Marzena Czapnik, Michał Tylman, Maciej Jaskulski, Paweł Wawrzyniak
{"title":"用化学热泵进行热回收","authors":"Marzena Czapnik, Michał Tylman, Maciej Jaskulski, Paweł Wawrzyniak","doi":"10.24425/cpe.2019.130206","DOIUrl":null,"url":null,"abstract":"Chemical heat pumps (CHP) use reversible exothermal and endothermal chemical reactions to increase the temperature of working fluids. In comparison to the “classical” vapour compression chemical heat pumps, CHP enables us to achieve significantly higher temperatures of a heated medium which is crucial for the potential application, e.g. for production of superheated steam. Despite the advantages presented, currently, there are no installations using CHP for lowgrade waste heat recovery available on the market. The scaling up of industrial processes is still one of the greatest challenges of process engineering. The aim of the theoretical and experimental concept study presented here was to evaluate a method of reclaiming energy from low temperature waste streams and converting it into a saturated steam of temperature from 120 to 150 ◦ C, which can be useful in industry. A chemical heat pump concept, based on the dilution and concentration of phosphoric acid, was used to test the method in the laboratory scale. The heat of dilution and energy needed for water evaporation from the acid solution were experimentally measured. The cycle of successive processes of dilution and concentration has been experimentally confirmed. A theoretical model of the chemical heat pump was tested and coefficient of performance measured.","PeriodicalId":55267,"journal":{"name":"Chemical and Process Engineering-Inzynieria Chemiczna I Procesowa","volume":"337 1","pages":"0"},"PeriodicalIF":0.5000,"publicationDate":"2023-11-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Heat recovery with chemical heat pump\",\"authors\":\"Marzena Czapnik, Michał Tylman, Maciej Jaskulski, Paweł Wawrzyniak\",\"doi\":\"10.24425/cpe.2019.130206\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Chemical heat pumps (CHP) use reversible exothermal and endothermal chemical reactions to increase the temperature of working fluids. In comparison to the “classical” vapour compression chemical heat pumps, CHP enables us to achieve significantly higher temperatures of a heated medium which is crucial for the potential application, e.g. for production of superheated steam. Despite the advantages presented, currently, there are no installations using CHP for lowgrade waste heat recovery available on the market. The scaling up of industrial processes is still one of the greatest challenges of process engineering. The aim of the theoretical and experimental concept study presented here was to evaluate a method of reclaiming energy from low temperature waste streams and converting it into a saturated steam of temperature from 120 to 150 ◦ C, which can be useful in industry. A chemical heat pump concept, based on the dilution and concentration of phosphoric acid, was used to test the method in the laboratory scale. The heat of dilution and energy needed for water evaporation from the acid solution were experimentally measured. The cycle of successive processes of dilution and concentration has been experimentally confirmed. A theoretical model of the chemical heat pump was tested and coefficient of performance measured.\",\"PeriodicalId\":55267,\"journal\":{\"name\":\"Chemical and Process Engineering-Inzynieria Chemiczna I Procesowa\",\"volume\":\"337 1\",\"pages\":\"0\"},\"PeriodicalIF\":0.5000,\"publicationDate\":\"2023-11-06\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chemical and Process Engineering-Inzynieria Chemiczna I Procesowa\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.24425/cpe.2019.130206\",\"RegionNum\":4,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"ENGINEERING, CHEMICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemical and Process Engineering-Inzynieria Chemiczna I Procesowa","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.24425/cpe.2019.130206","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"ENGINEERING, CHEMICAL","Score":null,"Total":0}
Chemical heat pumps (CHP) use reversible exothermal and endothermal chemical reactions to increase the temperature of working fluids. In comparison to the “classical” vapour compression chemical heat pumps, CHP enables us to achieve significantly higher temperatures of a heated medium which is crucial for the potential application, e.g. for production of superheated steam. Despite the advantages presented, currently, there are no installations using CHP for lowgrade waste heat recovery available on the market. The scaling up of industrial processes is still one of the greatest challenges of process engineering. The aim of the theoretical and experimental concept study presented here was to evaluate a method of reclaiming energy from low temperature waste streams and converting it into a saturated steam of temperature from 120 to 150 ◦ C, which can be useful in industry. A chemical heat pump concept, based on the dilution and concentration of phosphoric acid, was used to test the method in the laboratory scale. The heat of dilution and energy needed for water evaporation from the acid solution were experimentally measured. The cycle of successive processes of dilution and concentration has been experimentally confirmed. A theoretical model of the chemical heat pump was tested and coefficient of performance measured.
期刊介绍:
The content, aim and scope of the proposals should comply with the main subject of the journal, i.e. they should deal with mathematical modelling and/or experimental investigations on momentum, heat and mass transfer, unit processes and operations, integrated processes, biochemical engineering, statics and kinetics of chemical reactions. The experiments and modelling may cover different scales and processes ranging from the molecular phenomena up to production systems. The journal language is grammatically correct British English.
Chemical and Process Engineering publishes: i) full text research articles, ii) invited reviews, iii) letters to the editor and iv) short communications, aiming at important new results and/or applications. Each of the publication form is peer-reviewed by at least two independent referees.