2 - (1-Methoxycarbonyl-2-phenyleth-1-yl) -1-benzylpyridin-1-ium Bromide

IF 0.6 Q4 CHEMISTRY, ORGANIC

Molbank Pub Date : 2023-10-16 DOI:10.3390/m1738

Lorenzo Suigo, Valentina Straniero, Ermanno Valoti

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引用次数: 0

摘要

在这项工作中，我们报告了由于原油中存在未反应的苯溴，吡啶衍生物意外转化为相应的n -苄基化吡啶盐。这种转变是在室温下无溶剂环境下观察到的，没有任何搅拌。这些有趣的数据表明，吡啶盐是如何在温和的条件下形成的，避免了可能促进所需产品降解的高温。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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2-(1-Methoxycarbonyl-2-phenyleth-1-yl)-1-benzylpyridin-1-ium Bromide

In this work, we report the unexpected conversion of a pyridine derivative into the corresponding N-benzylated pyridinium salt due to the presence of unreacted benzyl bromide in the crude product. This transformation was observed at room temperature in a solvent-free environment and without any stirring. These interesting data show how pyridinium salts can be formed in mild conditions, avoiding high temperatures that could promote the degradation of the desired product.

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来源期刊

Molbank Chemistry-Physical and Theoretical Chemistry

CiteScore

0.70

自引率

33.30%

发文量

174

审稿时长

11 weeks

期刊介绍： •organic synthesis •biosynthesis •extraction and purification •natural product derivatives •structural elucidation (X-ray crystallography, NMR, etc.)