一个挑战

IF 1.1 4区化学 Q3 CHEMISTRY, MULTIDISCIPLINARY

Journal of the Mexican Chemical Society Pub Date : 2023-10-02 DOI:10.29356/jmcs.v67i4.2077

R. Daniel Little

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引用次数: 0

摘要

目前的贡献概述了我的小组在介导电子转移领域参与的几个方面。从其先驱的实验室到今天，这一领域一直保持着人们的兴趣和根本重要性，现在已被广泛接受和利用。我首先简要回顾一下基础知识，我们将: & # x0D;区分间接电解和直接电解; 强调它与敏化光解的相似性; 探索与中介过程相关的步骤/阶段，特别关注电子转移步骤的动力学和热力学; 描述如何克服经常伴随着电子转移的热力学僵局。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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A Challenge

The present contribution overviews several aspects of my groups’ involvement in the field of mediated electron transfer. From the laboratories of its pioneers to the present day, the field maintains a position of interest and fundamental importance, and is now widely accepted and utilized. I begin with a brief review of the basics where we will: differentiate mediated and direct electrolysis; highlight similarities between it and sensitized photolyses; explore the steps/stages associated with a mediated process focusing particularly upon the kinetics and thermodynamics of the electron transfer step; describe how to overcome the thermodynamic impasse that frequently accompanies electron transfer.

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来源期刊

Journal of the Mexican Chemical Society 化学-化学综合

CiteScore

2.00

自引率

0.00%

发文量

审稿时长

6-12 weeks

期刊介绍： The Journal of the Mexican Chemical Society (J. Mex. Chem. Soc.) is a scientific, blind, peer reviewed, and open access, free of charge publication that covers all areas of chemistry and its sub-disciplines (i.e. medicinal chemistry, natural products, electrochemistry, material science, computational chemistry, organic chemistry, bionirganic chemistry, etc). It is devoted to facilitating the worldwide advancement of our understanding of chemistry. It will primarily publish original contributions of research in all branches of the theory and practice of chemistry in its broadest context as well as critical reviews in active areas of chemical research where the author has published significant contribution. The J. Mex. Chem. Soc. is a quarterly publication which language of submission and publication is English. To be suitable for publication in J. Mex. Chem. Soc., manuscripts must describe novel aspects of chemistry, high quality of results and discussion an excellent bibliographic support, and contribute to the development of the field. Routine or incremental work are not suitable for publication in J. Mex. Chem. Soc. Authors are encouraged to send contributions in electronic form. Our online submission system guides you stepwise through the process of entering your article details and uploading your files.