硼酸锌Zn6B22O39·H2O的合成及晶体结构

Zeitschrift für Naturforschung B Pub Date : 2023-11-17 DOI:10.1515/znb-2023-0089

Raimund Ziegler, Hubert Huppertz

{"title":"硼酸锌Zn6B22O39·H2O的合成及晶体结构","authors":"Raimund Ziegler, Hubert Huppertz","doi":"10.1515/znb-2023-0089","DOIUrl":null,"url":null,"abstract":"The synthesis and crystal structure of Zn6B22O39·H2O are described. This new zinc borate was synthesized at 7 GPa and 1523 K in a multianvil device. It crystallizes in the orthorhombic space group Pnma (no. 62) with the lattice parameters a = 818.77(4), b = 768.42(3), c = 1744.82(9) pm, V = 1.09777(9) nm3, and two formula units per unit cell (Z = 2). The structure is closely related to those of M 6B22O39·H2O (M = Fe, Co, Ni, Cd) and features non-planar (BO3) units as demonstrated by single-crystal and powder X-ray diffraction techniques.","PeriodicalId":23831,"journal":{"name":"Zeitschrift für Naturforschung B","volume":"27 5","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2023-11-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis and crystal structure of the zinc borate Zn6B22O39·H2O\",\"authors\":\"Raimund Ziegler, Hubert Huppertz\",\"doi\":\"10.1515/znb-2023-0089\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The synthesis and crystal structure of Zn6B22O39·H2O are described. This new zinc borate was synthesized at 7 GPa and 1523 K in a multianvil device. It crystallizes in the orthorhombic space group Pnma (no. 62) with the lattice parameters a = 818.77(4), b = 768.42(3), c = 1744.82(9) pm, V = 1.09777(9) nm3, and two formula units per unit cell (Z = 2). The structure is closely related to those of M 6B22O39·H2O (M = Fe, Co, Ni, Cd) and features non-planar (BO3) units as demonstrated by single-crystal and powder X-ray diffraction techniques.\",\"PeriodicalId\":23831,\"journal\":{\"name\":\"Zeitschrift für Naturforschung B\",\"volume\":\"27 5\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2023-11-17\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Zeitschrift für Naturforschung B\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1515/znb-2023-0089\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Zeitschrift für Naturforschung B","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1515/znb-2023-0089","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}

引用次数: 0

摘要

介绍了Zn6B22O39·H2O的合成及晶体结构。在多砧装置中，在7 GPa和1523 K下合成了新型硼酸锌。它在正交空间群Pnma (no。晶格参数a = 818.77(4)， b = 768.42(3)， c = 1744.82(9) pm, V = 1.09777(9) nm3，单位晶胞两个公式单位(Z = 2)。结构与M 6B22O39·H2O (M = Fe, Co, Ni, Cd)密切相关，单晶和粉末x射线衍射技术证明其具有非平面(BO3)单元。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

查看原文本刊更多论文

Synthesis and crystal structure of the zinc borate Zn6B22O39·H2O

The synthesis and crystal structure of Zn6B22O39·H2O are described. This new zinc borate was synthesized at 7 GPa and 1523 K in a multianvil device. It crystallizes in the orthorhombic space group Pnma (no. 62) with the lattice parameters a = 818.77(4), b = 768.42(3), c = 1744.82(9) pm, V = 1.09777(9) nm3, and two formula units per unit cell (Z = 2). The structure is closely related to those of M 6B22O39·H2O (M = Fe, Co, Ni, Cd) and features non-planar (BO3) units as demonstrated by single-crystal and powder X-ray diffraction techniques.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Zeitschrift für Naturforschung B

自引率

0.00%

发文量