{"title":"γ，δ-不饱和酮O-(对氰苯基)肟光化学转化为3,4-二氢- 2h -吡咯衍生物","authors":"Tetsuhiro Mikami, Koichi Narasaka","doi":"10.1016/S1387-1609(01)01254-3","DOIUrl":null,"url":null,"abstract":"<div><p><em>γ,δ</em>-Unsaturated ketone <em>O</em>-(<em>p</em>-cyanophenyl)oximes are transformed into 3,4-dihydro-2<em>H</em>-pyrroles by a photochemical reaction in the presence of 1,5-dimethoxynaphthalene. The present transformation proceeds via photosensitized electron transfer between 1,5-dimethoxynaphthalene and <em>O</em>-(<em>p</em>-cyanophenyl)oximes.</p></div>","PeriodicalId":100305,"journal":{"name":"Comptes Rendus de l'Académie des Sciences - Series IIC - Chemistry","volume":"4 6","pages":"Pages 477-485"},"PeriodicalIF":0.0000,"publicationDate":"2001-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/S1387-1609(01)01254-3","citationCount":"0","resultStr":"{\"title\":\"Photochemical transformation of γ,δ-unsaturated ketone O-(p-cyanophenyl)oximes to 3,4-dihydro-2H-pyrrole derivatives\",\"authors\":\"Tetsuhiro Mikami, Koichi Narasaka\",\"doi\":\"10.1016/S1387-1609(01)01254-3\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p><em>γ,δ</em>-Unsaturated ketone <em>O</em>-(<em>p</em>-cyanophenyl)oximes are transformed into 3,4-dihydro-2<em>H</em>-pyrroles by a photochemical reaction in the presence of 1,5-dimethoxynaphthalene. The present transformation proceeds via photosensitized electron transfer between 1,5-dimethoxynaphthalene and <em>O</em>-(<em>p</em>-cyanophenyl)oximes.</p></div>\",\"PeriodicalId\":100305,\"journal\":{\"name\":\"Comptes Rendus de l'Académie des Sciences - Series IIC - Chemistry\",\"volume\":\"4 6\",\"pages\":\"Pages 477-485\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2001-06-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/S1387-1609(01)01254-3\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Comptes Rendus de l'Académie des Sciences - Series IIC - Chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S1387160901012543\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Comptes Rendus de l'Académie des Sciences - Series IIC - Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1387160901012543","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Photochemical transformation of γ,δ-unsaturated ketone O-(p-cyanophenyl)oximes to 3,4-dihydro-2H-pyrrole derivatives
γ,δ-Unsaturated ketone O-(p-cyanophenyl)oximes are transformed into 3,4-dihydro-2H-pyrroles by a photochemical reaction in the presence of 1,5-dimethoxynaphthalene. The present transformation proceeds via photosensitized electron transfer between 1,5-dimethoxynaphthalene and O-(p-cyanophenyl)oximes.
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