{"title":"碱超基性至中火成岩演化及热压测量的新实验约束","authors":"Andrés Fabián Salazar-Naranjo, Silvio Roberto Farias Vlach","doi":"10.1093/petrology/egad078","DOIUrl":null,"url":null,"abstract":"Abstract We report new experimental data from ultrabasic basanite and ultrabasic tephrite as starting material compositions in the 1350°C to 1000°C temperature range. Crystallization experiments under low- to high-pressure (0.5–2.0 GPa) were carried out under reduced conditions (≈CCO buffer), while one-atmosphere, anhydrous, experiments were performed ranging from reduced to oxidized conditions (−2 ≤ ∆QFM ≤ +2). The results highlight the ƒO2 role on the silica saturation of the alkali liquids differentiated from these primary ultrabasic magmas, on the mineral assemblage, and its composition. The liquid lines of descent (LLDs) from basanite are sodic and strongly SiO2 undersaturated, whereas from tephrite, the LLDs are sodic-potassic/potassic for both weakly SiO2-undersaturated and SiO2-saturated compositions, being more silica saturated under oxidized conditions. At the lowest temperature experiments, the percentage of liquid remaining is significantly higher in the basanite-derived products (ca. 35 wt.%) than in tephrite, indicating that the equivalent magmas are more prone to produce larger quantities of evolved melts. The best obtained Fe–Mg olivine/melt and clinopyroxene/melt exchange coefficients for these alkali compositions considering the new and available data are ${K_D}_{Fe^{2+}- Mg}^{Ol- Alkali\\ melt}=0.285\\pm 0.014$ and ${K_D}_{Fe^{2+}- Mg}^{Cpx- Alkali\\ melt}=0.245\\pm 0.008$, slightly lower than those observed in tholeiitic melts. Clinopyroxene compositions are Ti–Al-rich and Si-poor as compared with common clinopyroxenes in subalkali systems. We suggest that Ti should be allocated in the tetrahedral sites substituting for Si and that its contents are inversely correlated with pressure. Our results allow a simple new barometer based on clinopyroxene-only compositions, as follows:$$ P\\left(\\pm 0.16\\ GPa,1\\sigma \\right)=16.028\\left(\\pm 1.042\\right) Na-6.715\\left(\\pm 0.727\\right)\\frac{Ti}{Ti+ Al(t)}+0.494\\left(\\pm 0.441\\right) Si+0.144\\left(\\pm 0.079\\right) $$where Na, Ti, Al(t), and Si are molar proportions relative to 6O. This formulation accounts for the jadeite (NaAlSi2O6) component, herein computed from the Na contents, corrected for the Ti-diopside (CaMgTi2O6) component in clinopyroxene and also considers the evolutionary trend from Mg-augite to ferroan diopside. It applies to alkali ultrabasic to intermediate compositions in the examined P–T–ƒO2 range, resulting in more accurate estimates than the available calibrations. The MgO-in-melt thermometer was optimized for the studied compositions at one-atmosphere pressure and anhydrous conditions, as follows:$$ T\\ \\left(\\pm 5{}^{\\circ}C,1\\sigma \\right)=27.35\\left(\\pm 0.65\\right)\\ \\big({MgO}^{liq}\\big)+984\\left(\\pm 4\\right) $$which provides much more reliable liquidus temperatures for these alkali systems. Given data restriction, this formulation may be expanded to include the pressure effects for relatively low-H2O (< 3 wt.