{"title":"氧化镍改性蒙脱土复合材料吸附去除水中亚甲基蓝染料","authors":"","doi":"10.56042/ijct.v30i6.6546","DOIUrl":null,"url":null,"abstract":"In this study, the adsorptive removal of methylene blue (MB) from aqueous solutions onto nickel oxide (NiO) modified montmorillonite (NiO-Mt) has been studied and compared with that of commercial bentonite. The influences of various experimental factors such as contact time, adsorbent dosage, pH of solution, initial dye concentration and temperature have been investigated. Batch adsorption studies has manifested that the maximum adsorption capacity of MB is around 99.9 mg/g in 10 min with 25 mg adsorbent mass at an initial concentration of 100 mg/L at ambient temperature of 25°C and natural pH of solution (pH = 5.8 for NiO-Mt and pH = 6.3 for commercial bentonite). The adsorption kinetics and isotherms are well fitted by pseudo-second order and Langmuir models, respectively. The thermodynamic parameters such as the changes in Gibbs free energy, enthalpy, and entropy are determined. The MB adsorption is physical, spontaneous and exothermic for both adsorbents.","PeriodicalId":13388,"journal":{"name":"Indian Journal of Chemical Technology","volume":null,"pages":null},"PeriodicalIF":0.5000,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Removal of methylene blue dye from aqueous media by adsorption using nickel oxide modified montmorillonite composite\",\"authors\":\"\",\"doi\":\"10.56042/ijct.v30i6.6546\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"In this study, the adsorptive removal of methylene blue (MB) from aqueous solutions onto nickel oxide (NiO) modified montmorillonite (NiO-Mt) has been studied and compared with that of commercial bentonite. The influences of various experimental factors such as contact time, adsorbent dosage, pH of solution, initial dye concentration and temperature have been investigated. Batch adsorption studies has manifested that the maximum adsorption capacity of MB is around 99.9 mg/g in 10 min with 25 mg adsorbent mass at an initial concentration of 100 mg/L at ambient temperature of 25°C and natural pH of solution (pH = 5.8 for NiO-Mt and pH = 6.3 for commercial bentonite). The adsorption kinetics and isotherms are well fitted by pseudo-second order and Langmuir models, respectively. The thermodynamic parameters such as the changes in Gibbs free energy, enthalpy, and entropy are determined. The MB adsorption is physical, spontaneous and exothermic for both adsorbents.\",\"PeriodicalId\":13388,\"journal\":{\"name\":\"Indian Journal of Chemical Technology\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.5000,\"publicationDate\":\"2023-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Indian Journal of Chemical Technology\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.56042/ijct.v30i6.6546\",\"RegionNum\":4,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, APPLIED\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Indian Journal of Chemical Technology","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.56042/ijct.v30i6.6546","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, APPLIED","Score":null,"Total":0}
Removal of methylene blue dye from aqueous media by adsorption using nickel oxide modified montmorillonite composite
In this study, the adsorptive removal of methylene blue (MB) from aqueous solutions onto nickel oxide (NiO) modified montmorillonite (NiO-Mt) has been studied and compared with that of commercial bentonite. The influences of various experimental factors such as contact time, adsorbent dosage, pH of solution, initial dye concentration and temperature have been investigated. Batch adsorption studies has manifested that the maximum adsorption capacity of MB is around 99.9 mg/g in 10 min with 25 mg adsorbent mass at an initial concentration of 100 mg/L at ambient temperature of 25°C and natural pH of solution (pH = 5.8 for NiO-Mt and pH = 6.3 for commercial bentonite). The adsorption kinetics and isotherms are well fitted by pseudo-second order and Langmuir models, respectively. The thermodynamic parameters such as the changes in Gibbs free energy, enthalpy, and entropy are determined. The MB adsorption is physical, spontaneous and exothermic for both adsorbents.
期刊介绍:
Indian Journal of Chemical Technology has established itself as the leading journal in the exciting field of chemical engineering and technology. It is intended for rapid communication of knowledge and experience to engineers and scientists working in the area of research development or practical application of chemical technology. This bimonthly journal includes novel and original research findings as well as reviews in the areas related to – Chemical Engineering, Catalysis, Leather Processing, Polymerization, Membrane Separation, Pharmaceuticals and Drugs, Agrochemicals, Reaction Engineering, Biochemical Engineering, Petroleum Technology, Corrosion & Metallurgy and Applied Chemistry.