单氟烷基和多氟烷基物质在风化光非水相液体中的分配

IF 1.8 4区 环境科学与生态学 Q3 WATER RESOURCES
Yida Fang, Stephanie Fiorenza, Charles Schaefer, Kevin Molloy, Chris Gurr
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引用次数: 0

摘要

在使用水成膜泡沫(AFFF)扑灭高温石油火灾的场所,全氟烷基和多氟烷基物质(PFAS)和风化的石油碳氢化合物可能是共污染物。在这里,我们报告了6种PFAS在水和风化的柴油和汽油范围的碳氢轻非水相液体(LNAPL)之间的分配,这些液体是从一家退役炼油厂的地下收集的。结果表明,PFAS的结构特征和LNAPL的特性都对PFAS划分到LNAPL的大小有显著影响。本研究测量的PFOA和PFOS对风化LNAPL的lnal -水分配系数(Kl)比其他研究计算的分配给单组分、未风化nal的Kl值大近10倍或10倍以上,表明使用单组分napl评估lnal -水分配研究的实验室研究在很大程度上低估了污染AFFF站点预计遇到的Kl。与LNAPL的相互作用可能是PFAS命运和运输的重要控制因素,本工作估计的Kl值表明LNAPL可能是PFAS在野外的重要运输汇。本研究的结果表明,PFAS向风化LNAPL的分配是设计补救策略时需要考虑的重要过程,特别是那些包含监测的自然衰减或自然源带枯竭的补救策略。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Partitioning of Per- and Polyfluoroalkyl Substances to Weathered Light Non-Aqueous Phase Liquid

Per- and polyfluoroalkyl substances (PFAS) and weathered petroleum hydrocarbons can be co-contaminants at sites where aqueous film-forming foam (AFFF) was used to extinguish high-temperature petroleum fires. Here, we report on the partitioning of six PFAS between water and a weathered diesel and gasoline range hydrocarbon light non-aqueous phase liquid (LNAPL) collected from the subsurface of a decommissioned refinery. Results showed that both the structural features of PFAS and the characteristics of LNAPL exhibited significant impacts on the magnitude of PFAS partitioned to the LNAPL. The LNAPL–water partition coefficients (Kl) of PFOA and PFOS to the weathered LNAPL measured in this work were nearly or more than 10 times greater than Kl values calculated by others for partitioning to single-component, unweathered NAPLs, indicating that laboratory studies evaluating LNAPL–water partitioning studies using single component NAPLs can largely underestimate the Kl expected to be encountered at contaminated AFFF sites. Interactions with LNAPL can be important controllers of PFAS fate and transport, and the Kl values estimated in this work suggest that LNAPL could be a significant transport sink for PFAS in the field. Results from this work suggest that PFAS partitioning to weathered LNAPL is an important process to be considered when designing remedial strategies, particularly those incorporating monitored natural attenuation or natural source zone depletion.

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来源期刊
CiteScore
3.30
自引率
10.50%
发文量
60
审稿时长
>36 weeks
期刊介绍: Since its inception in 1981, Groundwater Monitoring & Remediation® has been a resource for researchers and practitioners in the field. It is a quarterly journal that offers the best in application oriented, peer-reviewed papers together with insightful articles from the practitioner''s perspective. Each issue features papers containing cutting-edge information on treatment technology, columns by industry experts, news briefs, and equipment news. GWMR plays a unique role in advancing the practice of the groundwater monitoring and remediation field by providing forward-thinking research with practical solutions.
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