temperature of the free surface of droplet were obtained for a wide range of the initial concentration of the polymer base \(C_{0}\). For \(C_{0}= 35\)% and less, no polymerization area was observed (according to thermal images). The temperature gradients observed over the droplet surface were very low (less than 0.3°C). At \(C_{0}= 65\)% and \(C_{0}= 90\)%, the average temperature \(T_{\rm S}\) on the free surface of droplet changed during polymerization by 2.8C° and 3.7°C, respectively. After polymerization, \(T_{\rm S}\) for the hydrogel became higher than \(T_{\rm S }\) of droplet of pure water. The average velocity of motion of polyamide particles \(U_{C}\) for water was 2.2–2.4 times higher than that for the PEGDA solution with the initial concentration \(C_{0} = 65\)%, which is associated with the higher viscosity of the solution. At the onset of polymerization, the velocity \(U_{C}\)dropped to 0 mm/s in a very short time. With increase in the concentration \(C_{0}\) in the pre-polymer, the time of polymerization reaction start decreased significantly, which shortened the time in which the particles stopped completely. Different limiting factors govern evaporation of a water droplet and a hydrogel droplet. The evaporation rate of droplet of hydrogel decreased with time due to the porous structure of the hydrogel.
期刊介绍:
Journal of Engineering Thermophysics is an international peer reviewed journal that publishes original articles. The journal welcomes original articles on thermophysics from all countries in the English language. The journal focuses on experimental work, theory, analysis, and computational studies for better understanding of engineering and environmental aspects of thermophysics. The editorial board encourages the authors to submit papers with emphasis on new scientific aspects in experimental and visualization techniques, mathematical models of thermophysical process, energy, and environmental applications. Journal of Engineering Thermophysics covers all subject matter related to thermophysics, including heat and mass transfer, multiphase flow, conduction, radiation, combustion, thermo-gas dynamics, rarefied gas flow, environmental protection in power engineering, and many others.