电化学过程在金属和合金萃取中的作用综述

Mohammad Shamsuddin, Hong Yong Sohn
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摘要

本文综述了从水溶液和熔盐电解质中回收金属的电化学原理。在这篇文章中,我们集中讨论了不同类型金属的电解加工,重点是电化学原理以及自由能和活度在普通金属和活性金属的电积和电精炼中的重要作用。根据放电电位的不同,将金属分为三种类型:无析氢的水溶液沉积、氢过电压下沉积和仅熔融电解质沉积。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Role of electrochemical processes in the extraction of metals and alloys – a review
This review discusses the electrochemical principles involved in the recovery of metals from aqueous solutions and fused salt electrolytes. In this article we concentrate on electrolytic processing of different types of metals with an emphasis on the significant role of electrochemical principles together with free energy and activity in electrowinning and electrorefining of common and reactive metals. Based on discharge potentials, metals are classified into three categories with respect to their characteristics of deposition from aqueous electrolytes without hydrogen evolution, under hydrogen over-voltage, and only from fused electrolytes.
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