对掺镝硼酸锌锂玻璃的过渡金属依赖结构、光学和电学性质的研究

IF 0.7 4区 化学 Q4 CHEMISTRY, MULTIDISCIPLINARY
Anju Bishnoi, Manoj Duhan, Satish Khasa
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引用次数: 0

摘要

摘要采用熔体淬火法合成了化学成分为x2o5·(10-x)ZnO·30Li2O·60B2O3 (x = 0,1,5,7,9,10), Dy3+掺杂的锌钒硼酸锂玻璃系列,其中Dy2O3含量为1.0 mol%。通过研究镝离子在VO2+离子存在下的结构、电学、光致发光(PL)和光学特性,努力寻找合适的光电材料。对PL发射光谱进行了研究,发现当在386和424 nm处激发时,玻璃基体适合激光作用,而在452nm处,它适合冷白光应用。关键词:直流电导率;非准光学带隙发光(PL);过渡金属离子(TMI)致谢作者感谢中央仪器实验室(CIL), DCRUST, Murthal,为FTIR测量提供了便利。披露声明作者未报告潜在的利益冲突。作者还想感谢德里的DST根据FIST研究资助(制裁令No. 1)提供荧光设备。日期:SR/FST/PS-1/2018/32)。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
An insight into the transition metal dependent structural, optical, and electrical properties of dysprosium doped lithium zinc borate glasses
AbstractA glass series of Dy3+ ions doped zinc vanadium lithium borate with chemical composition xV2O5·(10-x)ZnO·30Li2O·60B2O3 (x = 0, 1, 5, 7, 9, 10) with 1.0 mol% of Dy2O3 has been synthesized by melt quench method. Efforts have been made to identify suitable optoelectronic material by studying the structural, electrical, photo-luminescence (PL), and optical characteristics of the dysprosium ions in the presence of VO2+ ions. PL emission spectra have been explored, depicting that when excited at 386 and 424 nm, the glass matrix is suitable for laser action and at 452 nm, it is apt for cool white light applications.Keywords: Dc conductivitydysprosiumoptical band gapphotoluminescence (PL)transition metal ions (TMI) AcknowledgmentsThe authors would like to thank the Central Instrumentation Laboratory (CIL), DCRUST, Murthal, for facilitating FTIR measurements.Disclosure statementNo potential conflict of interest was reported by the author(s).Additional informationFundingThe authors also want to acknowledge DST, Delhi, for providing Fluorescence facilities under FIST Research Grant (Sanction Order No. & Date: SR/FST/PS-1/2018/32).
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来源期刊
CiteScore
1.20
自引率
14.30%
发文量
248
审稿时长
2 months
期刊介绍: Established in 1966, Molecular Crystals and Liquid Crystals is a world-leading journal publishing original research papers in both an experimental and theoretical nature in three areas of specialization: liquid crystals, molecular crystals, and low-dimensional solids. These cover, but are not limited to: Liquid Crystals: -Electro- and magneto-optical phenomena; thermodynamics; phase transitions; structure; NMR and orientation-controlled spectroscopy; theory. Molecular Crystals: -Spectroscopy; energy and charge transfer; solid state reactions; photo and radiation effects Low-dimensional Solids: -Structure, electronic, magnetic, and optical properties; transport mechanisms The journal publishes research papers, review papers, and book reviews. In all three areas, experimental manuscripts describing both preparation and properties will be considered. Papers that describe determination of crystal structure alone are not encouraged unless some solid state forces (hydrogen bonding, charge transfer, etc.) are playing a significant role and/or some solid state properties of the materials are measured.
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