用连接功能化嵌段共聚物在聚合物太阳能电池中选择性组装苝酰二亚胺给受体界面

IF 0.3 4区工程技术 Q4 MATERIALS SCIENCE, TEXTILES

Journal of Fiber Science and Technology Pub Date : 2023-01-01 DOI:10.2115/fiberst.2023-0030

Kousuke Tsuchiya, Sicong Qian, Kenji Ando, Kenji Ogino

{"title":"用连接功能化嵌段共聚物在聚合物太阳能电池中选择性组装苝酰二亚胺给受体界面","authors":"Kousuke Tsuchiya, Sicong Qian, Kenji Ando, Kenji Ogino","doi":"10.2115/fiberst.2023-0030","DOIUrl":null,"url":null,"abstract":"Novel block copolymers consisting of poly (3-hexylthiophene) (P3HT)/ poly (dimethylsiloxane) (PDMS) or P3HT / poly (ethylene glycol) (PEO) with a perylenediimide (PDI) unit at the junction between the segments were synthesized and utilized for donor materials in polymer solar cells. In the blend film of junction-modified block copolymer and [6,6]-phenyl-C61-butyric acid methyl ester (PCBM), the PDI unit introduced at the junction of block copolymers assembled at the interface of donor/acceptor domains. A distinctive phase-separated morphology was created in the block copolymer blend film, which provided higher device performance compared with a conventional polymer blend system.","PeriodicalId":54299,"journal":{"name":"Journal of Fiber Science and Technology","volume":"159 1","pages":"0"},"PeriodicalIF":0.3000,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Selective Assembly of Perylene Diimide into Donor-Acceptor Interface in Polymer Solar Cells by Junction-Functionalized Block Copolymer\",\"authors\":\"Kousuke Tsuchiya, Sicong Qian, Kenji Ando, Kenji Ogino\",\"doi\":\"10.2115/fiberst.2023-0030\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Novel block copolymers consisting of poly (3-hexylthiophene) (P3HT)/ poly (dimethylsiloxane) (PDMS) or P3HT / poly (ethylene glycol) (PEO) with a perylenediimide (PDI) unit at the junction between the segments were synthesized and utilized for donor materials in polymer solar cells. In the blend film of junction-modified block copolymer and [6,6]-phenyl-C61-butyric acid methyl ester (PCBM), the PDI unit introduced at the junction of block copolymers assembled at the interface of donor/acceptor domains. A distinctive phase-separated morphology was created in the block copolymer blend film, which provided higher device performance compared with a conventional polymer blend system.\",\"PeriodicalId\":54299,\"journal\":{\"name\":\"Journal of Fiber Science and Technology\",\"volume\":\"159 1\",\"pages\":\"0\"},\"PeriodicalIF\":0.3000,\"publicationDate\":\"2023-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Fiber Science and Technology\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.2115/fiberst.2023-0030\",\"RegionNum\":4,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"MATERIALS SCIENCE, TEXTILES\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Fiber Science and Technology","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.2115/fiberst.2023-0030","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"MATERIALS SCIENCE, TEXTILES","Score":null,"Total":0}

引用次数: 0

摘要

合成了由聚(3-己基噻吩)(P3HT)/聚二甲基硅氧烷(PDMS)或P3HT /聚乙二醇(PEO)组成的新型嵌段共聚物，在节段之间的连接处有一个苝二酰亚胺(PDI)单元，并将其用于聚合物太阳能电池的供体材料。在连接改性嵌段共聚物与[6,6]-苯基- c61 -丁酸甲酯(PCBM)共混膜中，在供体/受体界面组装的嵌段共聚物的连接处引入了PDI单元。在嵌段共聚物共混膜中形成了独特的相分离形态，与传统的聚合物共混体系相比，提供了更高的器件性能。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

查看原文本刊更多论文

Selective Assembly of Perylene Diimide into Donor-Acceptor Interface in Polymer Solar Cells by Junction-Functionalized Block Copolymer

Novel block copolymers consisting of poly (3-hexylthiophene) (P3HT)/ poly (dimethylsiloxane) (PDMS) or P3HT / poly (ethylene glycol) (PEO) with a perylenediimide (PDI) unit at the junction between the segments were synthesized and utilized for donor materials in polymer solar cells. In the blend film of junction-modified block copolymer and [6,6]-phenyl-C61-butyric acid methyl ester (PCBM), the PDI unit introduced at the junction of block copolymers assembled at the interface of donor/acceptor domains. A distinctive phase-separated morphology was created in the block copolymer blend film, which provided higher device performance compared with a conventional polymer blend system.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Journal of Fiber Science and Technology Materials Science-Materials Science (miscellaneous)

CiteScore

0.50

自引率

0.00%

发文量