发展中国家木屑高效热解及其产品产量的可行性

Jean Fidele Nzihou, Pierre Girod, Salou Hamidou, Yann Rogaume, Bila Gerard Segda, Frederic Ouattara
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摘要

本文研究了木材热解生产甲烷、乙烷和一氧化碳等可燃性气体的可行性。第一个实验室实验阶段的目标是看看在没有氧气和氮气的情况下,木材热解可以得到什么产品。研究了温度对产物收率的影响。用气相色谱法对产物进行表征。研究发现,木材在700、800、900、1000和1100℃温度下的热解产物主要是炭、CO2以及CH4、C2H2、CO和焦油等可燃性气体。产气中未发现NH3。 在我们的研究中,可冷凝气体没有回收和量化。在将气体输送到质谱仪之前,必须在热解反应器的出口插入一个气体冷凝器。研究表明,在700°C时,以重量为基础的焦炭产量从17.08%下降到1100°C时的12.95%。气体和焦油产量下降,从700°C时的82.92%(以重量为基础)下降到1100°C时的87.05%。二氧化碳的产生也随着温度的升高而增加。它是木材热解气体中产生气体最多的部分,平均重量占初始木材的6.99%。一氧化碳的产率几乎不变,在800、900和1000°C时约为1.6%,而在700°C时的产率略高,占初始木材重量的2.29%。与其他可燃气体如甲烷和一氧化碳相比,乙烯(C2H4)仅产生少量。它的比例几乎是恒定的,在700到900°C的初始木屑重量基础上约为0.14%,在1000°C时下降到0.02%。甲烷(CH4)的产率为2.55%,从700°C到1000°C几乎保持不变。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Feasibility of Efficient Pyrolysis of Wood Chips and its Product Yield in Developing Countries
This paper is about the feasibility of combustibles gases like methane, ethane and carbon monoxide production from wood pyrolysis. This first laboratory experimental stage objective was to see what products can be obtained from wood pyrolysis in absence of oxygen and presence of nitrogen. The effect of temperature on the product yields was investigated. Products were characterized using gas-chromatography. We found that products of wood pyrolysis for temperatures of 700, 800, 900, 1000 and 1100°C were char, CO2 and combustibles gases like CH4, C2H2, CO and tar. NH3 was not found in the produced gases. In our study, condensable gases were not recovered and quantified. A gas condenser would have been necessary inserted for this purpose at the outlet of the pyrolysis reactor before routing the gases to the mass spetrograph. This study show that char production decrease from 17.08% at 700°C on the weight basis to 12.95% at 1100°C. Gases and tar production decrease, going from 82.92% at 700 °C on the weight basis to 87.05% at 1100°C. Carbone dioxide production also increase with temperature. It is the biggest part of produced gases of the wood pyrolysis gases representing an average weight proportion of 6.99% of the initial wood. Carbone monoxide yield is almost constant, around 1.6% at 800, 900 and 1000°C thought its yield at 700°C was found slightly higher accounting for 2.29% weight of the initial wood. Ethylene (C2H4) is only produced in small amount compared to others combustibles gases like methane and carbon monoxide. Its proportion which was observed almost constant, around 0.14% on the weight basis in respect to the initial wood chips weight from 700 to 900°C dropped to 0.02% at 1000°C. Methane (CH4) is produced in weight basis proportions of 2.55% which remain almost constant from 700 to 1000°C.
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