固体分解过程中的表面能

V. T. Fedorov, M. N. Kokoev
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引用次数: 0

摘要

目标。本研究的目的是通过实验测量固体磨削过程中的表面能。方法。这项研究是基于测定固体表面张力的方法。世界上至少有20-25%的电力用于工业研磨材料。当得到的颗粒缩小到几十纳米时,表面能(st)对磨削功的贡献变得如此之大,以至于很难不加以考虑。测量液体表面张力的方法早已得到证实。但是固体的测量有很大的困难。目前已知的测定(st)的方法有20多种。结果。基于细线状结构的自发弯曲现象,提出了一种确定(st)的方法。给出了用强塑性变形法(SPD)获得具有微观结构的样品时,相界面处的st起重要作用的实例。为了获得精细的金属粉末,提出了一种SPD方法的变体。已经发现了一种使铝颗粒物理活化的方法,它使金属在水环境中的反应速率提高了大约一千倍。这对于开发能够在深海中运行的厌氧发电厂是必要的。结论。这项新技术可以获得高纯度,无氧化的金属粉末,没有有毒废物和排放,能源成本低于所有已知方法。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Surface Energy in the Processes of Disintegration of Solids
Objective . The purpose of the study is to experimentally measure the surface energy of solids during their grinding. Method . The study is based on the use of methods for determining the surface tension of solids. At least 20-25% of all electricity produced in the world is spent on grinding materials in industry. When the resulting particles are reduced to tens of nanometers, the contribution of surface energy (st) to the grinding work becomes so large that it is difficult not to take it into account. Measuring the surface tension of liquids has long been proven. But measuring (st) of solids causes great difficulties. Currently, more than twenty methods for determining (st) are known. Result . Based on the phenomenon of spontaneous bending of thin thread-like structures, a method for determining (st) has been developed. Examples are given in which (st) at the phase interface plays an important role in obtaining samples with a microstructure using the method of severe plastic deformation (SPD). To obtain fine metal powders, one of the variants of the SPD method has been proposed. A method has been found for the physical activation of aluminum granules, which increases the reaction rate of the metal in an aqueous environment by about a thousand times. This is necessary for the development of an anaerobic power plant capable of operating at great depths. Conclusion . The new technology makes it possible to obtain high-purity, non-oxidized metal powders without toxic waste and emissions and with energy costs lower than in all known methods.
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