卡达姆寨锑矿石中提钪工艺补充

A. Ukeleeva, Zh. Zhusupova, E. Dzhumabekova, E. Ysmanov
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引用次数: 0

摘要

本文讨论了从卡达姆寨锑矿废渣(磨砂)中提取稀土元素的方法。为此,钪的定量测定采用其配合物溶液的光比色法,与已知的方法相比,该方法可以在25-30分钟内进行分析,具有足够的准确性,并且可以在不预先分离干扰杂质的情况下测定技术废物中的钪。为此,在溶液中加入抗坏血酸,将pH值调整为1-2,然后加入二甲醇橙和比色仪,使用通常的方法。光比色法不受碱土元素(Ca、Ba、Sr、Mg)、稀土元素(La、Pr、Nd、Sm等)以及钇、锌、镉、锰、铁的影响。铁的有害作用通过添加抗坏血酸而消除。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Addendum to the Technology for Extraction of Scandium From Matte of the Kadamzhai Antimony Plant
The article discusses methods for extracting rare earth elements from the waste (matte) of the Kadamzhai antimony plant. For this purpose, the quantitative determination of scandium was used by photocolorimetry of solutions of its complexes, which, compared to the known ones, will allow analysis within 25-30 minutes with sufficient accuracy and makes it possible to determine scandium in technogenic waste without preliminary separation of interfering impurities. To do this, add ascorbic acid to the solution, adjust the pH to 1-2, then add xylenol orange and colorimeter using the usual methods Photocolorimetry is not affected by alkaline earth elements (Ca, Ba, Sr, Mg), rare earth elements (La, Pr, Nd, Sm and others), as well as yttrium, zinc, cadmium, manganese, iron. The harmful effects of Fe are eliminated by the addition of ascorbic acid.
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