赤藓糖醇作为一种潜在相变材料的表征

IF 1.3 Q3 ENGINEERING, MECHANICAL
Paul Gregory Felix, Velavan Rajagopal, Kannan Kumaresan
{"title":"赤藓糖醇作为一种潜在相变材料的表征","authors":"Paul Gregory Felix, Velavan Rajagopal, Kannan Kumaresan","doi":"10.1080/14484846.2023.2272329","DOIUrl":null,"url":null,"abstract":"ABSTRACTErythritol ((2 R,3S)-Butane-1,2,3,4-tetrol) is being considered as a phase change material (PCM) of interest owing to its potential applicability for solar thermal applications. But however, lack of inclusive material characterisation outcomes drives the need to bridge this research gap. In this study, erythritol was subjected to both chemical and thermal characterisation investigations. X-ray diffractometry (XRD) investigation estimated the degree of crystallinity to be 73.48% and the crystallite size to be 38.79 nm. The fourier transform infrared spectroscopy (FT-IR) investigation has identified -OH, -C-H and -CH2 to be the major functional groups. The scanning electron microscopy (SEM) investigation visualised the crystalline architecture of the PCM. The energy dispersive x-ray spectroscopy (EDAX) investigation quantified the composition of C and O in the eclectic constituency. The UV-visible spectrophotometry investigations confirmed that erythritol could be utilised for direct solar thermal applications. The thermal characterisation investigations rendered the latent heat of the PCM to be 333.48 kJ kg−1 and its peak melting temperature to be 118.18°C. The thermal stability investigations estimated the latent heat loss per cycle to be 1.1451 kJ kg−1.KEYWORDS: Characterisationphase change materialsthermal energy storage Nomenclature β=Full width at half maximum (FWHM) (radians)λ=Wave-length of x-ray (Å)ρ=Bulk density of erythritol (kg m−3)ρxr=X-ray density of erythritol (kg m−3)θ=Peak location (radians)Ag=Avagadro’s constant (or) Avagadro’s number: 6.02214076 × 10 23Cpl=Liquid phase specific heat (kJ kg−1 K)Cps=Solid phase specific heat (kJ kg−1 K)hm=Latent heat of fusion (kJ kg−1)M=Molecular weight of erythritol (g mol−1)Qm=Heat energy required for melting alone (kJ)Qls=Heat energy stored during liquid sensible heating (kJ)Qss=Heat energy stored during solid sensible heating (kJ)Tamb=Ambient temperature (K)Tpm=Peak melting temperature (K)V=Volume of the unit cell (m3)A=Absorbance (%)D=crystallite size (nm)K=Scherrer equation constantm=Mass of erythritol used (kg)Q(t)=Instantaneous heat energy stored (kJ)R=Reflectance (%)T=Transmittance (%)AcknowledgementsThe authors thank the Department of Science and Technology (DST), Government of India and the management of PSG College of Technology, Coimbatore for their financial support.Disclosure statementNo potential conflict of interest was reported by the authors.Additional informationFundingThis work was supported by the Department of Science and Technology (DST), Government of India under Grant No.: DST/TMD/MES/2K16/20(G).Notes on contributorsPaul Gregory FelixPaul Gregory Felix holds a doctoral degree in Energy Engineering. He is currently affiliated with Sri Krishna College of Technology, Coimbatore as an Assistant Professor. He is a practising engineer and a consultant Chartered Mechanical Engineer licensed by The Institution of Engineers (India). His fields of expertise include phase change materials, energy storage systems, computational fluid dynamics, sustainable architecture and energy-efficient building design.Velavan RajagopalVelavan Rajagopal completed his doctorate in GHG mitigation in a Textile Industrial Cluster from Anna University and his research area is application of sustainable energy for industrial and domestic use.Kannan KumaresanKannan Kumaresan has 7½ years of industrial experience in Boilers and completed his doctorate in Flow analysis of Shell and Tube Heat Exchangers from Anna University, Chennai, and his area of research is Phase change materials, solar latent heat storage systems, and Computational Fluid Dynamics.","PeriodicalId":8584,"journal":{"name":"Australian Journal of Mechanical Engineering","volume":null,"pages":null},"PeriodicalIF":1.3000,"publicationDate":"2023-11-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Characterisation of erythritol as a potential phase change material\",\"authors\":\"Paul Gregory Felix, Velavan Rajagopal, Kannan Kumaresan\",\"doi\":\"10.1080/14484846.2023.2272329\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"ABSTRACTErythritol ((2 R,3S)-Butane-1,2,3,4-tetrol) is being considered as a phase change material (PCM) of interest owing to its potential applicability for solar thermal applications. But however, lack of inclusive material