铁素体不锈钢互连器件上的 Co-WO3 复合涂层

Xueqi Zhao, Shujiang Geng, Gang Chen, Fuihui Wang
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引用次数: 0

摘要

为了在用于固体氧化物燃料电池(SOFC)互连器件的 SUS 430 钢互连器件上涂覆 Co-WO3 复合涂层,采用了电泳和电镀相结合的方法,然后在 800 ℃ 的环境温度下进行长达 5 周的热能暴露。氧化鳞片的热生长呈现三层结构,内层为 Cr2O3 层,中间为 CoWO4 层,外层为(Co,Fe)3O4 和 Co3O4 层。Co-WO3 涂层产生的氧化物层不仅能阻止 Cr2O3 的发展和 Cr 物种的向外迁移,还能增强表面鳞片的电气性能。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Co-WO3 composite coating on ferritic stainless steel interconnects

In order to apply Co-WO3 composite coating to SUS 430 steel interconnects for solid oxide fuel cell (SOFC) interconnects, a combination of electrophoresis and electroplating is used, followed by thermal energy exposure to ambient temperature at 800 ℃ for up to 5 weeks. The thermal growth of the oxide scale displays a tri-layer structure with a Cr2O3 layer in the inner part, a CoWO4 layer in the middle and (Co,Fe)3O4 and Co3O4 layer in the outer part. Co-WO3 coating produces an oxide layer that not only prevents Cr2O3 development and outward transport of Cr species but also enhances the electrical behavior of the surface scale.

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