纳米tio2 -对苯二酚掺杂Al复合材料的制备、表征及磨损性能研究

IF 1.1 4区 材料科学 Q3 METALLURGY & METALLURGICAL ENGINEERING
Fatma Bilge Emre, Süleyman Köytepe, Erkan Bahçe
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引用次数: 0

摘要

在本研究中,制备了具有改善力学性能和耐磨性的纳米多孔tio2掺杂Al复合材料。为此,首先采用水热合成的方法合成了纳米TiO2结构。采用粒度分析仪、SEM、XRD和FTIR等技术对制备的TiO2颗粒的粒度分布、形貌和化学结构进行了表征。同时,制备了含对苯二酚(Hq)的不同比例(5%、10%和15%)的TiO2结构,以确保Al基复合材料形成过程中TiO2分布均匀,防止复合材料铸造过程中可能发生的氧化。将合成的纯TiO2纳米粒子和含对苯二酚的TiO2纳米粒子以不同比例掺杂到Al基结构中,得到TiO2 - Al复合结构。采用FTIR和XRD光谱技术对复合材料结构进行了结构表征。然后,对所得复合材料的热性能进行了热重分析。利用扫描电镜和EDX技术对复合材料的形貌、微观结构和表面元素分布进行了研究。采用SiC纸(200-400-600目和800-1200目)对制备的TiO2 - Al复合材料结构的耐磨性进行了研究。结果表明,掺杂TiO2纳米粒子减少了磨损过程中的表面变形。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Preparation and Characterization of Nano TiO2–Hydroquinone-Doped Al Composites and Investigation of Theirs Wear Properties

Preparation and Characterization of Nano TiO2–Hydroquinone-Doped Al Composites and Investigation of Theirs Wear Properties

In this study, the preparation of nanoporous-TiO2-doped Al composites with improved mechanical properties and wear resistance was carried out. For this purpose, nanosized TiO2 structures were first synthesized using the hydrothermal synthesis method. The size distribution, morphology, and chemical structure of the obtained TiO2 particles were investigated by particle size analyzer, SEM, XRD, and FTIR spectroscopy techniques. At the same time, TiO2 structures containing hydroquinone (Hq) at different rates (5, 10, and 15%) were prepared in order to ensure homogeneous TiO2 distribution during the formation of Al matrix composites and to prevent oxidation that may occur during composite casting. TiO2–Al composite structures were obtained by doping the synthesized pure TiO2 nanoparticles and TiO2 nanoparticles containing hydroquinone in different ratios to the Al matrix structure. The obtained composite structures were examined structurally by FTIR and XRD spectroscopy techniques. Then, the thermal properties of the composite structures obtained were examined by TGA analysis. Morphological properties, microstructure, and surface elemental distribution of the composite structure were investigated by SEM and EDX techniques. The abrasion properties of the obtained TiO2 added Al composite structures were investigated using SiC papers (200–400–600 and 800–1200 mesh). As a result, it was observed that the doped TiO2 nanoparticles reduced surface deformation during abrasion.

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来源期刊
CiteScore
1.90
自引率
18.20%
发文量
90
审稿时长
4-8 weeks
期刊介绍: Protection of Metals and Physical Chemistry of Surfaces is an international peer reviewed journal that publishes articles covering all aspects of the physical chemistry of materials and interfaces in various environments. The journal covers all related problems of modern physical chemistry and materials science, including: physicochemical processes at interfaces; adsorption phenomena; complexing from molecular and supramolecular structures at the interfaces to new substances, materials and coatings; nanoscale and nanostructured materials and coatings, composed and dispersed materials; physicochemical problems of corrosion, degradation and protection; investigation methods for surface and interface systems, processes, structures, materials and coatings. No principe restrictions exist related systems, types of processes, methods of control and study. The journal welcomes conceptual, theoretical, experimental, methodological, instrumental, environmental, and all other possible studies.
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