Tarjei Heggset, Ole Meyer, Luis Tay Wo Chong Hilares, Andrea Ciani, Andrea Gruber
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However, ammonia combustion is governed by widely different thermo-chemical processes compared to hydrogen, requiring a considerably different approach to mitigate crucial issues with extremely low flame reactivity (blow-out) and formation of significant amounts of undesired pollutants and greenhouse gases (NOx and N2O). In this work, we present a fuel-flexible operational concept for the CPSC system and, based on unsteady Reynolds-Averaged Navier-Stokes (uRANS) and Large Eddy Simulation (LES) performed in conjunction with detailed chemical kinetics, we explore for the first time full-load operation of the CPSC architecture in a Rich-Quench-Lean (RQL) strategy applied to combustion of partially-decomposed ammonia. Results from the numerical simulations confirm the main features of ammonia-firing in RQL operation already observed from previous work on different combustion systems and suggests that the CPSC architecture has excellent potential to operate in RQL-mode with low NOx and N2O emissions and good combustion efficiency.","PeriodicalId":1,"journal":{"name":"Accounts of Chemical Research","volume":null,"pages":null},"PeriodicalIF":16.4000,"publicationDate":"2023-11-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Numerical Assessment of a Rich-Quench-Lean Staging Strategy for Clean and Efficient Combustion of Partially Decomposed Ammonia in the Constant Pressure Sequential Combustion System\",\"authors\":\"Tarjei Heggset, Ole Meyer, Luis Tay Wo Chong Hilares, Andrea Ciani, Andrea Gruber\",\"doi\":\"10.1115/1.4063958\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Abstract In a future energy-system prospective, predictably dominated by (often) remote and (always) unsteady, non-dispatchable renewable power generation from solar and wind resources, hydrogen (H2) and ammonia (NH3) have emerged as logistically convenient, chemically-simple and carbon-free chemicals for energy transport and storage. In this context, a convenient feature of Ansaldo's Constant Pressure Sequential Combustion (CPSC) system, resulting in a fundamental advantage compared to alternative approaches, is the possibility of controlling the amount of fuel independently fed to the two combustion stages, depending on the fuel reactivity and combustion characteristics. However, ammonia combustion is governed by widely different thermo-chemical processes compared to hydrogen, requiring a considerably different approach to mitigate crucial issues with extremely low flame reactivity (blow-out) and formation of significant amounts of undesired pollutants and greenhouse gases (NOx and N2O). In this work, we present a fuel-flexible operational concept for the CPSC system and, based on unsteady Reynolds-Averaged Navier-Stokes (uRANS) and Large Eddy Simulation (LES) performed in conjunction with detailed chemical kinetics, we explore for the first time full-load operation of the CPSC architecture in a Rich-Quench-Lean (RQL) strategy applied to combustion of partially-decomposed ammonia. 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Numerical Assessment of a Rich-Quench-Lean Staging Strategy for Clean and Efficient Combustion of Partially Decomposed Ammonia in the Constant Pressure Sequential Combustion System
Abstract In a future energy-system prospective, predictably dominated by (often) remote and (always) unsteady, non-dispatchable renewable power generation from solar and wind resources, hydrogen (H2) and ammonia (NH3) have emerged as logistically convenient, chemically-simple and carbon-free chemicals for energy transport and storage. In this context, a convenient feature of Ansaldo's Constant Pressure Sequential Combustion (CPSC) system, resulting in a fundamental advantage compared to alternative approaches, is the possibility of controlling the amount of fuel independently fed to the two combustion stages, depending on the fuel reactivity and combustion characteristics. However, ammonia combustion is governed by widely different thermo-chemical processes compared to hydrogen, requiring a considerably different approach to mitigate crucial issues with extremely low flame reactivity (blow-out) and formation of significant amounts of undesired pollutants and greenhouse gases (NOx and N2O). In this work, we present a fuel-flexible operational concept for the CPSC system and, based on unsteady Reynolds-Averaged Navier-Stokes (uRANS) and Large Eddy Simulation (LES) performed in conjunction with detailed chemical kinetics, we explore for the first time full-load operation of the CPSC architecture in a Rich-Quench-Lean (RQL) strategy applied to combustion of partially-decomposed ammonia. Results from the numerical simulations confirm the main features of ammonia-firing in RQL operation already observed from previous work on different combustion systems and suggests that the CPSC architecture has excellent potential to operate in RQL-mode with low NOx and N2O emissions and good combustion efficiency.
期刊介绍:
Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance.
Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.