Hadi Afshari, Sergio A. Chacon, Shashi Sourabh, Todd A. Byers, Vincent R. Whiteside, Rose Crawford, Bibhudutta Rout, Giles E. Eperon, Ian R. Sellers
{"title":"三卤化物钙钛矿太阳能电池的耐辐射性能和自修复性能","authors":"Hadi Afshari, Sergio A. Chacon, Shashi Sourabh, Todd A. Byers, Vincent R. Whiteside, Rose Crawford, Bibhudutta Rout, Giles E. Eperon, Ian R. Sellers","doi":"10.1063/5.0158216","DOIUrl":null,"url":null,"abstract":"The high tolerance and stability of triple halide perovskite solar cells is demonstrated in practical space conditions at high irradiation levels. The solar cells were irradiated for a range of proton energies (75 keV, 300 keV, and 1 MeV) and fluences (up to 4 × 1014 p/cm2). The fluences of the energy proton irradiations were varied to induce the same amount of vacancies in the absorber layer due to non-ionizing nuclear energy loss (predominant at <300 keV) and electron ionization loss (predominant at >300 keV). While proton irradiation of the solar cells initially resulted in degradation of the photovoltaic parameters, self-healing was observed after two months where the performance of the devices was shown to return to their pristine operation levels. Their ability to recover upon radiation exposure supports the practical potential of perovskite solar cells for next-generation space missions.","PeriodicalId":486383,"journal":{"name":"APL Energy","volume":"4 1","pages":"0"},"PeriodicalIF":0.0000,"publicationDate":"2023-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Radiation tolerance and self-healing in triple halide perovskite solar cells\",\"authors\":\"Hadi Afshari, Sergio A. Chacon, Shashi Sourabh, Todd A. Byers, Vincent R. Whiteside, Rose Crawford, Bibhudutta Rout, Giles E. Eperon, Ian R. Sellers\",\"doi\":\"10.1063/5.0158216\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The high tolerance and stability of triple halide perovskite solar cells is demonstrated in practical space conditions at high irradiation levels. The solar cells were irradiated for a range of proton energies (75 keV, 300 keV, and 1 MeV) and fluences (up to 4 × 1014 p/cm2). The fluences of the energy proton irradiations were varied to induce the same amount of vacancies in the absorber layer due to non-ionizing nuclear energy loss (predominant at <300 keV) and electron ionization loss (predominant at >300 keV). While proton irradiation of the solar cells initially resulted in degradation of the photovoltaic parameters, self-healing was observed after two months where the performance of the devices was shown to return to their pristine operation levels. Their ability to recover upon radiation exposure supports the practical potential of perovskite solar cells for next-generation space missions.\",\"PeriodicalId\":486383,\"journal\":{\"name\":\"APL Energy\",\"volume\":\"4 1\",\"pages\":\"0\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2023-09-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"APL Energy\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1063/5.0158216\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"APL Energy","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1063/5.0158216","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Radiation tolerance and self-healing in triple halide perovskite solar cells
The high tolerance and stability of triple halide perovskite solar cells is demonstrated in practical space conditions at high irradiation levels. The solar cells were irradiated for a range of proton energies (75 keV, 300 keV, and 1 MeV) and fluences (up to 4 × 1014 p/cm2). The fluences of the energy proton irradiations were varied to induce the same amount of vacancies in the absorber layer due to non-ionizing nuclear energy loss (predominant at <300 keV) and electron ionization loss (predominant at >300 keV). While proton irradiation of the solar cells initially resulted in degradation of the photovoltaic parameters, self-healing was observed after two months where the performance of the devices was shown to return to their pristine operation levels. Their ability to recover upon radiation exposure supports the practical potential of perovskite solar cells for next-generation space missions.