V. D. Brovchenko, I. A. Kirillina, M. A. Yudovskaya, G. Costin, I. V. Pshenitsyn, E. V. Kovalchuk, Yu. O. Larionova, Yu. D. Gritsenko, A. A. Ketrov, S. F. Sluzhenikin
{"title":"Norilsk地区Imangda岩群Rudnaya岩脉铜硫化物矿化与高镍橄榄石来源:基于成分、同位素和模型数据","authors":"V. D. Brovchenko, I. A. Kirillina, M. A. Yudovskaya, G. Costin, I. V. Pshenitsyn, E. V. Kovalchuk, Yu. O. Larionova, Yu. D. Gritsenko, A. A. Ketrov, S. F. Sluzhenikin","doi":"10.1134/S086959112306005X","DOIUrl":null,"url":null,"abstract":"<div><p>The Rudnaya dyke of the Imangda ore cluster is composed of weakly differentiated olivine-bearing to olivine gabbrodolerites with globular and interstitial sulfides of a chalcopyrite–cubanite- (pentlandite-pyrrhotite) composition. Along with sulfide mineralization, gabbrodolerites of the dyke contain xenoliths of hornfelsed basalts, abundant amygdales and rare grains of zoned olivine-1 <i>Fo</i><sub>90–47</sub> that coexists with subhedral olivine <i>Fo</i><sub>74–36</sub> of the second generation. Modeling with the COMAGMAT and alphaMELTS programs showed that high-Mg <i>Ol</i>-1 with Cr-spinel inclusions cannot be crystallized from a Fe-enriched tholeiitic melt with 4.8–7.3 wt % MgO and 11.6–16.7 wt % total Fe<sub>2</sub>O<sub>3</sub> that is parental for the dyke. The variation trend and high Ni up to 0.5 wt % NiO in the cores of xenocrystic olivine <i>Fo</i><sub>90–76</sub> in contrast to maximum <i>Fo</i><sub>83</sub> and 0.4 wt % NiO in olivine from the ore-bearing intrusions and picritic basalts of the Norilsk region point toward the presence of deep-seated cumulates of picritic magmas, which had not exchanged with sulfide liquid. Platinum group element (PGE) abundances increase (up to 2.2 ppm) with increasing Cu/Ni in the whole rocks and proportions of pentlandite in a sulfide association. A specific pattern of chalcophile metal distribution with Ni, Os and Ir minima, elevated Cu/Ni (5–15) and Cu/Pd (3200–10 900) along with lower PGE tenor (PGE content in 100% sulfide) of sulfides (2–65 ppm) and Pd content in pentlandite (<175 ppm) compared to those of the ore-bearing intrusions suggest that cuprous sulfide mineralization was not physically captured from highly fractionated sulfide fractions of ore-bearing magmas but is cogenetic with a magma of the dyke. Sulfide saturation, near-simultaneous with fluid saturation and degassing, was achieved in the dyke conduit due to assimilation of sedimentary sulfur and volatiles from Devonian evaporites that is supported by the heavy S isotope composition of dyke’s sulfides with the average δ<sup>34</sup>S = 14.7 ±1.1‰ (<i>n</i> = 31) close to the values for sulfides from the endocontact zones of the Imangda ore-bearing intrusions hosted by the Devonian sequences. The initial isotopic characteristics of dyke rocks (Sr<sub>i</sub> 0.70517–0.70532, ɛNd from –0.4 to 0.8) imply its comagmatic origin with the Norilsk-type intrusions whereas the overall data do not exclude its spatial connection with an upper crustal conduit network of the ore-bearing magmas.</p></div>","PeriodicalId":20026,"journal":{"name":"Petrology","volume":"31 6","pages":"624 - 647"},"PeriodicalIF":1.0000,"publicationDate":"2023-11-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Sources of Cuprous Sulfide Mineralization and High-Ni Olivine of the Rudnaya Dyke (Imangda Cluster, Norilsk region): Based on Compositional, Isotope and Model Data\",\"authors\":\"V. D. Brovchenko, I. A. Kirillina, M. A. Yudovskaya, G. Costin, I. V. Pshenitsyn, E. V. Kovalchuk, Yu. O. Larionova, Yu. D. Gritsenko, A. A. Ketrov, S. F. Sluzhenikin\",\"doi\":\"10.1134/S086959112306005X\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The Rudnaya dyke of the Imangda ore cluster is composed of weakly differentiated olivine-bearing to olivine gabbrodolerites with globular and interstitial sulfides of a chalcopyrite–cubanite- (pentlandite-pyrrhotite) composition. Along with sulfide mineralization, gabbrodolerites of the dyke contain xenoliths of hornfelsed basalts, abundant amygdales and rare grains of zoned olivine-1 <i>Fo</i><sub>90–47</sub> that coexists with subhedral olivine <i>Fo</i><sub>74–36</sub> of the second generation. Modeling with the COMAGMAT and alphaMELTS programs showed that high-Mg <i>Ol</i>-1 with Cr-spinel inclusions cannot be crystallized from a Fe-enriched tholeiitic melt with 4.8–7.3 wt % MgO and 11.6–16.7 wt % total Fe<sub>2</sub>O<sub>3</sub> that is parental for the dyke. The variation trend and high Ni up to 0.5 wt % NiO in the cores of xenocrystic olivine <i>Fo</i><sub>90–76</sub> in contrast to maximum <i>Fo</i><sub>83</sub> and 0.4 wt % NiO in olivine from the ore-bearing intrusions and picritic basalts of the Norilsk region point toward the presence of deep-seated cumulates of picritic magmas, which had not exchanged with sulfide liquid. Platinum group element (PGE) abundances increase (up to 2.2 ppm) with increasing Cu/Ni in the whole rocks and proportions of pentlandite in a sulfide association. A specific pattern of chalcophile metal distribution with Ni, Os