V. I. Radomskaya, L. P. Shumilova, A. P. Sorokin, B. R. Soktoev, V. V. Ivanov, L. M. Pavlova
{"title":"黑龙江地区谢尔盖夫斯科矿床褐煤中稀土元素提取实验研究","authors":"V. I. Radomskaya, L. P. Shumilova, A. P. Sorokin, B. R. Soktoev, V. V. Ivanov, L. M. Pavlova","doi":"10.3103/S036152192306006X","DOIUrl":null,"url":null,"abstract":"<p>A series of experiments on the leaching of rare earth elements (REEs) from Miocene brown coals of the Sergeevskoe deposit with water and alkaline and acid solutions was carried out. Using a set of methods (ICP MS, XRD analysis, heavy concentrate analysis, SEM EDS, and IR spectrometry), it was revealed that acid leaching was the most effective: 72–99% of REEs was extracted with a 1 M solution of hydrochloric acid in 24–48 h. This fact indicates that most of the REEs in the brown coals of the Sergeevskoe deposit were associated with the organic matrix in the form of complexes with the carboxyl groups of humic and fulvic acids. The high percentage of REE extraction indicates the possibility of using coals from the Sergeevskoe deposit as an easily enriched source of REEs.</p>","PeriodicalId":779,"journal":{"name":"Solid Fuel Chemistry","volume":"57 6","pages":"411 - 422"},"PeriodicalIF":0.8000,"publicationDate":"2023-11-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Extraction of Rare Earth Elements from Brown Coals of the Sergeevskoe Deposit (Amur Region) According to Experimental Data\",\"authors\":\"V. I. Radomskaya, L. P. Shumilova, A. P. Sorokin, B. R. Soktoev, V. V. Ivanov, L. M. Pavlova\",\"doi\":\"10.3103/S036152192306006X\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>A series of experiments on the leaching of rare earth elements (REEs) from Miocene brown coals of the Sergeevskoe deposit with water and alkaline and acid solutions was carried out. Using a set of methods (ICP MS, XRD analysis, heavy concentrate analysis, SEM EDS, and IR spectrometry), it was revealed that acid leaching was the most effective: 72–99% of REEs was extracted with a 1 M solution of hydrochloric acid in 24–48 h. This fact indicates that most of the REEs in the brown coals of the Sergeevskoe deposit were associated with the organic matrix in the form of complexes with the carboxyl groups of humic and fulvic acids. The high percentage of REE extraction indicates the possibility of using coals from the Sergeevskoe deposit as an easily enriched source of REEs.</p>\",\"PeriodicalId\":779,\"journal\":{\"name\":\"Solid Fuel Chemistry\",\"volume\":\"57 6\",\"pages\":\"411 - 422\"},\"PeriodicalIF\":0.8000,\"publicationDate\":\"2023-11-24\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Solid Fuel Chemistry\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://link.springer.com/article/10.3103/S036152192306006X\",\"RegionNum\":4,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Solid Fuel Chemistry","FirstCategoryId":"5","ListUrlMain":"https://link.springer.com/article/10.3103/S036152192306006X","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Extraction of Rare Earth Elements from Brown Coals of the Sergeevskoe Deposit (Amur Region) According to Experimental Data
A series of experiments on the leaching of rare earth elements (REEs) from Miocene brown coals of the Sergeevskoe deposit with water and alkaline and acid solutions was carried out. Using a set of methods (ICP MS, XRD analysis, heavy concentrate analysis, SEM EDS, and IR spectrometry), it was revealed that acid leaching was the most effective: 72–99% of REEs was extracted with a 1 M solution of hydrochloric acid in 24–48 h. This fact indicates that most of the REEs in the brown coals of the Sergeevskoe deposit were associated with the organic matrix in the form of complexes with the carboxyl groups of humic and fulvic acids. The high percentage of REE extraction indicates the possibility of using coals from the Sergeevskoe deposit as an easily enriched source of REEs.
期刊介绍:
The journal publishes theoretical and applied articles on the chemistry and physics of solid fuels and carbonaceous materials. It addresses the composition, structure, and properties of solid fuels. The aim of the published articles is to demonstrate how novel discoveries, developments, and theories may be used in improved analysis and design of new types of fuels, chemicals, and by-products. The journal is particularly concerned with technological aspects of various chemical conversion processes and includes papers related to geochemistry, petrology and systematization of fossil fuels, their beneficiation and preparation for processing, the processes themselves, and the ultimate recovery of the liquid or gaseous end products.