%) systems as:$$ T\\ \\left(\\pm 20{}^{\\circ}C,1\\sigma \\right)=27.35\\left(\\pm 0.65\\right)\\big({MgO}^{liq}\\big)+80.20\\left(\\pm 5.50\\right)P(GPa)+981\\left(\\pm 4\\right) $$","PeriodicalId":16751,"journal":{"name":"Journal of Petrology","volume":null,"pages":null},"PeriodicalIF":3.5000,"publicationDate":"2023-10-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"New experimental constraints for the evolution and thermobarometry of alkali ultrabasic to intermediate igneous rocks\",\"authors\":\"Andrés Fabián Salazar-Naranjo, Silvio Roberto Farias Vlach\",\"doi\":\"10.1093/petrology/egad078\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Abstract We report new experimental data from ultrabasic basanite and ultrabasic tephrite as starting material compositions in the 1350°C to 1000°C temperature range. Crystallization experiments under low- to high-pressure (0.5–2.0 GPa) were carried out under reduced conditions (≈CCO buffer), while one-atmosphere, anhydrous, experiments were performed ranging from reduced to oxidized conditions (−2 ≤ ∆QFM ≤ +2). The results highlight the ƒO2 role on the silica saturation of the alkali liquids differentiated from these primary ultrabasic magmas, on the mineral assemblage, and its composition. The liquid lines of descent (LLDs) from basanite are sodic and strongly SiO2 undersaturated, whereas from tephrite, the LLDs are sodic-potassic/potassic for both weakly SiO2-undersaturated and SiO2-saturated compositions, being more silica saturated under oxidized conditions. At the lowest temperature experiments, the percentage of liquid remaining is significantly higher in the basanite-derived products (ca. 35 wt.%) than in tephrite, indicating that the equivalent magmas are more prone to produce larger quantities of evolved melts. The best obtained Fe–Mg olivine/melt and clinopyroxene/melt exchange coefficients for these alkali compositions considering the new and available data are ${K_D}_{Fe^{2+}- Mg}^{Ol- Alkali\\\\ melt}=0.285\\\\pm 0.014$ and ${K_D}_{Fe^{2+}- Mg}^{Cpx- Alkali\\\\ melt}=0.245\\\\pm 0.008$, slightly lower than those observed in tholeiitic melts. Clinopyroxene compositions are Ti–Al-rich and Si-poor as compared with common clinopyroxenes in subalkali systems. We suggest that Ti should be allocated in the tetrahedral sites substituting for Si and that its contents are inversely correlated with pressure. Our results allow a simple new barometer based on clinopyroxene-only compositions, as follows:$$ P\\\\left(\\\\pm 0.16\\\\ GPa,1\\\\sigma \\\\right)=16.028\\\\left(\\\\pm 1.042\\\\right) Na-6.715\\\\left(\\\\pm 0.727\\\\right)\\\\frac{Ti}{Ti+ Al(t)}+0.494\\\\left(\\\\pm 0.441\\\\right) Si+0.144\\\\left(\\\\pm 0.079\\\\right) $$where Na, Ti, Al(t), and Si are molar proportions relative to 6O. This formulation accounts for the jadeite (NaAlSi2O6) component, herein computed from the Na contents, corrected for the Ti-diopside (CaMgTi2O6) component in clinopyroxene and also considers the evolutionary trend from Mg-augite to ferroan diopside. It applies to alkali ultrabasic to intermediate compositions in the examined P–T–ƒO2 range, resulting in more accurate estimates than the available calibrations. The MgO-in-melt thermometer was optimized for the studied compositions at one-atmosphere pressure and anhydrous conditions, as follows:$$ T\\\\ \\\\left(\\\\pm 5{}^{\\\\circ}C,1\\\\sigma \\\\right)=27.35\\\\left(\\\\pm 0.65\\\\right)\\\\ \\\\big({MgO}^{liq}\\\\big)+984\\\\left(\\\\pm 4\\\\right) $$which provides much more reliable liquidus temperatures for these alkali systems. Given data restriction, this formulation may be expanded to include the pressure effects for relatively low-H2O (< 3 wt.