不同空气电极结构对可充电锌空气电池放电特性的影响

Gergő Kecsmár, Máté Czagány, Péter Baumli, Zsolt Dobó
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引用次数: 0

摘要

可充电金属-空气电池技术是一种备受关注的环保和可持续能源存储的智能方法。与锂离子相比,每吨锌的全球市场价格低了两个数量级,与世界范围内的锂离子设计相比,可充电ZAB的理论和实际比能量密度都有所提高,这有助于可充电锌空气电池的不断发展。空气电极作为阴极对提高ZABs的充放电性能起着至关重要的作用,因此,利用泡沫镍、石墨涂层和纳米碳颗粒组装不同层序的空气电极。与单(泡沫镍)层和双(泡沫镍+石墨涂层)层结构相比,三层阴极显示出最高的电压和性能值。电解质无机添加剂(2 n/n% ZnCl2和0.05 wt% MnO2)的影响在空载期间尤为明显。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
The influence of different air electrode structures to discharge characteristics in rechargeable Zn-air battery
The rechargeable metal-air battery technology is a well-interested smart method for eco-friendly and sustainable energy storage. Both of the two order of magnitude lower global market price per tonne of Zn compared to lithium and the multiple theoretical and practical specific energy density of rechargeable ZAB compared to the worldwide Li-ion designs contributes the developing continuously of rechargeable Zn-air battery. The air electrode as a cathode has a vital role in increasing the discharge-charge performance in ZABs, therefore different layers-order air electrodes were assembledwith the utilization of Ni-foam, graphite coating and carbon nanoparticles. The tri-layers cathode showed the highest voltage and performance values compared to the mono- (Ni-foam) and bi- (Ni-foam + graphite coating) layers architectures. The effect of electrolyte inorganic additives (e.g., 2 n/n% ZnCl2 and 0,05 wt% MnO2) was experienced especially at the no-load period.
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