酸处理对现代沸石特性的影响

Sumiati Side, Suriati Eka Putri, Diana Eka Pratiwi, Aulia Rahma, Abd. Rahman
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引用次数: 0

摘要

本文研究了酸处理对沸石矿物特性的影响。采用x射线荧光(XRF)、x射线衍射(XRD)和扫描电镜(SEM)检测了不同酸溶液(盐酸(HCl)和硫酸(H2SO4))对沸石的处理效果。结果表明,沸石活化后的SiO2和Al2O3含量有所增加,杂质含量有所减少。采用XRD对沸石的晶相进行了分析,表明沸石的类型为现代沸石。样品中的SiO2相为石英,Al2O3相为刚玉。活化后平均晶粒尺寸减小,HCl和H2SO4分别从14.23 nm和5.42 nm降至6.85 nm和6.85 nm。此外,所有沸石样品的表面形貌都具有不规则的球形形式,活化后的颗粒表面尺寸呈现较小的颗粒形状。本研究结果有望为进一步研究天然沸石作为催化剂载体的预处理提供参考。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
The Effect Of Acid Treatment On The Characteristics Of Modernite Zeolite
This work investigated the use of acid treatment on the characteristics of zeolite mineral. The effects of treating zeolite with various acid solutions hydrochloric acid (HCl) and sulfuric acid (H2SO4) were measured using x-ray fluorescence (XRF), x-ray diffraction (XRD), and scanning electron microscope (SEM). The results showed an increase in the percentage of SiO2 and Al2O3 after zeolite activation, and also a decrease in the amount of impurities. The crystalline phase of the zeolite was carried out using XRD analysis, indicating the type of zeolite used is modernite. The SiO2 phase in the sample is quartz, and the Al2O3 phase is corundum. The average crystal size decreased after activation, from 14.23 nm to 6.85 nm for HCl and 5.42 nm for H2SO4. Futhermore, the surface morphology of all zeolite samples has a form of irregular spherical surface, and the surface size of the particles after activation shows a smaller particle shape. The results of this study are expected to become recommendations for further research related to natural zeolite pretreatment as a catalyst support.
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