and Ir minima, elevated Cu/Ni (5–15) and Cu/Pd (3200–10 900) along with lower PGE tenor (PGE content in 100% sulfide) of sulfides (2–65 ppm) and Pd content in pentlandite (<175 ppm) compared to those of the ore-bearing intrusions suggest that cuprous sulfide mineralization was not physically captured from highly fractionated sulfide fractions of ore-bearing magmas but is cogenetic with a magma of the dyke. Sulfide saturation, near-simultaneous with fluid saturation and degassing, was achieved in the dyke conduit due to assimilation of sedimentary sulfur and volatiles from Devonian evaporites that is supported by the heavy S isotope composition of dyke’s sulfides with the average δ<sup>34</sup>S = 14.7 ±1.1‰ (<i>n</i> = 31) close to the values for sulfides from the endocontact zones of the Imangda ore-bearing intrusions hosted by the Devonian sequences. The initial isotopic characteristics of dyke rocks (Sr<sub>i</sub> 0.70517–0.70532, ɛNd from –0.4 to 0.8) imply its comagmatic origin with the Norilsk-type intrusions whereas the overall data do not exclude its spatial connection with an upper crustal conduit network of the ore-bearing magmas.</p></div>\",\"PeriodicalId\":20026,\"journal\":{\"name\":\"Petrology\",\"volume\":\"31 6\",\"pages\":\"624 - 647\"},\"PeriodicalIF\":1.0000,\"publicationDate\":\"2023-11-27\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Petrology\",\"FirstCategoryId\":\"89\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S086959112306005X\",\"RegionNum\":4,\"RegionCategory\":\"地球科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"GEOCHEMISTRY & GEOPHYSICS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Petrology","FirstCategoryId":"89","ListUrlMain":"https://link.springer.com/article/10.1134/S086959112306005X","RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"GEOCHEMISTRY & GEOPHYSICS","Score":null,"Total":0}
Sources of Cuprous Sulfide Mineralization and High-Ni Olivine of the Rudnaya Dyke (Imangda Cluster, Norilsk region): Based on Compositional, Isotope and Model Data
The Rudnaya dyke of the Imangda ore cluster is composed of weakly differentiated olivine-bearing to olivine gabbrodolerites with globular and interstitial sulfides of a chalcopyrite–cubanite- (pentlandite-pyrrhotite) composition. Along with sulfide mineralization, gabbrodolerites of the dyke contain xenoliths of hornfelsed basalts, abundant amygdales and rare grains of zoned olivine-1 Fo90–47 that coexists with subhedral olivine Fo74–36 of the second generation. Modeling with the COMAGMAT and alphaMELTS programs showed that high-Mg Ol-1 with Cr-spinel inclusions cannot be crystallized from a Fe-enriched tholeiitic melt with 4.8–7.3 wt % MgO and 11.6–16.7 wt % total Fe2O3 that is parental for the dyke. The variation trend and high Ni up to 0.5 wt % NiO in the cores of xenocrystic olivine Fo90–76 in contrast to maximum Fo83 and 0.4 wt % NiO in olivine from the ore-bearing intrusions and picritic basalts of the Norilsk region point toward the presence of deep-seated cumulates of picritic magmas, which had not exchanged with sulfide liquid. Platinum group element (PGE) abundances increase (up to 2.2 ppm) with increasing Cu/Ni in the whole rocks and proportions of pentlandite in a sulfide association. A specific pattern of chalcophile metal distribution with Ni, Os and Ir minima, elevated Cu/Ni (5–15) and Cu/Pd (3200–10 900) along with lower PGE tenor (PGE content in 100% sulfide) of sulfides (2–65 ppm) and Pd content in pentlandite (<175 ppm) compared to those of the ore-bearing intrusions suggest that cuprous sulfide mineralization was not physically captured from highly fractionated sulfide fractions of ore-bearing magmas but is cogenetic with a magma of the dyke. Sulfide saturation, near-simultaneous with fluid saturation and degassing, was achieved in the dyke conduit due to assimilation of sedimentary sulfur and volatiles from Devonian evaporites that is supported by the heavy S isotope composition of dyke’s sulfides with the average δ34S = 14.7 ±1.1‰ (n = 31) close to the values for sulfides from the endocontact zones of the Imangda ore-bearing intrusions hosted by the Devonian sequences. The initial isotopic characteristics of dyke rocks (Sri 0.70517–0.70532, ɛNd from –0.4 to 0.8) imply its comagmatic origin with the Norilsk-type intrusions whereas the overall data do not exclude its spatial connection with an upper crustal conduit network of the ore-bearing magmas.
期刊介绍:
Petrology is a journal of magmatic, metamorphic, and experimental petrology, mineralogy, and geochemistry. The journal offers comprehensive information on all multidisciplinary aspects of theoretical, experimental, and applied petrology. By giving special consideration to studies on the petrography of different regions of the former Soviet Union, Petrology provides readers with a unique opportunity to refine their understanding of the geology of the vast territory of the Eurasian continent. The journal welcomes manuscripts from all countries in the English or Russian language.