有机质对Salah al-Din省部分石膏质土壤铜吸附和释放的影响

Basim S. Obaid, Ragaa S. Salih, Yasir H. Ajrash
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引用次数: 0

摘要

通过对铜在不同有机源石膏土中的吸附和释放条件的了解,利用物理化学Langmuir、Freundlich和Temkin三个方程,对铜在不同有机源石膏土中的行为进行了实验研究。采用测定系数(R2)作为描述铜吸附的较好选择方程,结果表明,Langmuir方程与其他根据最高测定系数R2使用的物理化学方程相比,足以描述和评价铜的吸附,Langmuir方程、Freundlich方程和Temkin方程的R2效率分别为(92,87,65)%。Langmuir方程的最大吸附值为61.728 ~ 25,906 mg。根据Freundlech方程,最大吸附值为1.346 ~ 0.855 L.mg-1,最大吸附能为15.160 ~ 4.010 mg。最大吸附值符合Temkin方程,在(35 ~ 29)mg之间。kg-1能量连通性范围在(0.495-0.185)l kg-1之间,从公式Temkin可以定义类型吸附物理或化学家,并在大多数化学日历上的高度有价热相互作用bT,范围从(84.86 - 70.34)。从吸附铜的析出结果来看,析出铜的最大值为。从铜(50,100,150)mg -1中添加高水平,从铜(2,5,10)mg -1中添加低水平是有价值的解放铜零(nill)。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Effect of organic matter on the adsorption and release of copper in some gypsiferous soils in Salah al-Din Governorate
A laboratory experiment was conducted to study the behavior of copper in gypsum soils of different organic sources through a number of experiences, and knowledge of copper adsorption and release conditions in it, and used three equations physicochemical Langmuir, Freundlich, and Temkin. It was adopted The coefficient of determination (R2 ) is a better choice equation to describe the adsorption of copper, the results showed that the Langmuir equation was enough for the description and evaluation of copper adsorption compared to the rest of the physicochemical equations used according to the highest coefficient of determination R2, and the efficiency of R2 was (92, 87, 65) % for each of the Langmuir and Freundlich equations and Temkin, respectively. The maximum adsorption values of the Langmuir equation were (61.728 - 25,906) mg.kg-1 and a bonding energy (0.731 - 0.128) L.mg-1, and Freundlech's equation showed the maximum adsorption values (1.346 - 0.855) L.mg-1 and a bonding energy (15.160 - 4.010) mg.kg-1, while the maximum adsorption values were to equation Temkin range between (35 - 29) mg.kg-1 energy connectivity ranging what between (0.495-0.185) L.kg-1, and from equation Temkin can that define type adsorption physical or a chemist and on the most chemical calendar for height valuable heat interaction bT, which ranges from (84.86 - 70.34). As for the results of liberating copper adsorbed, the highest values of liberated copper were recorded at. Levels add high from copper (50,100,150) mgkg-1 and at levels low add from copper (2,5,10) mgkg-1 be valuable Liberation copper zero (nill).
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