三乙胺存在下氮杂嗪与N-(酰基)邻苯二胺的光诱导烷基化反应

IF 2.2 4区化学 Q2 CHEMISTRY, ORGANIC

Synthesis-Stuttgart Pub Date : 2023-09-27 DOI:10.1055/a-2182-7416

Itziar Guerrero, Eugene Yew Kun Tan, Yuliang Liu, Lee J. Edwards, Shunsuke Chiba

引用次数: 0

摘要

摘要:本文提出了一种与N-(酰基)邻苯二甲酸亚胺烷基化二嗪类化合物(嘧啶类、吡嗪类和吡啶类)的光化学反应方案。在427-390 nm光照射下，三乙胺的存在促进了该过程;这使得快速交叉偶联反应能够构建广泛的烷基化嘧啶。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Photoinduced alkylation of diazines with N-(acyloxy)phthalimides in the presence of triethylamine

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Photoinduced alkylation of diazines with N-(acyloxy)phthalimides in the presence of triethylamine

Abstract A photochemical protocol for the alkylation of diazines (pyrimidines, pyrazines, and pyridazines) with N-(acyloxy)phthalimides has been developed. The process is facilitated by the presence of triethylamine under irradiation with 427–390 nm light; this enables rapid cross-coupling reactions to construct a wide range of alkylated diazines.

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来源期刊

Synthesis-Stuttgart 化学-有机化学

CiteScore

4.50

自引率

7.70%

发文量

435

审稿时长

1 months

期刊介绍： SYNTHESIS is an international full-paper journal devoted to the advancement of the science of chemical synthesis. It covers all fields of organic chemistry involving synthesis, including catalysis, organometallic, medicinal, biological, and photochemistry, but also related disciplines. SYNTHESIS provides dependable research results with detailed and reliable experimental procedures and full characterization of all important new products as well as scientific primary data.