EVALUATION OF AN HPHT UNIT COUPLED WITH NIR PROBE TO DETERMINE ASPHALTENES PRECIPITATION ONSET UNDER DIFFERENT PRESSURES

Asphaltenes are characterized as the crude oil fraction with the highest molar mass and polarity, presetting mainly (poly) aromatic groups. The flocculation and deposition of asphaltenes causes large losses to the oil industry. Understanding the phase behavior of asphaltenes under conditions closer to those found in reservoirs is important. Therefore, LMCP/UFRJ started operating a high-pressure high-temperature (HPHT) unit coupled to a near-infrared spectrometer probe that can use different flocculants. This work describes the development of a procedure as well as the validation of the results obtained from this unit. Due to the complex composition of crude oil, model systems (MS) were prepared with asphaltenes extracted with n-pentane (C5I) and n-heptane (C7I). The experiments were carried out at atmospheric pressure, titrated with n-heptane, and at 100 and 300 bar titrated with propane. As expected, C7I asphaltenes were more unstable, presenting lower precipitation onset than C5I asphaltenes under ambient conditions and higher pressures. However, for both MS, the stability increased with rising pressure when using propane as a solvent. The proposed method to evaluate asphaltenes precipitation onset was effective for MS in toluene and dead crude oil, and is a promising alternative for investigation of different types of crude oil.