解决钙钛矿太阳能电池的稳定性挑战:离子液体掺入提高设备耐久性的潜力

Q4 Engineering
Artur Farinha, Luís Santos, José Costa
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引用次数: 0

摘要

与传统的硅基太阳能电池相比,钙钛矿太阳能电池(PSCs)由于其低成本和低碳足迹而成为一种有前途的可再生能源发电技术。然而,与psc相关的一些主要挑战还在前面,即它们的毒性和缺乏稳定性,特别是在光、温度、氧气和湿度等因素下。我们的重点是psc缺乏稳定性,以及可以减轻稳定性的各种方法。我们探索使用气相沉积方法,可以提高钙钛矿的结晶度,从而提高稳定性和寿命。此外,我们还研究了离子液体(ILs)作为提高psc稳定性和性能的有前途的材料的潜力。il具有优越的物理化学性质,使其适合作为PSCs的添加剂或界面层。它们优化了界面接触,改善了能级匹配,抑制了离子迁移,增加了疏水性,从而抑制了器件在潮湿环境中的分解。钛酸盐也被用作用于PSC应用的钙钛矿薄膜溶液制备的前驱体,有助于钙钛矿的结晶。一些研究表明,在psc中掺入il可以增加稳定性、寿命和效率。总的来说,现有的研究表明,作为提高psc稳定性和性能的材料,il具有很大的前景,这可能对低成本可再生能源技术的发展产生重大影响。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Addressing the Stability Challenge of Perovskite Solar Cells: The Potential of Ionic Liquid Incorporation for Improved Device Durability
Perovskite solar cells (PSCs) have emerged as a promising technology for renewable energy generation due to their low cost and low carbon footprint compared to traditional silicon-based solar cells. However, some main challenges associated with PSCs lie ahead, namely their toxicity and lack of stability, particularly under factors such as light, temperature, oxygen, and humidity. We focus on the lack of stability of PSCs and the various ways it can be mitigated. We explore the use of vapor deposition methods, which can increase the crystallinity of the perovskite and thus improve stability and lifetime. Furthermore, we look into the potential of ionic liquids (ILs) as promising materials for improving the stability and performance of PSCs. ILs have advantageous physicochemical properties that make them suitable as an additive or interfacial layer in PSCs. They optimize the interface contact, improve energy level matching, suppress ion migration, and increase hydrophobicity, which inhibits the decomposition of the device in humid environments. ILs have also been used as precursors in the solution-based fabrication of perovskite thin films for PSC applications, assisting in the perovskite crystallization. Several studies have shown that the incorporation of ILs in PSCs can increase stability, lifetime, and efficiency. Overall, the existing research indicates that ILs hold great promise as materials for improving the stability and performance of PSCs, which could have significant implications for the development of low-cost, renewable energy technologies.
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来源期刊
U.Porto Journal of Engineering
U.Porto Journal of Engineering Engineering-Engineering (all)
CiteScore
0.70
自引率
0.00%
发文量
58
审稿时长
20 weeks
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