{"title":"纳米tio2 -对苯二酚掺杂Al复合材料的制备、表征及磨损性能研究","authors":"Fatma Bilge Emre, Süleyman Köytepe, Erkan Bahçe","doi":"10.1134/S2070205123700867","DOIUrl":null,"url":null,"abstract":"<p>In this study, the preparation of nanoporous-TiO<sub>2</sub>-doped Al composites with improved mechanical properties and wear resistance was carried out. For this purpose, nanosized TiO<sub>2</sub> structures were first synthesized using the hydrothermal synthesis method. The size distribution, morphology, and chemical structure of the obtained TiO<sub>2</sub> particles were investigated by particle size analyzer, SEM, XRD, and FTIR spectroscopy techniques. At the same time, TiO<sub>2</sub> structures containing hydroquinone (Hq) at different rates (5, 10, and 15%) were prepared in order to ensure homogeneous TiO<sub>2</sub> distribution during the formation of Al matrix composites and to prevent oxidation that may occur during composite casting. TiO<sub>2</sub>–Al composite structures were obtained by doping the synthesized pure TiO<sub>2</sub> nanoparticles and TiO<sub>2</sub> nanoparticles containing hydroquinone in different ratios to the Al matrix structure. The obtained composite structures were examined structurally by FTIR and XRD spectroscopy techniques. Then, the thermal properties of the composite structures obtained were examined by TGA analysis. Morphological properties, microstructure, and surface elemental distribution of the composite structure were investigated by SEM and EDX techniques. The abrasion properties of the obtained TiO<sub>2</sub> added Al composite structures were investigated using SiC papers (200–400–600 and 800–1200 mesh). As a result, it was observed that the doped TiO<sub>2</sub> nanoparticles reduced surface deformation during abrasion.</p>","PeriodicalId":745,"journal":{"name":"Protection of Metals and Physical Chemistry of Surfaces","volume":"59 5","pages":"911 - 921"},"PeriodicalIF":1.1000,"publicationDate":"2023-11-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Preparation and Characterization of Nano TiO2–Hydroquinone-Doped Al Composites and Investigation of Theirs Wear Properties\",\"authors\":\"Fatma Bilge Emre, Süleyman Köytepe, Erkan Bahçe\",\"doi\":\"10.1134/S2070205123700867\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>In this study, the preparation of nanoporous-TiO<sub>2</sub>-doped Al composites with improved mechanical properties and wear resistance was carried out. For this purpose, nanosized TiO<sub>2</sub> structures were first synthesized using the hydrothermal synthesis method. The size distribution, morphology, and chemical structure of the obtained TiO<sub>2</sub> particles were investigated by particle size analyzer, SEM, XRD, and FTIR spectroscopy techniques. At the same time, TiO<sub>2</sub> structures containing hydroquinone (Hq) at different rates (5, 10, and 15%) were prepared in order to ensure homogeneous TiO<sub>2</sub> distribution during the formation of Al matrix composites and to prevent oxidation that may occur during composite casting. TiO<sub>2</sub>–Al composite structures were obtained by doping the synthesized pure TiO<sub>2</sub> nanoparticles and TiO<sub>2</sub> nanoparticles containing hydroquinone in different ratios to the Al matrix structure. The obtained composite structures were examined structurally by FTIR and XRD spectroscopy techniques. Then, the thermal properties of the composite structures obtained were examined by TGA analysis. Morphological properties, microstructure, and surface elemental distribution of the composite structure were investigated by SEM and EDX techniques. The abrasion properties of the obtained TiO<sub>2</sub> added Al composite structures were investigated using SiC papers (200–400–600 and 800–1200 mesh). As a result, it was observed that the doped TiO<sub>2</sub> nanoparticles reduced surface deformation during abrasion.</p>\",\"PeriodicalId\":745,\"journal\":{\"name\":\"Protection of Metals and Physical Chemistry of Surfaces\",\"volume\":\"59 5\",\"pages\":\"911 - 921\"},\"PeriodicalIF\":1.1000,\"publicationDate\":\"2023-11-02\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Protection of Metals and Physical Chemistry of Surfaces\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S2070205123700867\",\"RegionNum\":4,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"METALLURGY & METALLURGICAL ENGINEERING\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Protection of Metals and Physical Chemistry of Surfaces","FirstCategoryId":"88","ListUrlMain":"https://link.springer.com/article/10.1134/S2070205123700867","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"METALLURGY & METALLURGICAL ENGINEERING","Score":null,"Total":0}
Preparation and Characterization of Nano TiO2–Hydroquinone-Doped Al Composites and Investigation of Theirs Wear Properties
In this study, the preparation of nanoporous-TiO2-doped Al composites with improved mechanical properties and wear resistance was carried out. For this purpose, nanosized TiO2 structures were first synthesized using the hydrothermal synthesis method. The size distribution, morphology, and chemical structure of the obtained TiO2 particles were investigated by particle size analyzer, SEM, XRD, and FTIR spectroscopy techniques. At the same time, TiO2 structures containing hydroquinone (Hq) at different rates (5, 10, and 15%) were prepared in order to ensure homogeneous TiO2 distribution during the formation of Al matrix composites and to prevent oxidation that may occur during composite casting. TiO2–Al composite structures were obtained by doping the synthesized pure TiO2 nanoparticles and TiO2 nanoparticles containing hydroquinone in different ratios to the Al matrix structure. The obtained composite structures were examined structurally by FTIR and XRD spectroscopy techniques. Then, the thermal properties of the composite structures obtained were examined by TGA analysis. Morphological properties, microstructure, and surface elemental distribution of the composite structure were investigated by SEM and EDX techniques. The abrasion properties of the obtained TiO2 added Al composite structures were investigated using SiC papers (200–400–600 and 800–1200 mesh). As a result, it was observed that the doped TiO2 nanoparticles reduced surface deformation during abrasion.
期刊介绍:
Protection of Metals and Physical Chemistry of Surfaces is an international peer reviewed journal that publishes articles covering all aspects of the physical chemistry of materials and interfaces in various environments. The journal covers all related problems of modern physical chemistry and materials science, including: physicochemical processes at interfaces; adsorption phenomena; complexing from molecular and supramolecular structures at the interfaces to new substances, materials and coatings; nanoscale and nanostructured materials and coatings, composed and dispersed materials; physicochemical problems of corrosion, degradation and protection; investigation methods for surface and interface systems, processes, structures, materials and coatings. No principe restrictions exist related systems, types of processes, methods of control and study. The journal welcomes conceptual, theoretical, experimental, methodological, instrumental, environmental, and all other possible studies.