characterisation outcomes drives the need to bridge this research gap. In this study, erythritol was subjected to both chemical and thermal characterisation investigations. X-ray diffractometry (XRD) investigation estimated the degree of crystallinity to be 73.48% and the crystallite size to be 38.79 nm. The fourier transform infrared spectroscopy (FT-IR) investigation has identified -OH, -C-H and -CH2 to be the major functional groups. The scanning electron microscopy (SEM) investigation visualised the crystalline architecture of the PCM. The energy dispersive x-ray spectroscopy (EDAX) investigation quantified the composition of C and O in the eclectic constituency. The UV-visible spectrophotometry investigations confirmed that erythritol could be utilised for direct solar thermal applications. The thermal characterisation investigations rendered the latent heat of the PCM to be 333.48 kJ kg−1 and its peak melting temperature to be 118.18°C. The thermal stability investigations estimated the latent heat loss per cycle to be 1.1451 kJ kg−1.KEYWORDS: Characterisationphase change materialsthermal energy storage Nomenclature β=Full width at half maximum (FWHM) (radians)λ=Wave-length of x-ray (Å)ρ=Bulk density of erythritol (kg m−3)ρxr=X-ray density of erythritol (kg m−3)θ=Peak location (radians)Ag=Avagadro’s constant (or) Avagadro’s number: 6.02214076 × 10 23Cpl=Liquid phase specific heat (kJ kg−1 K)Cps=Solid phase specific heat (kJ kg−1 K)hm=Latent heat of fusion (kJ kg−1)M=Molecular weight of erythritol (g mol−1)Qm=Heat energy required for melting alone (kJ)Qls=Heat energy stored during liquid sensible heating (kJ)Qss=Heat energy stored during solid sensible heating (kJ)Tamb=Ambient temperature (K)Tpm=Peak melting temperature (K)V=Volume of the unit cell (m3)A=Absorbance (%)D=crystallite size (nm)K=Scherrer equation constantm=Mass of erythritol used (kg)Q(t)=Instantaneous heat energy stored (kJ)R=Reflectance (%)T=Transmittance (%)AcknowledgementsThe authors thank the Department of Science and Technology (DST), Government of India and the management of PSG College of Technology, Coimbatore for their financial support.Disclosure statementNo potential conflict of interest was reported by the authors.Additional informationFundingThis work was supported by the Department of Science and Technology (DST), Government of India under Grant No.: DST/TMD/MES/2K16/20(G).Notes on contributorsPaul Gregory FelixPaul Gregory Felix holds a doctoral degree in Energy Engineering. He is currently affiliated with Sri Krishna College of Technology, Coimbatore as an Assistant Professor. He is a practising engineer and a consultant Chartered Mechanical Engineer licensed by The Institution of Engineers (India). His fields of expertise include phase change materials, energy storage systems, computational fluid dynamics, sustainable architecture and energy-efficient building design.Velavan RajagopalVelavan Rajagopal completed his doctorate in GHG mitigation in a Textile Industrial Cluster from Anna University and his research area is application of sustainable energy for industrial and domestic use.Kannan KumaresanKannan Kumaresan has 7½ years of industrial experience in Boilers and completed his doctorate in Flow analysis of Shell and Tube Heat Exchangers from Anna University, Chennai, and his area of research is Phase change materials, solar latent heat storage systems, and Computational Fluid Dynamics.\",\"PeriodicalId\":8584,\"journal\":{\"name\":\"Australian Journal of Mechanical Engineering\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":1.3000,\"publicationDate\":\"2023-11-09\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Australian Journal of Mechanical Engineering\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1080/14484846.2023.2272329\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"ENGINEERING, MECHANICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Australian Journal of Mechanical Engineering","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1080/14484846.2023.2272329","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"ENGINEERING, MECHANICAL","Score":null,"Total":0}
引用次数: 0

摘要

