{"title":"非晶态聚合物在高温和低温状态下变形的非线性效应","authors":"V. D. Natsik, H. V. Rusakova","doi":"10.1063/10.0021378","DOIUrl":null,"url":null,"abstract":"One of the important problems of the modern rheology of polymer materials, namely, the possibility of describing the deformation of amorphous polymers within the framework of linear rheological relationships between relative deformation and deforming stress or the need to use nonlinear rheological equations is considered. The criteria for distinguishing these approaches, namely, the determination of the corresponding critical values of the macro- and microphysical characteristics of the material and the conditions for carrying out the mechanical tests are also discussed. In particular, the difference between the influence of kinetic and thermodynamic nonlinear effects on the regularities of deformation processes of amorphous polymers in warm and frozen states was noted. The influence of nonlinear effects on the general shape and characteristics of individual stages of the “relative strain - deforming stress” diagram at deformation of polymer samples with specified values of strain rate and temperature is analyzed in detail. The results of the theoretical analysis were used for the physical interpretation of the general form and features of individual stages of the tensile test diagrams of amorphous polyimide films (V. D. Natsik, H. V. Rusakova, S. V. Lubenets, V. A. Lototskaya, and L. F. Yakovenko, Fiz. Nyzk. Temp. 49, 569 (2023) [Low Temp. Phys. 49, 521 (2023)]), empirical estimates for the rheological characteristics of this polymer were obtained.","PeriodicalId":18077,"journal":{"name":"Low Temperature Physics","volume":"23 1","pages":"0"},"PeriodicalIF":0.6000,"publicationDate":"2023-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Nonlinear effects at the deformation of amorphous polymers in warm and frozen states\",\"authors\":\"V. D. Natsik, H. V. Rusakova\",\"doi\":\"10.1063/10.0021378\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"One of the important problems of the modern rheology of polymer materials, namely, the possibility of describing the deformation of amorphous polymers within the framework of linear rheological relationships between relative deformation and deforming stress or the need to use nonlinear rheological equations is considered. The criteria for distinguishing these approaches, namely, the determination of the corresponding critical values of the macro- and microphysical characteristics of the material and the conditions for carrying out the mechanical tests are also discussed. In particular, the difference between the influence of kinetic and thermodynamic nonlinear effects on the regularities of deformation processes of amorphous polymers in warm and frozen states was noted. The influence of nonlinear effects on the general shape and characteristics of individual stages of the “relative strain - deforming stress” diagram at deformation of polymer samples with specified values of strain rate and temperature is analyzed in detail. The results of the theoretical analysis were used for the physical interpretation of the general form and features of individual stages of the tensile test diagrams of amorphous polyimide films (V. D. Natsik, H. V. Rusakova, S. V. Lubenets, V. A. Lototskaya, and L. F. Yakovenko, Fiz. Nyzk. Temp. 49, 569 (2023) [Low Temp. Phys. 49, 521 (2023)]), empirical estimates for the rheological characteristics of this polymer were obtained.\",\"PeriodicalId\":18077,\"journal\":{\"name\":\"Low Temperature Physics\",\"volume\":\"23 1\",\"pages\":\"0\"},\"PeriodicalIF\":0.6000,\"publicationDate\":\"2023-11-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Low Temperature Physics\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1063/10.0021378\",\"RegionNum\":4,\"RegionCategory\":\"物理与天体物理\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"PHYSICS, APPLIED\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Low Temperature Physics","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1063/10.0021378","RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"PHYSICS, APPLIED","Score":null,"Total":0}
引用次数: 0
摘要
考虑了现代高分子材料流变学的一个重要问题,即在相对变形与变形应力之间的线性流变关系框架内描述非晶聚合物变形的可能性或使用非线性流变方程的必要性。还讨论了区分这些方法的标准,即确定材料的宏观和微观物理特性的相应临界值以及进行力学试验的条件。特别指出了动力学和热力学非线性效应对非晶聚合物在温暖和冷冻状态下变形过程规律的影响的区别。详细分析了在一定应变速率和温度条件下,非线性效应对聚合物试样变形时“相对应变-变形应力”图的总体形状和各阶段特征的影响。理论分析的结果被用于对非晶聚酰亚胺薄膜拉伸试验图的一般形式和各个阶段的特征的物理解释(V. D. Natsik, H. V. Rusakova, S. V. Lubenets, V. A. Lototskaya和L. F. Yakovenko, Fiz)。Nyzk。温度。49,569(2023)[低温。物理。49,521(2023)]),获得了该聚合物流变特性的经验估计。
Nonlinear effects at the deformation of amorphous polymers in warm and frozen states
One of the important problems of the modern rheology of polymer materials, namely, the possibility of describing the deformation of amorphous polymers within the framework of linear rheological relationships between relative deformation and deforming stress or the need to use nonlinear rheological equations is considered. The criteria for distinguishing these approaches, namely, the determination of the corresponding critical values of the macro- and microphysical characteristics of the material and the conditions for carrying out the mechanical tests are also discussed. In particular, the difference between the influence of kinetic and thermodynamic nonlinear effects on the regularities of deformation processes of amorphous polymers in warm and frozen states was noted. The influence of nonlinear effects on the general shape and characteristics of individual stages of the “relative strain - deforming stress” diagram at deformation of polymer samples with specified values of strain rate and temperature is analyzed in detail. The results of the theoretical analysis were used for the physical interpretation of the general form and features of individual stages of the tensile test diagrams of amorphous polyimide films (V. D. Natsik, H. V. Rusakova, S. V. Lubenets, V. A. Lototskaya, and L. F. Yakovenko, Fiz. Nyzk. Temp. 49, 569 (2023) [Low Temp. Phys. 49, 521 (2023)]), empirical estimates for the rheological characteristics of this polymer were obtained.
期刊介绍:
Guided by an international editorial board, Low Temperature Physics (LTP) communicates the results of important experimental and theoretical studies conducted at low temperatures. LTP offers key work in such areas as superconductivity, magnetism, lattice dynamics, quantum liquids and crystals, cryocrystals, low-dimensional and disordered systems, electronic properties of normal metals and alloys, and critical phenomena. The journal publishes original articles on new experimental and theoretical results as well as review articles, brief communications, memoirs, and biographies.
Low Temperature Physics, a translation of the copyrighted Journal FIZIKA NIZKIKH TEMPERATUR, is a monthly journal containing English reports of current research in the field of the low temperature physics. The translation began with the 1975 issues. One volume is published annually beginning with the January issues.