[6-(呋喃-2-基)-2,2 ' -联吡啶]二(三苯基膦)四氟硼酸铜

IF 0.6 Q4 CHEMISTRY, ORGANIC

Molbank Pub Date : 2023-09-13 DOI:10.3390/m1724

Panagiotis Kouvatsis, Dimitrios Glykos, John C. Plakatouras, Gerasimos Malandrinos

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引用次数: 0

摘要

新型杂电性Cu(I)配合物[Cu(L)(PPh3)2][BF4] (L = 6-(呋喃-2-基)-2,2′-联吡啶;成功合成了三苯基膦(PPh3 = triphenylphosphine)。用x射线晶体学确定了其分子结构，核磁共振和HR-ESI-MS数据证实了该化合物在溶液中的完整性。该配合物仅在固态(λem = 576 nm)下发光，光致发光量子产率为2.5%。

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[6-(Furan-2-yl)-2,2′-bipyridine]bis(triphenylphosphine) Copper(I) Tetrafluoroborate

A new heteroleptic Cu(I) complex, [Cu(L)(PPh3)2][BF4] (L = 6-(furan-2-yl)-2,2′-bipyridine; PPh3 = triphenylphosphine), was successfully synthesized and characterized. Its molecular structure was determined using X-ray crystallography, and NMR as well as HR-ESI-MS data confirm the compound’s integrity in solution. The complex exhibits emission solely in the solid state (λem = 576 nm) and demonstrates a photoluminescence quantum yield of 2.5%.

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来源期刊

Molbank Chemistry-Physical and Theoretical Chemistry

CiteScore

0.70

自引率

33.30%

发文量

174

审稿时长

11 weeks

期刊介绍： •organic synthesis •biosynthesis •extraction and purification •natural product derivatives •structural elucidation (X-ray crystallography, NMR, etc.)