纳米颗粒修饰碳糊循环伏安法、高效液相色谱法和分光光度法测定2,4-二硝基苯肼

Khalil Ibrahim Alabid, Hajar Naser Nasser
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引用次数: 0

摘要

研究了用改性碳糊制备测定2,4-二硝基苯肼(2,4- dnphz)的电极,该改性碳糊电极为NiO-NCQD/g-C3N4/MCPE。结果表明:存在氧化峰和还原峰,属于准可逆体系;最佳pH值为(1),使用浓度为(0.1M)的硫酸,扫描速率为100 mv秒-1,氧化和还原的线性范围分别为(1 ~ 1000)µM和(100 ~ 1000)µM,相关系数分别为(R2=0.9717)和(R2=0.9914)。并与分光光度法(波长360 nm)和高效液相色谱法(波长340 nm和250 nm)进行了比较。结果表明,电化学方法(NiO-NCQD/g-C3N4/MCPE)在检出限上优于分光光度法。结果表明,(HPLC)与(NiO-NCQD/g-C3N4/MCPE)在准确度上无显著差异。该方法是一种准确度高、重复性好、可靠性好的新型分析方法。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Determination of 2,4-dinitrophenylhydrazine using carbon paste modified with nanoparticles by cyclic voltammetry, high-performance liquid chromatography and spectrophotometry methods
The research deals with the manufacture of an electrode using modified carbon paste to determine 2,4-dinitrophenylhydrazine (2,4-DNPHZ), The modified carbon paste electrode (NiO-NCQD/g-C3N4/MCPE). The results show the presence of oxidation and reduction peaks, and it is subject to a quasi-reversible system; the best value ​​of pH is (1) using sulfuric acid with a concentration of (0.1M), and scan rate is 100 mv sec-1, it was linearity range of (1-1000) µM for oxidation, and (100-1000) µM for reduction, with correlation coefficient (R2=0.9717) and (R2=0.9914) for each of them, respectively. The proposed electrochemical method was compared with two methods they are spectrophotometry at a wavelength 360) nm( and high-performance liquid chromatography (HPLC) at wavelengths (340 and 250) nm. It turned out that the electrochemical method (NiO-NCQD/g-C3N4/MCPE) was superior to the spectrophotometry method in terms of the detection limit. It turns out that there is no significant difference between (HPLC) and (NiO-NCQD/g-C3N4/MCPE) in terms of accuracy. The proposed electrochemical method is a new analytical method characterized by accuracy, repeatability, and reliability.
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CiteScore
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