Granular Carbon Adsorbent Based on Carbon Black and Synthetic Pitch

A method for producing granular carbon adsorbent by stirring a suspension of carbon black in a solution of naphthalene (in heptane) in the presence of sulfuric acid was proposed. Experimental research together with mathematical processing of the results made it possible to propose a mechanism for the formation of spherical carbon granules from carbon black and naphthalene: in the course of intense mixing in the presence of concentrated sulfuric acid, a binder material was formed from naphthalene, and it was adsorbed on the surface of carbon black particles. The resulting particles with a thin layer of binding material on their surface stuck together in the field of centrifugal forces to form larger particles, which ultimately acquired a spherical shape and had a size of up to 5 mm. A comparison of the resulting carbon granules (from carbon black and synthetic pitch) with granules prepared by mixing carbon black and petroleum pitch showed that the proposed adsorbent had specific surface area and mechanical strength greater by factors of 1.5–2.