%) systems as:$$ T\\\\ \\\\left(\\\\pm 20{}^{\\\\circ}C,1\\\\sigma \\\\right)=27.35\\\\left(\\\\pm 0.65\\\\right)\\\\big({MgO}^{liq}\\\\big)+80.20\\\\left(\\\\pm 5.50\\\\right)P(GPa)+981\\\\left(\\\\pm 4\\\\right) $$\",\"PeriodicalId\":16751,\"journal\":{\"name\":\"Journal of Petrology\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":3.5000,\"publicationDate\":\"2023-10-17\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Petrology\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1093/petrology/egad078\",\"RegionNum\":2,\"RegionCategory\":\"地球科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"GEOCHEMISTRY & GEOPHYSICS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Petrology","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1093/petrology/egad078","RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"GEOCHEMISTRY & GEOPHYSICS","Score":null,"Total":0}
引用次数: 0
摘要
摘要在1350 ~ 1000℃的温度范围内,我们报道了超基性玄武岩和超基性翡翠作为起始材料组成的新实验数据。低至高压(0.5-2.0 GPa)的结晶实验在还原条件下(≈CCO缓冲液)进行,而一气无水的实验在还原至氧化条件下(−2≤∆QFM≤+2)进行。研究结果强调了ƒO2在这些原生超基性岩浆中区分的碱液体的硅饱和度、矿物组合及其组成方面的作用。玄武岩的液态下降线(LLDs)为钠质和强SiO2欠饱和,而软玉的液态下降线(LLDs)为弱SiO2欠饱和和SiO2饱和成分的钠质钾/钾质,在氧化条件下更饱和二氧化硅。在最低温度实验中,玄武岩衍生产品中剩余液体的百分比明显更高(约35 wt)。%) than in tephrite, indicating that the equivalent magmas are more prone to produce larger quantities of evolved melts. The best obtained Fe–Mg olivine/melt and clinopyroxene/melt exchange coefficients for these alkali compositions considering the new and available data are ${K_D}_{Fe^{2+}- Mg}^{Ol- Alkali\ melt}=0.285\pm 0.014$ and ${K_D}_{Fe^{2+}- Mg}^{Cpx- Alkali\ melt}=0.245\pm 0.008$, slightly lower than those observed in tholeiitic melts. Clinopyroxene compositions are Ti–Al-rich and Si-poor as compared with common clinopyroxenes in subalkali systems. We suggest that Ti should be allocated in the tetrahedral sites substituting for Si and that its contents are inversely correlated with pressure. Our results allow a simple new barometer based on clinopyroxene-only compositions, as follows:$$ P\left(\pm 0.16\ GPa,1\sigma \right)=16.028\left(\pm 1.042\right) Na-6.715\left(\pm 0.727\right)\frac{Ti}{Ti+ Al(t)}+0.494\left(\pm 0.441\right) Si+0.144\left(\pm 0.079\right) $$where Na, Ti, Al(t), and Si are molar proportions relative to 6O. This formulation accounts for the jadeite (NaAlSi2O6) component, herein computed from the Na contents, corrected for the Ti-diopside (CaMgTi2O6) component in clinopyroxene and also considers the evolutionary trend from Mg-augite to ferroan diopside. It applies to alkali ultrabasic to intermediate compositions in the examined P–T–ƒO2 range, resulting in more accurate estimates than the available calibrations. The MgO-in-melt thermometer was optimized for the studied compositions at one-atmosphere pressure and anhydrous conditions, as follows:$$ T\ \left(\pm 5{}^{\circ}C,1\sigma \right)=27.35\left(\pm 0.65\right)\ \big({MgO}^{liq}\big)+984\left(\pm 4\right) $$which provides much more reliable liquidus temperatures for these alkali systems. Given data restriction, this formulation may be expanded to include the pressure effects for relatively low-H2O (< 3 wt.%) systems as:$$ T\ \left(\pm 20{}^{\circ}C,1\sigma \right)=27.35\left(\pm 0.65\right)\big({MgO}^{liq}\big)+80.20\left(\pm 5.50\right)P(GPa)+981\left(\pm 4\right) $$
New experimental constraints for the evolution and thermobarometry of alkali ultrabasic to intermediate igneous rocks