四四醇((2r,3S)-丁烷-1,2,3,4-四醇)由于其在太阳能热应用中的潜在适用性,被认为是一种有趣的相变材料(PCM)。但是,缺乏包容性的材料表征结果推动了弥合这一研究差距的需要。在本研究中,赤藓糖醇进行了化学和热表征研究。x射线衍射(XRD)测定结晶度为73.48%,晶粒尺寸为38.79 nm。傅里叶变换红外光谱(FT-IR)研究确定-OH、-C-H和-CH2是主要官能团。扫描电子显微镜(SEM)研究可视化的晶体结构的PCM。能量色散x射线光谱(EDAX)研究量化了折衷选区中C和O的组成。紫外可见分光光度法研究证实赤藓糖醇可以直接用于太阳能热应用。热表征研究表明,PCM的潜热为333.48 kJ kg−1,峰值熔化温度为118.18°C。热稳定性研究估计每个循环的潜热损失为1.1451 kJ kg−1。关键词:表征;相变材料;热储能;命名法β=半最大值全宽度(FWHM)(弧度)λ= x射线波长(Å)ρ=赤四糖醇体积密度(kg m−3)ρxr=赤四糖醇x射线密度(kg m−3)θ=峰位(弧度)Ag=Avagadro常数(或)Avagadro数6.02214076 × 10 23Cpl=液相比热(kJ kg−1 K)Cps=固相比热(kJ kg−1 K)hm=熔化潜热(kJ kg−1)M=赤糖醇分子量(g mol−1)Qm=单独熔化所需的热能(kJ)Qls=液相显热过程中储存的热能(kJ)Qss=固显热过程中储存的热能(kJ)Tamb=环境温度(K)Tpm=熔化峰值温度(K)V=晶胞体积(m3)A=吸光度(%)D=晶体尺寸(nm)K=Scherrer方程constant =所用赤藓糖醇质量(kg)Q(t)=瞬时储存热能(kJ)R=反射率(%)t =透射率(%)感谢印度政府科学技术部(DST)和哥印拜陀PSG技术学院管理层的资金支持。披露声明作者未报告潜在的利益冲突。本研究得到了印度政府科学技术部(DST)的资助。: DST / TMD / MES / 2 k16/20 (G)。paul Gregory Felix拥有能源工程博士学位。他目前在哥印拜陀的克里希纳理工学院担任助理教授。他是一名执业工程师和顾问,由工程师学会(印度)许可的特许机械工程师。他的专业领域包括相变材料、储能系统、计算流体动力学、可持续建筑和节能建筑设计。Velavan Rajagopal完成了Anna大学纺织产业集群温室气体减排博士学位,他的研究领域是工业和家庭使用可持续能源的应用。Kannan Kumaresan拥有7年半的锅炉行业经验,并在金奈安娜大学完成了壳管式热交换器流动分析博士学位,他的研究领域是相变材料、太阳能潜热储存系统和计算流体动力学。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Characterisation of erythritol as a potential phase change material
ABSTRACTErythritol ((2 R,3S)-Butane-1,2,3,4-tetrol) is being considered as a phase change material (PCM) of interest owing to its potential applicability for solar thermal applications. But however, lack of inclusive material characterisation outcomes drives the need to bridge this research gap. In this study, erythritol was subjected to both chemical and thermal characterisation investigations. X-ray diffractometry (XRD) investigation estimated the degree of crystallinity to be 73.48% and the crystallite size to be 38.79 nm. The fourier transform infrared spectroscopy (FT-IR) investigation has identified -OH, -C-H and -CH2 to be the major functional groups. The scanning electron microscopy (SEM) investigation visualised the crystalline architecture of the PCM. The energy dispersive x-ray spectroscopy (EDAX) investigation quantified the composition of C and O in the eclectic constituency. The UV-visible spectrophotometry investigations confirmed that erythritol could be utilised for direct solar thermal applications. The thermal characterisation investigations rendered the latent heat of the PCM to be 333.48 kJ kg−1 and its peak melting temperature to be 118.18°C. The thermal stability investigations estimated the latent heat loss per cycle to be 1.1451 kJ kg−1.KEYWORDS: Characterisationphase change materialsthermal energy storage Nomenclature β=Full width at half maximum (FWHM) (radians)λ=Wave-length of x-ray (Å)ρ=Bulk density of erythritol (kg m−3)ρxr=X-ray density of erythritol (kg m−3)θ=Peak location (radians)Ag=Avagadro’s constant (or) Avagadro’s number: 6.02214076 × 10 23Cpl=Liquid phase specific heat (kJ kg−1 K)Cps=Solid phase specific heat (kJ kg−1 K)hm=Latent heat of fusion (kJ kg−1)M=Molecular weight of erythritol (g mol−1)Qm=Heat energy required for melting alone (kJ)Qls=Heat energy stored during liquid sensible heating (kJ)Qss=Heat energy stored during solid sensible heating (kJ)Tamb=Ambient temperature (K)Tpm=Peak melting temperature (K)V=Volume of the unit cell (m3)A=Absorbance (%)D=crystallite size (nm)K=Scherrer equation constantm=Mass of erythritol used (kg)Q(t)=Instantaneous heat energy stored (kJ)R=Reflectance (%)T=Transmittance (%)AcknowledgementsThe authors thank the Department of Science and Technology (DST), Government of India and the management of PSG College of Technology, Coimbatore for their financial support.Disclosure statementNo potential conflict of interest was reported by the authors.Additional informationFundingThis work was supported by the Department of Science and Technology (DST), Government of India under Grant No.: DST/TMD/MES/2K16/20(G).Notes on contributorsPaul Gregory FelixPaul Gregory Felix holds a doctoral degree in Energy Engineering. He is currently affiliated with Sri Krishna College of Technology, Coimbatore as an Assistant Professor. He is a practising engineer and a consultant Chartered Mechanical Engineer licensed by The Institution of Engineers (India). His fields of expertise include phase change materials, energy storage systems, computational fluid dynamics, sustainable architecture and energy-efficient building design.Velavan RajagopalVelavan Rajagopal completed his doctorate in GHG mitigation in a Textile Industrial Cluster from Anna University and his research area is application of sustainable energy for industrial and domestic use.Kannan KumaresanKannan Kumaresan has 7½ years of industrial experience in Boilers and completed his doctorate in Flow analysis of Shell and Tube Heat Exchangers from Anna University, Chennai, and his area of research is Phase change materials, solar latent heat storage systems, and Computational Fluid Dynamics.
求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
CiteScore
3.70
自引率
7.10%
发文量
77
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信