蓝光发射异质金属微型-微型配合物的合成、晶体结构、光谱、发光研究和赫希菲尔德表面分析

E. Gungor
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引用次数: 0

摘要

报道了一种新型杂金属配合物[Mn(L)(H2O)(CH3CH2OH)]2[Ni(CN)4], (H2L=N,N -双(3,5-二-丁基水杨酸二烯)-1,2-丙二胺)的合成、晶体结构、光谱、发光性质和Hirshfeld表面分析。单晶衍射测量表明,异质金属MnIII-NiII配合物由两个[(Mn(L)(H2O)(CH3CH2OH)]+阳离子和一个[Ni(CN)4]2-阴离子组成。Mn1和Mn2离子由N2O4供体集六配位,具有扭曲的八面体几何结构。三维Hirshfeld表面和二维指纹图谱显示,H∙∙∙H分子间相互作用为主要相互作用,相对贡献率约为73.8%。根据固态发光测量,新的杂金属MnIII-NiII配合物表现出微弱的蓝光发射。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
SYNTHESIS, CRYSTAL STRUCTURE, SPECTROSCOPIC, LUMINESCENCE STUDIES AND HIRSHFELD SURFACE ANALYSIS OF BLUE LIGHT EMITTING HETEROMETALLIC MNIII-NIII COMPLEX
The synthesis, crystal structure, spectroscopic, luminescence properties and Hirshfeld surface analysis of a new heterometallic complex, [Mn(L)(H2O)(CH3CH2OH)]2[Ni(CN)4], (H2L=N,N՛-bis(3,5-di-t-butylsalicylidene)-1,2-propanediamine) was reported. Single crystal diffraction measurements showed that the heterometallic MnIII-NiII complex consists of two [(Mn(L)(H2O)(CH3CH2OH)]+ cations and one [Ni(CN)4 ]2- anion. The Mn1 and Mn2 ions are hexacoordinate by N2O4 donor sets and have a distorted octahedral geometry. The 3-D Hirshfeld surface and 2-D fingerprint plots showed that the main interactions were the H∙∙∙H intermolecular interactions with relative contributions of about 73.8%. According to solid-state luminescence measurements, the new heterometallic MnIII-NiII complex showed weak blue light emission.
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