铁/生物炭催化剂的相组成对费托合成产物组成的影响:双功能催化中心的Lapidus理论

IF 0.8 4区 工程技术 Q4 CHEMISTRY, MULTIDISCIPLINARY
M. I. Ivantsov, K. O. Krysanova, A. A. Grabchak, M. V. Kulikova
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引用次数: 0

摘要

研究了以纤维素和木质素为原料,水热炭化生物炭为载体的负载型铁催化剂。催化体系在费托合成中表现出较高的活性。记录了C5+液体产物的组成,这是含铁催化剂所不具备的特征,其特征是异烷烃含量高(高达55%)。这一事实在A.L. Lapidus及其同事提出的双功能中心理论的背景下进行了讨论。结果表明,试验催化剂的活性中心可以认为是双功能的(碳化物相和氧化物相)。测试催化剂上的费托合成数据与Lapidus及其同事在含钴催化剂上获得的数据之间存在相关性。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Influence of the Phase Composition of the Fe/Biochar Catalysts on the Composition of Fischer–Tropsch Synthesis Products: The Lapidus Theory of Bifunctional Catalytic Centers

Influence of the Phase Composition of the Fe/Biochar Catalysts on the Composition of Fischer–Tropsch Synthesis Products: The Lapidus Theory of Bifunctional Catalytic Centers

Supported iron catalysts based on a carbon-containing material, biochar obtained by the hydrothermal carbonization of biopolymers (cellulose and lignin), were studied. The catalytic systems showed high activity in the Fischer–Tropsch synthesis. A composition of C5+ liquid products, uncharacteristic for iron-containing catalysts, characterized by high isoalkane content (up to 55%) was recorded. This fact was discussed in the context of the theory of bifunctional centers proposed by A.L. Lapidus with coworkers. It was suggested that the active centers of the test catalysts can be considered bifunctional (a carbide phase and an oxide phase). A correlation between the Fischer–Tropsch synthesis data on the test catalysts and the data obtained by Lapidus and coworkers on cobalt-containing catalysts was shown.

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来源期刊
Solid Fuel Chemistry
Solid Fuel Chemistry CHEMISTRY, MULTIDISCIPLINARY-ENERGY & FUELS
CiteScore
1.10
自引率
28.60%
发文量
52
审稿时长
6-12 weeks
期刊介绍: The journal publishes theoretical and applied articles on the chemistry and physics of solid fuels and carbonaceous materials. It addresses the composition, structure, and properties of solid fuels. The aim of the published articles is to demonstrate how novel discoveries, developments, and theories may be used in improved analysis and design of new types of fuels, chemicals, and by-products. The journal is particularly concerned with technological aspects of various chemical conversion processes and includes papers related to geochemistry, petrology and systematization of fossil fuels, their beneficiation and preparation for processing, the processes themselves, and the ultimate recovery of the liquid or gaseous end products.
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