溶剂萃取-吸附法回收废油中基础油的研究进展

Aftab Hasnat Khan, Nadia Batool, Abdul Aziz
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摘要

基础油是润滑油的主要成分,它以其原始形式存在,并以足够的量使用润滑油。综述了利用溶剂萃取-吸附法从废油中回收基础油的研究进展。研究了不同的溶剂和不同的溶剂油比。溶剂的选择是基于它有选择地从废油中溶解基础油和拒绝溶液中的杂质的能力。萃取油的收率和质量通常取决于溶剂的性质、溶剂油比和杂质的性质。研究了各种溶剂和溶剂油比。然而,结果表明,甲基乙基酮(MEK)是最好的溶剂,因为它能最大限度地去除污泥,更容易回收,而且成本低。溶剂和油充分混合后形成两相体系。在加入溶剂之前,将油脱水以除去作为杂质存在的水,然后使用真空蒸馏除去轻烃。加入溶剂后,萃取相分离,留下污泥相,污泥相由杂质聚集物组成。溶剂从萃取相中蒸发。将提取的油与合适的吸附剂接触,吸附其中的芳香族成分和重金属。最后,将添加剂添加到回收的油中,以配制新的润滑剂。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Recovery of Base Oil from Used Oil through Solvent Extraction Followed by Adsorption: A Review
Base oil is the major component of lubricating oil, which is present in its original form and used lubricating oil in a sufficient amount. This review article focuses on the recovery of base oil from used oil through solvent extraction followed by adsorption. Different solvents and various solvent-to-oil ratios are studied. Solvent selection is based on its ability to selectively dissolve the base oil from used oil and to reject the impurities in the solution. The percentage yield and quality of extracted oil usually depend upon the nature of the solvent, solvent-to-oil ratio, and nature of impurities. Various solvents and solvent-to-oil ratios are studied. However, results show that methyl ethyl ketone (MEK) is the best solvent because it gives the maximum sludge removal, is more easily recovered, and also has a low cost. A two-phase system occurs after adequate mixing of solvent and oil. Before solvent addition, oil is dehydrated to remove water present as impurities, and then light hydrocarbons are removed using vacuum distillation. After solvent addition, the extracted phase is separated, leaving behind the sludge phase, which consists of aggregates of impurities. The solvent is evaporated from the extracted phase. The extracted oil is put in contact with a suitable adsorbent to absorb the aromatic contents and heavy metals in it. In the end, additives are added to the recovered oil for the formulation of a new lubricant.
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