Abstract We report new experimental data from ultrabasic basanite and ultrabasic tephrite as starting material compositions in the 1350°C to 1000°C temperature range. Crystallization experiments under low- to high-pressure (0.5–2.0 GPa) were carried out under reduced conditions (≈CCO buffer), while one-atmosphere, anhydrous, experiments were performed ranging from reduced to oxidized conditions (−2 ≤ ∆QFM ≤ +2). The results highlight the ƒO2 role on the silica saturation of the alkali liquids differentiated from these primary ultrabasic magmas, on the mineral assemblage, and its composition. The liquid lines of descent (LLDs) from basanite are sodic and strongly SiO2 undersaturated, whereas from tephrite, the LLDs are sodic-potassic/potassic for both weakly SiO2-undersaturated and SiO2-saturated compositions, being more silica saturated under oxidized conditions. At the lowest temperature experiments, the percentage of liquid remaining is significantly higher in the basanite-derived products (ca. 35 wt.%) than in tephrite, indicating that the equivalent magmas are more prone to produce larger quantities of evolved melts. The best obtained Fe–Mg olivine/melt and clinopyroxene/melt exchange coefficients for these alkali compositions considering the new and available data are ${K_D}_{Fe^{2+}- Mg}^{Ol- Alkali\ melt}=0.285\pm 0.014$ and ${K_D}_{Fe^{2+}- Mg}^{Cpx- Alkali\ melt}=0.245\pm 0.008$, slightly lower than those observed in tholeiitic melts. Clinopyroxene compositions are Ti–Al-rich and Si-poor as compared with common clinopyroxenes in subalkali systems. We suggest that Ti should be allocated in the tetrahedral sites substituting for Si and that its contents are inversely correlated with pressure. Our results allow a simple new barometer based on clinopyroxene-only compositions, as follows:$$ P\left(\pm 0.16\ GPa,1\sigma \right)=16.028\left(\pm 1.042\right) Na-6.715\left(\pm 0.727\right)\frac{Ti}{Ti+ Al(t)}+0.494\left(\pm 0.441\right) Si+0.144\left(\pm 0.079\right) $$where Na, Ti, Al(t), and Si are molar proportions relative to 6O. This formulation accounts for the jadeite (NaAlSi2O6) component, herein computed from the Na contents, corrected for the Ti-diopside (CaMgTi2O6) component in clinopyroxene and also considers the evolutionary trend from Mg-augite to ferroan diopside. It applies to alkali ultrabasic to intermediate compositions in the examined P–T–ƒO2 range, resulting in more accurate estimates than the available calibrations. The MgO-in-melt thermometer was optimized for the studied compositions at one-atmosphere pressure and anhydrous conditions, as follows:$$ T\ \left(\pm 5{}^{\circ}C,1\sigma \right)=27.35\left(\pm 0.65\right)\ \big({MgO}^{liq}\big)+984\left(\pm 4\right) $$which provides much more reliable liquidus temperatures for these alkali systems. Given data restriction, this formulation may be expanded to include the pressure effects for relatively low-H2O (< 3 wt.%) systems as:$$ T\ \left(\pm 20{}^{\circ}C,1\sigma \right)=27.35\left(\pm 0.65\right)\big({MgO}^{liq}\big)+80.20\left(\pm 5.50\right)P(GPa)+981\left(\pm 4\right) $$
期刊介绍:
The Journal of Petrology provides an international forum for the publication of high quality research in the broad field of igneous and metamorphic petrology and petrogenesis. Papers published cover a vast range of topics in areas such as major element, trace element and isotope geochemistry and geochronology applied to petrogenesis; experimental petrology; processes of magma generation, differentiation and emplacement; quantitative studies of rock-forming minerals and their paragenesis; regional studies of igneous and meta morphic rocks which contribute to the solution of fundamental petrological problems; theoretical modelling of petrogenetic processes.