含金属配位单元的亲水聚合物与多种金属离子的凝胶化

IF 1.4 4区化学 Q3 CHEMISTRY, MULTIDISCIPLINARY

Chemistry Letters Pub Date : 2023-09-28 DOI:10.1246/cl.230347

Daisuke Nagai, Naoki Isobe, Yasuyuki Maki, Shusuke Okamoto

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引用次数: 0

摘要

研究了一种含金属配位单元的亲水聚合物与多种金属离子的凝胶作用。根据金属离子种类的不同，形成了不同形态的凝胶。这些凝胶的形成机理可以根据它们的交联速率来解释。研究了不同比例的PdII与其他金属离子(AuIII和PtIV)在双组分溶液中的凝胶作用。研究了一种含金属配位单元的亲水聚合物与多种金属离子的凝胶作用。根据金属离子种类的不同，形成了不同形态的凝胶。这些凝胶的形成机理可以根据它们的交联速率来解释。研究了不同比例的PdII与其他金属离子(AuIII和PtIV)在双组分溶液中的凝胶作用。

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Gelation of Hydrophilic Polymer Bearing Metal-Coordination Unit with Various Metal Ions

Gelation of a hydrophilic polymer bearing a metal-coordination unit with various metal ions was examined. Gels with different morphologies were formed depending on the metal ion species. The formation mechanism for these gels could be explained based on their cross-linking rates. Gelation in two-component solutions containing different ratios of PdII to other metal ions (AuIII and PtIV) was also investigated. Gelation of a hydrophilic polymer bearing a metal-coordination unit with various metal ions was examined. Gels with different morphologies were formed depending on the metal ion species. The formation mechanism for these gels could be explained based on their cross-linking rates. Gelation in two-component solutions containing different ratios of PdII to other metal ions (AuIII and PtIV) was also investigated.

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来源期刊

Chemistry Letters 化学-化学综合

CiteScore

3.00

自引率

6.20%

发文量

260

审稿时长

1.2 months

期刊介绍： Chemistry Letters covers the following topics: -Organic Chemistry- Physical Chemistry- Inorganic Chemistry- Analytical Chemistry- Materials Chemistry- Polymer Chemistry- Supramolecular Chemistry- Organometallic Chemistry- Coordination Chemistry- Biomolecular Chemistry- Natural Products and Medicinal Chemistry- Electrochemistry