{"title":"还原氧化石墨烯包裹二氧化钛纳米纤维对硫化氢的吸附","authors":"Kanchit Kamlangkla, Aphichard Phongphala, Udomdej Pakdee","doi":"10.1155/2023/5570029","DOIUrl":null,"url":null,"abstract":"This work presents a fabrication of room-temperature gas sensor for hydrogen sulfide (H2S) adsorption. Pristine titanium dioxide (TiO2) nanofibers, reduced graphene oxide (rGO) sheets, and reduced graphene oxide-wrapped titanium dioxide (rGO-wrapped TiO2) nanofibers were presented in the form of integrated suspension used for a gas-sensing layer. The TiO2 nanofibers were firstly synthesized by using an electrospinning method with a polyvinylpyrrolidone (PVP) polymer. The rGO sheets were then wrapped around TiO2 nanofibers by a hydrothermal method. Scanning electron microscope, transmission electron microscope, X-ray diffractometer, and Raman spectrometer confirmed the presence of rGO sheets onto the surface of TiO2 nanofibers. Ultraviolet-visible spectrophotometer was also considered and displayed to calculate the band gap of TiO2 and rGO-wrapped TiO2 nanofibers. After preparing the gas-sensing suspensions, they were dropped onto the polyethylene terephthalate substrates with silver-interdigitated electrodes. The gas-sensing properties of sensors were evaluated for H2S adsorption at room temperature. Based on the results, the rGO-wrapped TiO2 nanofiber gas sensor exhibited higher H2S sensitivity and selectivity than pristine TiO2 nanofiber and pure rGO gas sensors. The H2S-sensing mechanism of rGO-wrapped TiO2 nanofiber gas sensor was discussed based on a formation of p-n heterojunctions between p-type rGO sheets and n-type TiO2 nanofibers. Furthermore, a direct charge-transfer process by physisorption was also highlighted as a second H2S-sensing mechanism.","PeriodicalId":7315,"journal":{"name":"Adsorption Science & Technology","volume":"22 1","pages":"0"},"PeriodicalIF":2.8000,"publicationDate":"2023-09-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Adsorption of Hydrogen Sulfide on Reduced Graphene Oxide-Wrapped Titanium Dioxide Nanofibers\",\"authors\":\"Kanchit Kamlangkla, Aphichard Phongphala, Udomdej Pakdee\",\"doi\":\"10.1155/2023/5570029\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"This work presents a fabrication of room-temperature gas sensor for hydrogen sulfide (H2S) adsorption. Pristine titanium dioxide (TiO2) nanofibers, reduced graphene oxide (rGO) sheets, and reduced graphene oxide-wrapped titanium dioxide (rGO-wrapped TiO2) nanofibers were presented in the form of integrated suspension used for a gas-sensing layer. The TiO2 nanofibers were firstly synthesized by using an electrospinning method with a polyvinylpyrrolidone (PVP) polymer. The rGO sheets were then wrapped around TiO2 nanofibers by a hydrothermal method. Scanning electron microscope, transmission electron microscope, X-ray diffractometer, and Raman spectrometer confirmed the presence of rGO sheets onto the surface of TiO2 nanofibers. Ultraviolet-visible spectrophotometer was also considered and displayed to calculate the band gap of TiO2 and rGO-wrapped TiO2 nanofibers. After preparing the gas-sensing suspensions, they were dropped onto the polyethylene terephthalate substrates with silver-interdigitated electrodes. The gas-sensing properties of sensors were evaluated for H2S adsorption at room temperature. Based on the results, the rGO-wrapped TiO2 nanofiber gas sensor exhibited higher H2S sensitivity and selectivity than pristine TiO2 nanofiber and pure rGO gas sensors. The H2S-sensing mechanism of rGO-wrapped TiO2 nanofiber gas sensor was discussed based on a formation of p-n heterojunctions between p-type rGO sheets and n-type TiO2 nanofibers. Furthermore, a direct charge-transfer process by physisorption was also highlighted as a second H2S-sensing mechanism.\",\"PeriodicalId\":7315,\"journal\":{\"name\":\"Adsorption Science & Technology\",\"volume\":\"22 1\",\"pages\":\"0\"},\"PeriodicalIF\":2.8000,\"publicationDate\":\"2023-09-28\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Adsorption Science & Technology\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1155/2023/5570029\",\"RegionNum\":4,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, APPLIED\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Adsorption Science & Technology","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1155/2023/5570029","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, APPLIED","Score":null,"Total":0}
Adsorption of Hydrogen Sulfide on Reduced Graphene Oxide-Wrapped Titanium Dioxide Nanofibers
This work presents a fabrication of room-temperature gas sensor for hydrogen sulfide (H2S) adsorption. Pristine titanium dioxide (TiO2) nanofibers, reduced graphene oxide (rGO) sheets, and reduced graphene oxide-wrapped titanium dioxide (rGO-wrapped TiO2) nanofibers were presented in the form of integrated suspension used for a gas-sensing layer. The TiO2 nanofibers were firstly synthesized by using an electrospinning method with a polyvinylpyrrolidone (PVP) polymer. The rGO sheets were then wrapped around TiO2 nanofibers by a hydrothermal method. Scanning electron microscope, transmission electron microscope, X-ray diffractometer, and Raman spectrometer confirmed the presence of rGO sheets onto the surface of TiO2 nanofibers. Ultraviolet-visible spectrophotometer was also considered and displayed to calculate the band gap of TiO2 and rGO-wrapped TiO2 nanofibers. After preparing the gas-sensing suspensions, they were dropped onto the polyethylene terephthalate substrates with silver-interdigitated electrodes. The gas-sensing properties of sensors were evaluated for H2S adsorption at room temperature. Based on the results, the rGO-wrapped TiO2 nanofiber gas sensor exhibited higher H2S sensitivity and selectivity than pristine TiO2 nanofiber and pure rGO gas sensors. The H2S-sensing mechanism of rGO-wrapped TiO2 nanofiber gas sensor was discussed based on a formation of p-n heterojunctions between p-type rGO sheets and n-type TiO2 nanofibers. Furthermore, a direct charge-transfer process by physisorption was also highlighted as a second H2S-sensing mechanism.
期刊介绍:
Adsorption Science & Technology is a peer-reviewed, open access journal devoted to studies of adsorption and desorption phenomena, which publishes original research papers and critical review articles, with occasional special issues relating to particular topics and symposia.