有机合成新技术简介:颗粒聚四氟乙烯促进高熔点稀溶底物的水反应研究进展

IF 1.9 4区化学 Q2 CHEMISTRY, ORGANIC

Mini-reviews in Organic Chemistry Pub Date : 2023-10-05 DOI:10.2174/0118756298253318230929034500

Linlin Xing, Yong Zhang, Taixuan Jia, Chunbao Li

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引用次数: 0

摘要

摘要:水作为一种丰富的自然资源，因其成本低、安全性高、环境友好而被认为是一种绿色、理想的溶剂。本文简要介绍了在颗粒聚四氟乙烯(PTFE)的辅助下，利用水作为反应介质，在大多数情况下以绿色、定量、快速和立体选择性的方式介导一系列水不溶性和高熔点底物的反应的方法。此外，本文的综述将有助于进一步研究颗粒聚四氟乙烯促进这些水反应的实际应用和机理，以合成新的有趣的结构。

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Introduction to a New Technique in Organic Synthesis: Recent Advances in Aqueous Reactions of Sparingly Soluble High-Melting Point Substrates Promoted by Granular Polytetrafluoroethylene

Abstract: Water, a kind of abundant natural resource, is considered to be a green and desirable solvent for reasons of its low cost, high safety and environmental friendliness. This review article aims to briefly introduce the methodologies that have utilized water as reaction media under the aid of granular polytetrafluoroethylene (PTFE) to mediate reactions of a series of water-insoluble and high melting points substrates in a green, quantitative, fast, and stereoselective way in most situations. Besides, this review will be helpful to stimulate further study on both practical applications and mechanistic understanding of these aqueous reactions promoted by granular PTFE for the novel synthesis of interesting structures.

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来源期刊

Mini-reviews in Organic Chemistry 化学-有机化学

CiteScore

4.50

自引率

4.30%

发文量

116

审稿时长

>12 weeks

期刊介绍： Mini-Reviews in Organic Chemistry is a peer reviewed journal which publishes original reviews on all areas of organic chemistry including organic synthesis, bioorganic and medicinal chemistry, natural product chemistry, molecular recognition, and physical organic chemistry. The emphasis will be on publishing quality papers very rapidly, without any charges. The journal encourages submission of reviews on emerging fields of organic chemistry including: Bioorganic Chemistry Carbohydrate Chemistry Chemical Biology Chemical Process Research Computational Organic Chemistry Development of Synthetic Methodologies Functional Organic Materials Heterocyclic Chemistry Macromolecular Chemistry Natural Products Isolation And Synthesis New Synthetic Methodology Organic Reactions Organocatalysis Organometallic Chemistry Theoretical Organic Chemistry Polymer Chemistry Stereochemistry Structural Investigations Supramolecular Chemistry